Knowledge-based control of emulsion polymerization: Tailoring adhesive properties

Journal of Coatings Technology and Research

Volumn 1, Issue 1, 2004, Pages 45-51

  Elizalde, Oihana ^a   Vicente, Matias ^a,b   Plessis, Christophe ^a,c   Leiza, Jose R ^a   Asua, Jose M ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b Aiscondel Division Quimica   (Spain)

^c UCB PHARMA   (Belgium)

Author keywords

Acrylics; Colloids; Emulsions; Gel permeation chromatography; Latexes; Process control

Indexed keywords

ACRYLICS; ADHESIVES; CHEMICAL RESISTANCE; GEL PERMEATION CHROMATOGRAPHY; GELS; KNOWLEDGE BASED SYSTEMS; LATEXES; LEAST SQUARES APPROXIMATIONS; MOLECULAR WEIGHT; PROCESS CONTROL; REGRESSION ANALYSIS;

ACRYLIC ADHESIVES; ADHESIVE PROPERTIES; COPOLYMER COMPOSITION; COPOLYMER LATEXES;

EMULSION POLYMERIZATION;

EID: 2442630420     PISSN: 15470091     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11998-004-0024-0     Document Type: Conference Paper

References (23)

1. MacGregor, J.F., Penlidis, A., and Hamielec, A.E., "Control of Polymerization Reactors: A Review," Polymer Process Engineering, 2, No. 2-3, 179 (1984).
2. Echevarría, A., Leiza, J.R., de la Cal, J.C., and Asua, J.M., "Molecular-Weight Distribution Control in Emulsion Polymerization," AIChE J., 44, 1667 (1998).
3. Crowley, T.J., Meadows, E.S., Kostoulas, E., and Doyle, F.J. III, "Control of Particle Size Distribution Described by a Population Balance Model of Semibatch Emulsion Polymerization," J. Process Control, 10, No. 5, 419 (2000).
4. Vicente, M., Ben Amor, S., Gugliotta, L.M., Leiza, J.R., and Asua, J.M., "Control of Molecular Weight Distribution in Emulsion Polymerization Using On-Line Reaction Calorimetry," Ind. Eng. Chem. Res., 40, 218 (2001).
5. Vicente, M., Leiza, J.R., and Asua, J.M., "Simultaneous Control of Copolymer Composition and MWD in Emulsion Polymerization," AIChE J., 47, No. 7, 1594 (2001).
6. Flores-Cerrillo, J. and MacGregor, J.F., "Control of Particle Size Distributions In Emulsion Semibatch Polymerization Using Mid-Course Correction Policies," Ind. Eng. Chem. Res., 41, No. 7, 1805 (2002).
7. Prasad, V., Schley, M., Russo, L.P., and Bequette, B.W., "Product Property and Production Rate Control of Styrene Polymerization," J. Process Control, 12, No. 3, 353 (2002).
8. Aubrey, D.W., Pressure Sensitive Adhesives - Principles of Formulation. Developments in Adhesives, Wake, W.C. (Ed.), Applied Sci., Publishers, Barking, England, 1977.
9. Laureau, C., Vicente, M., Barandiaran, M.J., Leiza, J.R., and Asua, J.M., "Effect of the Composition Profile of 2-ethylhexyl acrylate/methyl methacrylate Latex Particles and Adhesion," J. Appl. Poly. Sci., 81, No. 5, 1258 (2001).
10. Dale, W.C., Hayne, J.K., Paster, M.D., and Alstede, E.F., Tech. Seminar. Proc., Pressure Sensitive Tape Council, Itasca, 1987.
11. Zosel, A. and Ley, G., "Influence of Crosslinking on Structure, Mechanical Properties, and Strength of Latex Films," Macromolecules, 26, 2222 (1993).
12. Plessis, C., Arzamendi, G., Leiza, J.R., Schoonbrood, H., Charmot, D., and Asua, J.M., "Kinetics and Polymer Microstructure of the Seeded Semibatch Emulsion Copolymerization of n-butyl Acrylate and Styrene," Macromolecules, 34, No. 15, 5147 (2001).
13. Plessis, C., Arzamendi, G., Alberdi, J.M., Leiza, J.R., Schoonbrood, H., Charmot, D., and Asua, J.M., "Seeded Semibatch Emulsion Polymerization of Butyl Acrylate: Effect of Chain Transfer Agent on the Kinetics and the Structural Properties," J. Polym. Sci., Part A: Polym. Chem., 39, No. 7, 1106 (2001).
14. Satas, D., Handbook of Pressure Sensitive Adhesive Technology, Van Nostrand Reinhold, New York, 1989.
15. Satas, D., "Tayloring Pressure-Sensitive Adhesive Polymers," Adhesives Age, 15, No. 10, 19 (1972).
16. Plessis, C., Ph.D. Dissertation, The University of the Basque Country (Spain), 2000.
17. Elizalde, O., Vicente, M., Leiza, J.R., and Asua, J.M., "Control of the Adhesive Properties of n-butyl Acrylate/Styrene Latexes," Polym. React. Eng., 10, No. 4, 265 (2002).
18. Geladi, P. and Kowalski, B.R., "Partial Least-Squares Regression: a Tutorial," Anal. Chim. Acta, 185, 1 (1986).
19. Esbensen, K.H., Multivariate Data Analysis - In Practice, CAMO ASA, Oslo, Norway, 2000.
20. Saenz de Buruaga, I., Arotçarena, M., Armitage, P.D., Gugliotta, L.M., Leiza, J.R., and Asua, J.M., "On-Line Calorimetric Control of Emulsion Polymerization Reactors," Chem. Eng. Sci., 51, 2781 (1996).
21. Saenz de Buruaga, I., Echeverria, A., Armitage, P.D., de la Cal, J.C., Leiza, J.R., and Asua, J.M., "On-Line Control of a Semibatch Emulsion Polymerization Reactor Based on Calorimetry," AIChE J., 43, No. 4, 1069 (1997).
22. Storti, G. and Morbidelli, M., "Open-Loop Control of Polymerization Reactors," in Polymer Dispersions. Principles and Applications, Asua. J.M. (Ed), Kluwer Academic Publishers, Dordretch, 1997.
23. Odian, G., Principles of Polymerization, 3rd ed. John Wiley and Sons, Inc., New York, 1991.