Thin-layer electrochemistry of 1,3-diferrocenyl-2-buten-1-one: Direct correlation between driving force and liquid/liquid interfacial electron transfer rates

Journal of Physical Chemistry B

Volumn 108, Issue 18, 2004, Pages 5742-5746

  Xu, Jie ^a   Frcic, Amir ^a   Clyburne, Jason A C ^a   Gossage, Robert A ^b   Yu, Hua Zhong ^a  

^a SIMON FRASER UNIVERSITY   (Canada)

^b ACADIA UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; CONCENTRATION (PROCESS); CYCLIC VOLTAMMETRY; DIFFUSION; ELECTRIC REACTANCE MEASUREMENT; ELECTROCHEMISTRY; REDOX REACTIONS; SURFACE CHEMISTRY; THERMODYNAMICS;

CYCLIC VOLTAMMETRIC BEHAVIOUR; KINETICS PARAMETERS; THIN LAYER ELECTROCHEMISTRY;

KETONES;

EID: 2442636466     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp049104c     Document Type: Article

References (42)

1. (a) Girault, H. H. J.; Schiffrin, D. J. In Charge and Field Effects in Biosystems; Allen, M. J., Usherwood, P. N. R., Eds.; Abacus Press: Kent (UK), 1984; pp 171-178.
2. Matsuno, S.; Ohki, A.; Takagi, M.; Ueno, K. Chem. Lett. 1981, 1543-1546.
3. (c) Lillie, G. C.; Holmes, S. M.; Dryfe, R. A. W. J. Phys. Chem. B 2002, 106, 12101-12103.
4. Girault, H. H. J.; Schiffrin, D. J. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1989; Vol. 15, pp 1-141.
5. Girault, H. H. J. In Modern Aspects of Electrochemistry; Bockris, J. O'M., Conway, B. E., White, R. E., Eds.; Plenum Press: New York, 1993; Vol. 25, pp 1-62.
6. Samec, Z.; Mareček, V.; Koryta, J.; Khalil, M. W. J. Electroanal. Chem. 1977, 83, 393-397.
7. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
8. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
9. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
10. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
11. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
12. For examples, see: (a) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1984, 161, 415-417. (b) Girault, H. H. J.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 15-26. (c) Geblewicz, G.; Schiffrin, D. J. J. Electroanal. Chem. 1988, 244, 27-37. (d) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1991, 314, 153-163. (e) Cheng, Y.; Schiffrin, D. J. J. Chem. Soc., Faraday Trans. 1994, 90, 2517-2523. (f) Ding, Z. F.; Fermín, D. J.; Brevet, P.-F.; Girault, H. H. J. Electronanal. Chem. 1998, 458, 139-148.
13. (a) Wei, C.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1995, 99, 16033-16042.
14. (b) Solomon, T.; Bard, A. J. J. Phys. Chem. 1995, 99, 17487-17489.
15. (c) Tsionsky, M.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1996, 100, 17881-17888.
16. (d) Ding, Z. F.; Quinn, B. M.; Bard, A. J. J. Phys. Chem. B 2001, 705, 6367-6374.
17. (a) Liu, B.; Mirkin, M. V. J. Am. Chem. Soc. 1999, 121, 8352-8355.
18. (b) Shao, Y.; Mirkin, M. V.; Rusling, J. F. J. Phys. Chem. B 1997, 101, 3202-3208.
19. (a) Zhang, J.; Unwin, P. R. J. Phys. Chem. B 2000, 104, 2341-2347.
20. (b) Zhang, J.; Barker, A. L.; Unwin, P. R. J. Electroanal. Chem. 2000, 483, 95-107.
21. (a) Shi, C.; Anson, F. C. Anal. Chem. 1998, 70, 3114-3118.
22. (b) Shi, C.; Anson, F. C. J. Phys. Chem. B 1998, 102, 9850-9854.
23. (c) Shi, C.; Anson, F. C. J. Phys. Chem. B 1999, 103, 6283-6289.
24. Shi, C.; Anson, F. C. J. Phys. Chem. B 2001, 105, 1047-1049.
25. (e) Shi, C.; Anson, F. C. J. Phys. Chem. B 2001, 105, 8963-8969.
26. Shafer, H. O.; Derback, T. L.; Koval, C. A. J. Phys. Chem. B 2000, 104, 1025-1032.
27. Park, H.; Higuchi, T.; Okazaki, S.; Oyama, M. J. Electroanal. Chem. 2002, 518, 27-32.
28. Wang, R.; Okajima, T.; Kitamura, F.; Matsumoto, N.; Thiemann, T.; Mataka, S.; Ohsaka, T. J. Phys. Chem. B 2003, 107, 9452-9458.
29. Erasmus, J. J. C.; Lamprecht, G. J.; Swarts, J. C.; Roodt, A.; Oskarsson, A. Acta Crystallogr. 1996, C52, 3000-3002.
30. du Plessis, W. C.; Vosloo, T. G.; Swarts, J. C. J. Chem. Soc., Dalton Trans. 1998, 2507-2514.
31. du Plessis, W. C.; Erasmus, J. J. C.; Lamprecht, G. J.; Conradie, J.; Cameron, T. S.; Aquino, M. A. S.; Swarts, J. C. Can. J. Chem. 1999, 77, 378-386.
32. Gupta, H. K.; Reginato, N.; Ogini, F. O.; Brydges, S.; McGlinchey, M. J. Can. J. Chem. 2002, 80, 1546-1554.
33. Steiger, B.; Anson, F. C. Inorg. Chem. 2000, 39, 4579-4585.
34. (a) Alvarez, J.; Kaifer, A. E. Organometallics 1999, 18, 5733-5734.
35. (b) Flanagan, J. B.; Margel, S.; Bard, A. J.; Anson, F. C. J. Am. Chem. Soc. 1978, 100, 4278-4253, and references therein.
36. oø at this particular interface are -93 and -83 mV, which are identical to each other within the experimental uncertainty.
37. Amemiya, S.; Ding, Z.; Zhou, J.; Bard, A. J. J. Electroanal. Chem. 2000, 483, 7-17.
38. oø) in ref 20, the ratios of rate constants for the two redox steps are estimated to be 28.9 (in 0.1 M HCl) and 32.1 (in 0.1 M NaCl), assuming other constants in the equations are the same.
39. Marcus, R. A. J. Phys. Chem. 1991, 95, 2010-2013.
40. Marcus, R. A. J. Chem. Phys. 1965, 43, 679-701.
41. (a) Roling, P. V.; Rausch, M. D. J. Org. Chem. 1972, 37, 729-732.
42. (b) Brown, G. M.; Meyer, T. J.; Cowan, D. O.; LeVanda, C.; Kaufman, F.; Roling, P. V.; Rausch, M. D. Inorg. Chem. 1975, 14, 506-511.