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Volumn 74, Issue 8, 2005, Pages 2214-2216

Transformation between monovalent and divalent ionic solids: An ionic(I)-ionic(II) phase transition in a biferrocene-F1TCNQ charge-transfer complex

Author keywords

Biferrocene; Charge transfer complex; F1 TCNQ; Phase transition; Valence transition

Indexed keywords


EID: 24644448237     PISSN: 00319015     EISSN: None     Source Type: Journal    
DOI: 10.1143/JPSJ.74.2214     Document Type: Article
Times cited : (30)

References (18)
  • 5
    • 0003740824 scopus 로고
    • Mixed Valency Systems: Applications in Chemistry, Physics, and Biology
    • ed. K. Prassides (Kluwer, Dordrecht)
    • D. N. Hendrickson: in Mixed Valency Systems: Applications in Chemistry, Physics, and Biology, ed. K. Prassides (Kluwer, Dordrecht, 1991) NATO ASI Series, Series C, p. 343.
    • (1991) NATO ASI Series, Series C , pp. 343
    • Hendrickson, D.N.1
  • 9
    • 24644523233 scopus 로고    scopus 로고
    • note
    • 3, Z = 1, R1 = 0:0637, and wR2 = 0:1313. The space group of the crystal was found to be invariant throughout the transition.
  • 10
    • 24644523987 scopus 로고    scopus 로고
    • note
    • 3, R1 = 0:0508, and wR2 = 0:1250.
  • 16
    • 0001294785 scopus 로고
    • The negative charges on the trimer estimated from the bond lengths were approximately -1.0 at RT and -2.4 at 90 K. This is a rough estimation but qualitatively consistent with one-electron transfer. As for the method of estimating the charge distribution, see T. J. Kistenmacher, T. J. Emge, A. N. Bloch and D. O. Cowan: Acta Crystallogr. B 38 (1982) 1193;
    • (1982) Acta Crystallogr. B , vol.38 , pp. 1193
    • Kistenmacher, T.J.1    Emge, T.J.2    Bloch, A.N.3    Cowan, D.O.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.