Effect of the emulsifier on the dynamic behavior of particle size distribution in continuous emulsion polymerization of vinyl acetate

Journal of Chemical Engineering of Japan

Volumn 37, Issue 3, 2004, Pages 461-464

  Ohmura, Naoto ^a   Matsuzaki, Shigefumi ^a   Kondo, Kentaro ^a   Kataoka, Kunio ^b  

^a KOBE UNIVERSITY   (Japan)

^b Kansai Chemical Engineering Co Ltd   (Japan)

Author keywords

Continuous emulsion polymerization; Particle aggregation; Particle size distribution; Time dependent behavior; Vinyl acetate

Indexed keywords

CONCENTRATION (PROCESS); EMULSIFICATION; EMULSION POLYMERIZATION; MONOMERS; PARAMETER ESTIMATION; SURFACE ACTIVE AGENTS;

DYNAMIC BEHAVIOR; EMULSIFIER; TIME-DEPENDENT BEHAVIOR;

PARTICLE SIZE ANALYSIS;

POLYMERIZATION;

EID: 2442609692     PISSN: 00219592     EISSN: None     Source Type: Journal    
DOI: 10.1252/jcej.37.461     Document Type: Article

References (11)

1. Badder, E. E. and B. W. Brooks; "Start-Up Procedures for Continuous Flow Emulsion Polymerization Reactors," Chem. Eng. Sci., 39, 1499-1509 (1984)
2. Brooks, B. W. and G. Raman; "Effects Different Reactor Start-Up Procedures on the Continuous-Flow Emulsion Polymerization of Methylmethacrylate," Chem. Eng. Sci., 42, 1439-1449 (1987)
3. Brooks, B. W., H. W. Kropholler and S. N. Purt; "Emulsion Polymerization of Styrene in a Continuous Stirred Reactor," Polymer, 19, 193-196 (1978)
4. Greene, R. K., R. A. Gonzalez and G. W. Poehlein; "Continuous Emulsion Polymerization-Steady State and Transient Experiments with Vinyl Acetate and Methyl Methacrylate," Emulsion Polymerization-ACS Symposium Series No. 24, 1. Piirma and J. L. Gardon, eds., pp. 341-358, American Chemical Society, Washington, D.C., USA (1976)
5. Kemmere, M. F., J. Meuldijk, A. A. H. Drinkenburg and A. L. German; "Aspects of Coagulation During Emulsion Polymerization Styrene and Vinyl Acetate," J. Appl. Poly. Sci., 69, 2409-2421 (1998)
6. Muroi, S.: Chemistry of High Polymer Latices (Kobunshi Ratekkusu no Kagaku), pp. 97-98, Kobunshi Kankoukai, Kyoto, Japan (1970)
7. Nomura, M., S. Sasaki and K. Fujita; "Continuous Emulsion Polymerization of Vinyl Acetate in a Single Continuous Stirred-Tank" (in Japanese), Report of the Asahi Glass Foundation for Industrial Technology, 32, 301-313 (1978)
8. Ohmura, N., K. Kataoka, T. Yano, S. Matsuzaki and K. Kondo; "Self-Sustained Oscillation of PSD of Latex Particles in Continuous Emulsion Polymerization," Proc. of the 9th APCChE, Paper #654, Christchurch, New Zealand (2002)
9. Okamura, S. and T. Motoyama; "Emulsion Polymerization of Vinyl Avetate," J. Poly. Sci., 58, 221-227 (1962)
10. Penlidis, A., J. F. Macgregor and A. E. Hamielec; "Continuous Emulsion Polymerization: Design an Control of CSTR Trains," Chem. Eng. Sci., 44, 273-281 (1989)
11. Verwey, E. J. and J. T. G. Onerbeek; Theory of the Stability of Lyophobic Colloids, Elsevier, Amsterdam, the Netherlands (1948)