Isomerization in substitution processes of cyclometallated dimethylhaloplatinum(IV) complexes

Dalton Transactions

Volumn , Issue 6, 2003, Pages 1106-1113

  Font Bardía, Mercè ^a   Gallego, Carlos ^a   González, Gabriel ^a,b   Martinez, Manuel ^a   Merbach, André E ^b   Solans, Xavier ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

^b Institut de chimie moleculaire et biologique Ecole Polytechnique Federale de Lausanne   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; DERIVATIVES; RIGIDITY; SUBSTITUTION REACTIONS; X RAY CRYSTALLOGRAPHY;

CYCLOMETALLED IMINE; ISOMERIZATION REACTIONS;

ISOMERIZATION;

EID: 24644450125     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b209844j     Document Type: Article

References (39)

1. M. L. Tobe and J. Burgess, Inorganic Reaction Mechanisms, Longman, New York, 1999.
2. See for example: M. V. Twigg, Mechanisms of Inorganic and Organometallic Reactions, Plenum, New York, 1983-1994.
3. N. J. Curtis, G. A. Lawrance, P. A. Lay and A. M. Sargeson, Inorg. Chem., 1986, 25, 484.
4. N. E. Dixon, G. A. Lawrance, P. A. Lay and A. M. Sargeson, Inorg. Chem., 1983, 22, 846.
5. L. Drougge and L. I. Elding, Inorg. Chim. Acta, 1986, 121, 175.
6. A. Peloso, Coord. Chem. Rev., 1973, 10, 123.
7. R. Romeo, Comments Inorg. Chem., 1990, 11, 21.
8. U. Frey, L. Helm, A. E. Merbach and R. Romeo, J. Am. Chem. Soc., 1989, 111, 8161.
9. S. Reinartz, P. S. White, M. Brookhart and J. L. Templeton, J. Am. Chem. Soc., 2001, 123, 6425.
10. U. Felk, W. Kaminsky and K. Goldberg, J. Am. Chem. Soc., 2001, 123, 6423.
11. S. Otto and A. Roodt, Inorg. Chem. Commun., 2001, 4, 49.
12. U. Fekl and K. I. Goldberg, J. Am. Chem. Soc., 2002, 124, 6804.
13. P. V. Bernhardt, C. Gallego and M. Martinez, Organometallics, 2000, 19, 4862.
14. P. V. Bernhardt, C. Gallego, M. Martinez and T. Parella, Inorg. Chem., 2002, 41, 1747.
15. M. Font Bardía, C. Gallego, M. Martinez and X. Solans, Organometallics, 2002, 21, 305.
16. C. Anderson, M. Crespo, M. Font-Bardía, A. Klein and X. Solans, J. Organomet. Chem., 2000, 601, 22.
17. M. Crespo, M. Martinez and J. Sales, Organometallics, 1993, 12, 4267.
18. M. Crespo, M. Martinez, J. Sales, X. Solans and M. Font-Bardía, Organometallics, 1992, 11, 1288.
19. R. B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1991.
20. M. Gómez, J. Granell and M. Martinez, Organometallics, 1997, 16, 2539.
21. M. Gómez, J. Granell and M. Martinez, J. Chem. Soc., Dalton Trans., 1998, 37.
22. E. W. Abel, Chem. Br., 1990, 148.
23. E. W. Abel, A. R. Khan, K. Kite, K. G. Orrell and V. Sik, J. Organomet. Chem., 1982, 225, 357.
24. S. G. Murray and F. R. Hartley, Chem. Rev., 1981, 81, 365.
25. N. Quirós Méndez, A. M. Arif and J. A. Gladysz, Organometallics, 1991, 10, 2199.
26. A. T. Ashby, S. S. Alguindigue, J. D. Schwane and T. A. Daniel, Inorg. Chem., 2001, 40, 6643.
27. F. Bozoglián, G. Gonzalez, M. Martinez, M. Queirolo and B. Sienra, Inorg. Chim. Acta, 2001, 318, 191.
28. M. Crespo, X. Solans and M. Font-Bardía, Organometallics, 1995, 14, 355.
29. M. Crespo, M. Font Bardía and X. Solans, Polyhedron, 2002, 21, 105.
30. The equivalent endo compound prepared in ref. 13 showed the presence of 100% of the trans-MeS isomer in solution.
31. P. H. H. Budzelaar, gNMR version 4.1, Cherwell Scientific, Letchworth, 1995.
32. M. G. Basallote, J. Durán, M.-J. Fernández- Trujillo and M.-A. Máñez, J. Chem. Soc., Dalton Trans., 1998, 3227.
33. J. H. Espenson, Chemical Kinetics and Reaction Mechanisms, McGraw-Hill, New York, 1995.
34. J. D. Scott and R. J. Puddephatt, Organometallics, 1983, 2, 1643.
35. SHELXS in: G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467.
36. G. M. Sheldrick, SHELXL-97, Program for refinement of crystal structures, University of Göttingen, Germany, 1997.
37. International Tables of X-Ray Crystallography, Kynoch Press, Birmingham, 1974.
38. R. A. Binstead and A. D. Zuberbühler, SPECFIT version 2.10, Spectrum Software Associates, Marlborough, 1996.
39. P. Bugnon, L. G., Y. Ducommun, P. Sauvageat, A. E. Merbach, R. Ith, R. Tschanz, M. Doludda, R. Bergbauer and E. Grell, Anal. Chem., 1996, 68, 3045.