Kinetics of proton transfer from cationic carbon acids in water and aqueous DMSO. Effect of activating groups and solvent on intrinsic rate constants

Journal of Organic Chemistry

Volumn 70, Issue 19, 2005, Pages 7721-7730

  Bernasconi, Claude F ^a   Fairchild, Douglas E ^a   Montañez, Robert L ^a   Aleshi, Perdram ^a   Zheng, Huaiben ^a   Lorance, Edward ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; INORGANIC ACIDS; IONIC CONDUCTION; PHOSPHORUS COMPOUNDS; POSITIVE IONS; RATE CONSTANTS; SOLUTIONS; WATER;

CARBON ACID; CONJUGATE BASES; PROTON TRANSFER; SOLVENT TRANSFER;

PROTONS;

ACETONYLTRIPHENYLPHOSPHONIUM ION; AMINE; CARBONIC ACID DERIVATIVE; DIMETHYL SULFOXIDE; ION; N METHYL 4 (PHENYLSULFONYLMETHYL)PYRIDINIUM ION; N METHYL 4 PHENACYLPYRIDINIUM PYRIDINIUM ION; NITROALKANE; PHENACYLTRIPHENYLPHOSPHONIUM ION; UNCLASSIFIED DRUG;

ACIDITY; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; PROTON TRANSPORT; SOLVATION;

EID: 24944488874     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo051166r     Document Type: Article

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