Fractionation of Fe isotopes as a result of redox processes in a basin

Geochemistry International

Volumn 43, Issue 8, 2005, Pages 797-803

  Malinovsky, D N ^a,d   Rodyushkin, I V ^a,c   Shcherbakova, E P ^b,d   Ponter, C ^c   Ohlander B ^d   Ingri, J ^d  

^a GEOLOGICAL INSTITUTE   (Russian Federation)

^b NATIONAL UNIVERSITY OF SCIENCE AND TECHNOLOGY MISIS   (Russian Federation)

^c Sweden   (Sweden)

^d LULEÅ UNIVERSITY OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

FRACTIONATION; GEOCHEMISTRY; IRON; ISOTOPES; MASS SPECTROMETRY; REDOX REACTIONS;

BOTTOM SEDIMENTS; ISOTOPE FRACTIONATION; NATURAL BASINS;

SEDIMENTS;

IRON; ISOTOPIC FRACTIONATION; REDOX CONDITIONS; SEDIMENT CHEMISTRY;

EID: 24644458602     PISSN: 00167029     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (28)

1. X. K. Zhu, Y. Guo, R. J. P. Williams, et al., "Mass Fractionation Processes of Transition Metal Isotopes," Earth Planet. Sci. Lett. 200, 47-62 (2002).
2. B. L. Beard, C. M. Johnson, L. Cox, et al., "Iron Isotope Biosignature," Science 285, 1889-1892 (1999).
3. B. L. Beard and C. M. Johnson, "High Precision Iron Isotope Measurements of Terrestrial and Lunar Materials," Geochim. Cosmochim. Acta 63, 1653-1660 (1999).
4. A. D. Anbar, J. E. Roe, J. Berling, and K. N. Nealson "Nonbiological Fractionation of Iron Isotopes," Science, 288, 126-128 (2000).
5. X. K. Zhu, R. K. O'Nions, Y. Guo, and B. C. Reynolds, "Secular Variation of Iron Isotopes in North Atlantic Deep Water," Science 287, 2000-2002 (2000).
6. M. Sharma, M. Polizzotto, and A. D. Anbar, "Iron Isotopes in Hot Springs along the Juan de Fuca Ridge," Earth Planet. Sci. Lett. 194, 39-51 (2001).
7. T. D. Bullen, A. F. White, C. W. Childs, et al., "Demonstration of Significant Abiotic Iron Isotope Fractionation in Nature," Geology 29, 699-702 (2001).
8. S. L. Brantley, L. Liermann, and T. D. Bullen, "Fractionation of Fe Isotopes by Soil Microbes and Organic Acids," Geology 29, 535-538 (2001).
9. B. L. Beard, C. M. Johnson, J. L. Skulan, et al., "Application of Fe Isotopes to Tracing the Geochemical and Biological Cycling of Fe," Chem. Geol. 195, 87-117 (2003).
10. J. L. Skulan, B. L. Beard, and C. M. Johnson, "Kinetic and Equilibrium Fe Isotope Fractionation between Fe(III) and Hematite," Geochim. Cosmochim. Acta 66, 2995-3015 (2002).
11. F. Ödman, T. Ruth, and C. Pontér, "Validation of a Field Filtration Technique for Characterization of Suspended Particulate Matter from Freshwater: I. Major Elements," Appl. Geochem. 14, 301-317 (1999).
12. K. Boström, L. Wiborg, and J. Ingri, "Geochemistry and Origin of Ferromanganese Concretions in the Gulf of Bothnia," Mar. Geol. 50, 1-24 (1982).
13. M. Kersten and U. Forster, "Speciation of Trace Elements in Sediments," in Trace Element Speciation: Analytical Methods and Problems, Ed. by G. Batley (CRC, 1989), pp. 245-317.
14. F. W. E. Strelow, "Improved Separation of Iron from Copper and Other Elements by Anion-Exchange Chromatography on a 4% Cross-Linkage Resin with High Concentrations of Hydrochloric Acid," Talanta 27, 727-732 (1980)
15. A. Stenberg, D. Malinovsky, I. Rodushkin, et al., "Separation of Fe from Whole Blood Matrix for Precise Isotopic Ratio Measurements by MC-ICP-MS: A Comparison of Different Approaches," J. Anal. At. Spectrom. 18, 23-28 (2003).
16. D. Malinovsky, A. Stenberg, I. Rodushkin, et al., "Performance of High Resolution MC-ICP-MS for Fe Isotope Ratio Measurements in Sedimentary Geological Materials," J. Anal. At. Spectrom. 18, 687-695 (2003).
17. J. E. Roe, A. D. Anbar, and J. Barling, "Nonbiological Fractionation of Fe Isotopes: Evidence of an Equilibrium Isotope Effect," Chem. Geol. 195, 69-85 (2003).
18. J. Woodhead, "A Simple Method for Obtaining Highly Accurate Pb Isotope Data by MC-ICP-MS," J. Anal. At. Spectrom. 17, 1381-1384 (2002).
19. W. Davison, "Iron and Manganese in Lakes," Earth Sci. Rev. 34, 119-163 (1993).
20. E. M. Galimov, The Nature of Biological Isotope Fractionation (Nauka, Moscow, 1981) [in Russian].
21. J. R. O'Neil, "Theoretical and Experimental Aspects of Isotopic Fractionation," in Reviews in Mineralogy, Vol. 16: Stable Isotopes in High Temperature Geological Processes, Ed. by J. W. Valley, H. P. Taylor, and J. R. O'Neil (Mineral. Soc. Am., Washington, 1986), pp. 1-40.
22. 44Ca) in Inorganic Aragonite and Cultured Planktonic Foraminifera," Geochim. Cosmochim. Acta 47, 67-79 (2003).
23. V. B. Polyakov and S. D. Mineev, "Mössbauer Spectroscopy as Applied to Isotopic Geochemistry: I. Equilibrium Fractionation of Iron Isotopes," Geokhimiya, No. 8, 858-870 (1999) [Geochem. Int. 37, 765-776 (1999)].
24. R. E. Criss, Principles of Stable Isotope Distribution (Oxford Univ. Press, New York, 1999), p. 254.
25. F. J. Millero, "The Effect of Ionic Interactions on the Oxidation of Metals in Natural Waters," Geochim. Cosmochim. Acta 49, 547-553 (1985).
26. D. W. King, H. A. Lounsbury, and F. J. Millero, "Rates and Mechanisms of Fe(II) Oxidation at Nanomolar Total Iron Concentrations," Environ. Sci. Technol. 29, 818-824 (1995).
27. D. W. King, "Role of Carbonate Speciation on the Oxidation Rate of Fe(II) in Aquatic Systems," Environ. Sci. Technol. 32, 2997-3003 (1998).
28. B. L. Beard, C. M. Johnson, K. L. Von Damm, et al., "Iron Isotope Constraints on Fe Cycling and Mass Balance in Oxygenated Earth Oceans," Geology 31, 629-632 (2003).