Sorptive and catalytic properties of partially sulfonated resins

Industrial and Engineering Chemistry Research

Volumn 43, Issue 11, 2004, Pages 2658-2668

  Lode, Florian ^a,b   Freitas, Sergio ^a   Mazzotti, Marco ^a   Morbidelli, Massimo ^a  

^a ETH ZURICH   (Switzerland)

^b EVONIK INDUSTRIES AG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; METHANOL; POLYSTYRENES; SORPTION; SULFONATION;

METHYL ACETATE; SULFONATED RESINS;

ION EXCHANGE RESINS;

ACETIC ACID; ACETIC ACID DERIVATIVE; COPOLYMER; ION EXCHANGE RESIN; METHANOL; METHYL ACETATE; POLY(STYRENE CO DIVINYLBENZENE); RESIN; UNCLASSIFIED DRUG; WATER;

RESIN;

ARTICLE; CATALYSIS; CATALYST; CHROMATOGRAPHY; CROSS LINKING; EQUILIBRIUM CONSTANT; POROSITY; SULFONATION;

EID: 2442677973     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030664s     Document Type: Article

References (20)

1. Cornel, P.; Sontheimer, H. Sorption of dissolved organics from aqueous solution by polystyrene resins. 1. Resin characterization and sorption equilibrium. Chem. Eng. Sci. 1986, 41, 1791.
2. Gusler, G. M.; Browne, T. E.; Cohen, Y. Sorption of Organics from aqueous solution onto polymeric resins. Ind. Eng. Chem. Res. 1993, 32, 2727.
3. Sinegra, J. A.; Carta, G. Sorption of water from alcohol-water mixtures by cation-exchange resins. Ind. Eng. Chem. Res. 1987, 26, 2437.
4. Hoffmann, A. S. Application of thermally reversible polymer hydrogels in therapeutics and diagnostics. J. Controlled Release 1987, 6, 297.
5. Mazzotti, M.; Kruglov, A.; Neri, B.; Gelosa, D.; Morbidelli, M. A continuous chromatographic reactor: SMBR. Chem. Eng. Sci. 1996, 51, 1827.
6. Kawase, M.; Suzuki, T. B.; Inoue, K.; Yoshimoto, K.; Hashimoto, K. Increased esterification conversion by application of the simulated moving bed reactor. Chem. Eng. Sci. 1996, 51, 2971.
7. Mensah, P.; Carta, G. Adsorptive control of water in esterification with immobilized enzymes. Continuous operation in a periodic countercurrent reactor. Biotechnol. Bioeng. 1999, 66, 137.
8. Lode, F.; Houmard, M.; Mazzotti, M.; Morbidelli, M. Continuous Reactive Chromatography. Chem. Eng. Sci. 2001, 56, 269.
9. Mazzotti, M.; Neri, B.; Gelosa, D.; Morbidelli, M. Kinetics of liquid-phase esterification catalyzed by acidic resins. Ind. Eng. Chem. Res. 1997, 36, 3.
10. Tiihonen, J.; Laatikainen, M.; Markkanen, I.; Paatero, E. Sorption of neutral components in ion-exchange resins. 1. Effect of cross-link density and counter-ion on selective sorption of water-ethanol mixtures in sulfonated PS-DVB resins. Ind. Eng. Chem. Res. 1999, 38, 4832.
11. Bothe, N.; Doscher, F.; Klein, J.; Widdecke, H. Thermal stability of sulphonated styrene-divinylbenzene resins. Polymer 1979, 20, 850.
12. Bothe, N. Struktur, Stabilität und katalytische Aktivität sulfonsaurer Styrol-Divinylbenzolharze. Ph.D. Dissertation, Technical University of Braunschweig, Braunschweig, Germany, 1980.
13. Kipling, J. J. Adsorption from solutions of non-electrolytes; Academic Press: New York, 1965.
14. Maurer, G.; Prausnitz, J. Thermodynamics of phase equilibrium for systems containing gels. Fluid Phase Equilib. 1996, 115, 113.
15. Gmehling, J.; Li, J.; Schiller, M. A Modified UNIFAC Model. 2. Present Parameter Matrix and Results for Different Thermodynamic Properties. Ind. Eng. Chem. Res. 1993, 32, 178.
16. Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, 1953.
17. Tiihonen, J.; Markkanen, I.; P. Aanismaa; Laatikainen, M.; Paatero, E. Modelling the sorption of water-ethanol mixtures in cross-linked ionic and neutral polymers. Chem. Eng. Sci. 2002, 57, 1885.
18. Prange, M.; Hooper, H.; Prausnitz, J. Thermodynamics of Aqueous Systems Containing Hydrophilic Polymer Gels. AIChE J. 1989, 35, 803.
19. Ishidao, T.; Iwai, Y.; Hashimoto, Y.; Arai, Y. Correlation for volume phase transition of polymeric gel (vinyl alcohol-sodium acrylate copolymer) in water-alcohol mixtures. Polym. Eng. Sci. 1994, 34, 507.
20. Zundel, G. Hydration and Intermolecular Intermolecular Interaction; Academic Press: New York, 1969.