Ionic solutions in the binding mean spherical approximation. Thermodynamics of associating electrolytes up to very high concentrations

Journal of Physical Chemistry B

Volumn 108, Issue 18, 2004, Pages 5763-5770

  Vilariño, Teresa ^a   Bernard, Olivier ^b   Simonin, Jean Pierre ^b  

^a UNIVERSITY OF A CORUÑA   (Spain)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; HYDRATION; INORGANIC ACIDS; IONIC STRENGTH; IONS; NEGATIVE IONS; OSMOSIS; PARTICLE SIZE ANALYSIS; PERMITTIVITY; SODIUM; SOLUTIONS; THERMODYNAMICS; VACUUM;

HARD SPHERES; MEAN SPHERE APPROXIMATION; MOLECULAR REPRESENTATION OF SOLUTE; SPHERICAL APPROXIMATIONS;

ELECTROLYTES;

EID: 2442667750     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp037993i     Document Type: Article

References (63)

1. Percus, J. K.; Yevick, G. Phys. Rev. 1964, 136, 290. Lebowitz, J. L.; Percus, J. K. Phys. Rev. 1966, 144, 251. Waisman, E.; Lebowitz, J. L. J. Chem. Phys. 1970, 52, 4307.
2. Percus, J. K.; Yevick, G. Phys. Rev. 1964, 136, 290. Lebowitz, J. L.; Percus, J. K. Phys. Rev. 1966, 144, 251. Waisman, E.; Lebowitz, J. L. J. Chem. Phys. 1970, 52, 4307.
3. Percus, J. K.; Yevick, G. Phys. Rev. 1964, 136, 290. Lebowitz, J. L.; Percus, J. K. Phys. Rev. 1966, 144, 251. Waisman, E.; Lebowitz, J. L. J. Chem. Phys. 1970, 52, 4307.
4. (a) Blum, L. Mol. Phys. 1975, 30, 1529.
5. (b) Blum, L.; Høye, J. S. J. Phys. Chem. 1977, 81, 1311.
6. Blum, L. J. Stat. Phys. 1978, 18, 451. Blum, L.; Vericat, F.; Fawcett, W. R. J. Chem. Phys. 1992, 96, 3039. Blum, L. J. Chem. Phys. 2002, 117, 756.
7. Blum, L. J. Stat. Phys. 1978, 18, 451. Blum, L.; Vericat, F.; Fawcett, W. R. J. Chem. Phys. 1992, 96, 3039. Blum, L. J. Chem. Phys. 2002, 117, 756.
8. Blum, L. J. Stat. Phys. 1978, 18, 451. Blum, L.; Vericat, F.; Fawcett, W. R. J. Chem. Phys. 1992, 96, 3039. Blum, L. J. Chem. Phys. 2002, 117, 756.
9. Triolo, R.; Grigera, J. R.; Blum, L. J. Phys. Chem. 1976, 80, 1858. Triolo, R.; Blum, L.; Floriano, M. A. J. Chem. Phys. 1978, 82,1368. Triolo, R.; Blum, L.; Floriano, M. A. J. Phys. Chem. 1977, 67, 5956.
10. Triolo, R.; Grigera, J. R.; Blum, L. J. Phys. Chem. 1976, 80, 1858. Triolo, R.; Blum, L.; Floriano, M. A. J. Chem. Phys. 1978, 82,1368. Triolo, R.; Blum, L.; Floriano, M. A. J. Phys. Chem. 1977, 67, 5956.
11. Triolo, R.; Grigera, J. R.; Blum, L. J. Phys. Chem. 1976, 80, 1858. Triolo, R.; Blum, L.; Floriano, M. A. J. Chem. Phys. 1978, 82,1368. Triolo, R.; Blum, L.; Floriano, M. A. J. Phys. Chem. 1977, 67, 5956.
12. Watanasiri, S.; Brulé, M. R.; Lee, L. L. J. Phys. Chem. 1982, 86, 292. Sun, T.; Lénard, J. L.; Teja, A. S. J. Phys. Chem. 1994, 98, 6870.
13. Watanasiri, S.; Brulé, M. R.; Lee, L. L. J. Phys. Chem. 1982, 86, 292. Sun, T.; Lénard, J. L.; Teja, A. S. J. Phys. Chem. 1994, 98, 6870.
14. Fawcett, W. R.; Tikanen, A. C. J. Phys. Chem. 1996, 100, 4251.
15. Molero, M.; Gonzalez-Arjona, D.; Calvente, J. J.; Lopez-Perez, G. J. Electroanal. Chem. 1999, 460, 100. Lopez-Perez, G.; Gonzalez-Arjona, D.; Molero, M. J. Electroanal. Chem. 2000, 480, 9.
16. Molero, M.; Gonzalez-Arjona, D.; Calvente, J. J.; Lopez-Perez, G. J. Electroanal. Chem. 1999, 460, 100. Lopez-Perez, G.; Gonzalez-Arjona, D.; Molero, M. J. Electroanal. Chem. 2000, 480, 9.
17. Simonin, J. P., Blum, L.; Turq, P. J. Phys. Chem. 1996, 100, 7704.
18. Simonin, J. P. J. Phys. Chem. 1997, 101, 4313.
19. Ebeling, W.; Grigo, M. J. Solution Chem. 1982, 11, 151.
20. Barthel, J.; Krienke, H.; Kunz, W. Physical Chemistry of Electrolyte Solutions, Modern Aspects; Steinkopff Springer: Berlin, 1998.
21. Tikanen, A. C.; Fawcett, W. R. Ber. Bunsen-Ges. Phys. Chem. 1996, 100, 634; J. Electroanal. Chem. 1997, 439, 107.
22. Tikanen, A. C.; Fawcett, W. R. Ber. Bunsen-Ges. Phys. Chem. 1996, 100, 634; J. Electroanal. Chem. 1997, 439, 107.
23. Vilariño, T.; Sastre de Vicente, M. E. J. Phys. Chem. 1996, 100, 16378; Phys. Chem. Chem. Phys. 1999. 1, 2453.
24. Vilariño, T.; Sastre de Vicente, M. E. J. Phys. Chem. 1996, 100, 16378; Phys. Chem. Chem. Phys. 1999. 1, 2453.
25. (a) Simonin, J. P.; Bernard, O.; Blum, L. J. Phys. Chem. B 1998, 102, 4411.
26. (b) 1999, 103, 699.
27. Blum, L.; Bernard, O. J. Stat. Phys. 1995, 79, 569. Bernard, O.; Blum, L. J. Chem. Phys. 1996, 104, 4746.
28. Blum, L.; Bernard, O. J. Stat. Phys. 1995, 79, 569. Bernard, O.; Blum, L. J. Chem. Phys. 1996, 104, 4746.
29. Wertheim, M. S. J. Chem. Phys. 1986, 55, 2929; 1987, 87, 7323; 1988, 88, 1214; J. Stat. Phys. 1984, 35, 19; 1986, 42, 459.
30. Wertheim, M. S. J. Chem. Phys. 1986, 55, 2929; 1987, 87, 7323; 1988, 88, 1214; J. Stat. Phys. 1984, 35, 19; 1986, 42, 459.
31. Wertheim, M. S. J. Chem. Phys. 1986, 55, 2929; 1987, 87, 7323; 1988, 88, 1214; J. Stat. Phys. 1984, 35, 19; 1986, 42, 459.
32. Wertheim, M. S. J. Chem. Phys. 1986, 55, 2929; 1987, 87, 7323; 1988, 88, 1214; J. Stat. Phys. 1984, 35, 19; 1986, 42, 459.
33. Wertheim, M. S. J. Chem. Phys. 1986, 55, 2929; 1987, 87, 7323; 1988, 88, 1214; J. Stat. Phys. 1984, 35, 19; 1986, 42, 459.
34. (a) McMillan, W. G.; Mayer, J. E. J. Chem. Phys. 1945, 13, 276.
35. (b) van't Hoff, J. H. Z. Phys. Chem. 1887, 1, 481. A partial translation of this paper may be found at http://dbhs.wvusd.k12.ca.us/ChemTeamIndex.html (Classic Papers section).
36. Herrera, J. N.; Blum, L. J. Chem. Phys. 1991, 94, 5077.
37. Simonin, J. P.; Hendrawan, H. Phys. Chem. Chem. Phys. 2001, 3, 4286.
38. Andersen, H. C.; Chandler, D. J. Chem. Phys. 1972, 57, 1918.
39. Grundke, E. W.; Henderson, D. Mol. Phys. 1972, 24, 269. Henderson, D.; Sokolowski, S.; Wasan, D. Mol. Phys. 1998, 93, 295.
40. Grundke, E. W.; Henderson, D. Mol. Phys. 1972, 24, 269. Henderson, D.; Sokolowski, S.; Wasan, D. Mol. Phys. 1998, 93, 295.
41. Boublik, T. J. Chem. Phys. 1970, 53, 471. Mansoori, G. A.; Carnahan, N. F.; Starling, K. E.; Leland, T. W. J. Chem. Phys. 1971, 54, 1523.
42. Boublik, T. J. Chem. Phys. 1970, 53, 471. Mansoori, G. A.; Carnahan, N. F.; Starling, K. E.; Leland, T. W. J. Chem. Phys. 1971, 54, 1523.
43. Chang, J.; Sandler, S. I. Chem. Eng. Sci. 1994, 49, 2777.
44. Blum, L.; Rosenfeld, Y. J. Stat. Phys. 1991, 63, 1177.
45. Dolezalek, F. Z. Phys. Chem. 1908, 64, 727. Scatchard, G. J. Am. Chem. Soc. 1921, 43, 2387.
46. Dolezalek, F. Z. Phys. Chem. 1908, 64, 727. Scatchard, G. J. Am. Chem. Soc. 1921, 43, 2387.
47. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, 2nd ed.; Butterworths: London, 1968; p 38.
48. Pailthorpe, B. A.; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc., Faraday Trans. 1984, 80, 115. Simonin, J. P. J. Chem. Soc., Faraday Trans. 1996, 92, 3519.
49. Pailthorpe, B. A.; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc., Faraday Trans. 1984, 80, 115. Simonin, J. P. J. Chem. Soc., Faraday Trans. 1996, 92, 3519.
50. Novotny, P.; Söhnel, O. J. Chem. Eng. Data 1988, 33, 49.
51. Rupert, F. F. J. Am. Chem. Soc. 1909, 31, 851.
52. Goldberg, R. N.; Manley, J. L.; Nuttal, R. L. Program Gamphi for Calculating Activity and Osmotic Coefficients of Aqueous Electrolyte Solutions at 298.15 K; National Bureau of Standards, Chemical Thermodynamics Division: Gathersburg, MD, 1984.
53. Haase, R.; Naas, H.; Thumm, H. Z. Phys. Chem. 1963, 37, 210.
54. Hamer, W. J.; Wu, Y. C. J. Phys. Chem. Ref. Data 1972, 1, 1047.
55. Rard, J. A.; Habenschuss, A.; Spedding, F. H. J. Chem. Eng. Data 1976, 21, 374.
56. Available from the web site http://www.colby.edu/chemistry/webmo/mointro. html of the Paul J. Schupf Computational Chemistry Laboratory at Colby college (USA).
57. Sillen, L. G.; Martell, A. E. Stability Constants of Metal-Ion Complexes and Supplement no. 1; The Chemical Society: London, 1964 and 1970.
58. Hood, G. C.; Redlich, O.; Reilly, C. A. J. Chem. Phys. 1954, 22, 2067.
59. Robinson, R. A. J. Chem. Soc., Faraday Trans. 1936, 32, 743. Marsh, A. R. W.; McElroy, W. J. Atmos. Environ. 1985, 19, 1075.
60. Robinson, R. A. J. Chem. Soc., Faraday Trans. 1936, 32, 743. Marsh, A. R. W.; McElroy, W. J. Atmos. Environ. 1985, 19, 1075.
61. Gutowsky, H. S.; Saika, A. J. Chem. Phys. 1953, 21, 1688.
62. Pitzer, K. S.; Roy, R. N.; Silvester, L. F. J. Am. Chem. Soc. 1977, 99, 4930.
63. Laasonen, K. E.; Klein, M. L. J. Phys. Chem. A 1997, 101, 98.