Synthesis and characterization of an almost linear, quasi-two-coordinate, cationic diorganoaluminum compound

Organometallics

Volumn 23, Issue 9, 2004, Pages 1965-1967

  Young, Jackie D ^a   Khan, Masood A ^a   Wehmschulte, Rudolf J ^a  

^a UNIVERSITY OF OKLAHOMA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROBENZENE; DIORGANOALUMINUM COMPOUND; LEWIS ACIDITY; MESITYL GROUPS;

ALUMINUM COMPOUNDS; BENZENE; CRYSTAL STRUCTURE; ETHERS; FLUORINE; HYDRIDES; OLEFINS; POLYMERIZATION; QUASICRYSTALS;

ORGANOMETALLICS;

EID: 2442499462     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0341707     Document Type: Article

References (19)

1. Bochmann, M.; Dawson, D. M. Angew. Chem., Int. Ed. Engl. 1996, 35, 2226-2228.
2. Dagorne, S.; Guzei, I. A.; Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 2000, 122, 274-289.
3. Atwood, D. A. Coord. Chem. Rev. 1998, 176, 407-430.
4. Budzelaar, P. H. M.; Talarico, G. Struct. Bonding 2003, 106, 141-165.
5. Kim, K.-C.; Reed, C. A.; Long, G. S.; Sen, A. J. Am. Chem. Soc. 2002, 124, 7662-7663.
6. Twamley, B.; Haubrich, S. T.; Power, P. P. Adv. Organomet. Chem. 1999, 44, 1-65.
7. Clyburne, J. A. C.; McMullen, N. Coord. Chem. Rev. 2000, 210, 73-99.
8. Wehmschulte, H. J.; Steele, J. M.; Young, J. D.; Khan, M. A. J. Am. Chem. Soc. 2003, 125, 1470-1471.
9. FF = 21.4 Hz,p-F, 4F), -166.0 (s, br, m-F, 8F).
10. -1(m). Details of the X-ray crystal structure of 2 which is a rare example of a monomeric aluminum hydride, will be published elsewhere.
11. I.
12. I.
13. Klosin, J.; Roof, G. R.; Chen, E. Y. X.; Abboud, K. A. Organometallics 2000, 19, 4684-4686.
14. Korolev, A. V.; Delpech, F.; Dagorne, S.; Guzei, I. A.; Jordan, R. F. Organometallics 2001, 20, 3367-3369.
15. Hair, G. S.; Cowley, A. H.; Jones, R. A.; McBurnett, B. G.; Voigt, A. J. Am. Chem. Soc. 1999, 121, 4922-4923.
16. Atwood, J. L. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: New York, 1993; pp 197-232.
17. Dry 1-octene (19.1 mmol, 3.0 mL) was added via syringe to a solution of 1b (45 mg, 0.033 mmol) in chlorobenzene (10 mL) at room temperature. After it was stirred for 24 h, the reaction mixture was quenched with ethanol (5 mL), resulting in the formation of a dense bottom phase. Separation of this phase followed by removal of the volatile material in vacuo afforded a pale yellow viscous oil (0.26 g), which was analyzed by GPC vs polystyrene standards. Yield: 12%.
18. Wehmschulte, R. J.; Grigsby, W. J.; Schiemenz, B.; Bartlett, R. A.; Power, P. P. Inorg. Chem. 1996, 35, 6694-6702.
19. Ruhlandt-Senge, K.; Ellison, J. J.; Wehmschulte, R. J.; Pauer, F.; Power, P. P. J. Am. Chem. Soc. 1993, 115, 11353-11357.