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2442446472
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note
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See Supporting Information for preparation of alkoxy maleimides.
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For reference to photoenolization during Norrish-Yang cyclization, see: Wagner, P. J. In CRC Handbook of Organic Photochemistry and Photobiology, 2nd ed.; CRC Press: Boca Raton, FL, 2004, Chapter 58, pp 1-70.
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Reductive cleavage of saturated hydroxyoxetanes has been reported previously using metal hydride reagents; see: Bach, T.; Kather, K. J. Org. Chem. 1996, 61, 3900.
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Feigenbaum et al. report small amounts of reductively cleaved products on Pd-catalyzed hydrogenation of an alkylideneoxetane. The major product was the saturated hydroxyoxetane; see: Arnould, J. C.; Enger, A.; Feigenbaum, A.; Pete, J. P. Tetrahedron 1979, 35, 2501.
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