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Volumn 109, Issue 32, 2005, Pages 15226-15235

Examination of the charge-sensitive vibrational modes in bis(ethylenedithio)tetrathiafulvalene

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; DEUTERIUM; INFRARED SPECTROSCOPY; MOLECULAR VIBRATIONS; OXIDATION; SUBSTITUTION REACTIONS;

EID: 24344474080     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp050247o     Document Type: Article
Times cited : (132)

References (47)
  • 1
    • 0004970080 scopus 로고
    • Highly conducting quasi one-dimensional organic crystals
    • Academic Press: London
    • For example see: (a) Highly Conducting quasi one-dimensional Organic Crystals. In Semiconductors and Semimetals; Conwell, E., Ed.; Academic Press: London, 1988; Vol. 27.
    • (1988) Semiconductors and Semimetals , vol.27
    • Conwell, E.1
  • 3
    • 0031788087 scopus 로고    scopus 로고
    • Structural data of the numerical CT salts containing ET are described in: (a) Mori, T. Bull. Chem. Soc. Jpn. 1998, 71, 2509.
    • (1998) Bull. Chem. Soc. Jpn. , vol.71 , pp. 2509
    • Mori, T.1
  • 11
    • 24344500325 scopus 로고    scopus 로고
    • note
    • 4,6,7 the horizontal stripe includes the 1-D stripe which consists of either a charge-rich molecule or a charge-poor molecule extending along the crystallographic a-axis. The 1-D stripes are stacked along the crystallographic c-axis, so that a charge-rich stripe is sandwiched by charge-poor stripes.
  • 19
    • 24344498403 scopus 로고    scopus 로고
    • note
    • 3, which is the stretching mode of the central C=C bond, is influenced by the e-mv interaction much more than charge difference.
  • 26
    • 24344455691 scopus 로고    scopus 로고
    • note
    • 4)TCE from the products.
  • 32
    • 24344447384 scopus 로고    scopus 로고
    • note
    • 2 salts, respectively). These spectral shapes are almost the same as those shown in Figure 4 except for the intensities.
  • 33
    • 24344480149 scopus 로고    scopus 로고
    • note
    • The same result has been already reported by Kozlov et al. in ref 18.
  • 35
    • 24344495598 scopus 로고    scopus 로고
    • Yamamoto, T.; Uruichi, M.; Yakushi, K.; Kawamoto, A. Unpublished work
    • 27 mode at 200 K has a narrower line width. The vi mode also exhibits the same temperature dependence.
  • 37
    • 24344508298 scopus 로고    scopus 로고
    • note
    • 2-bending mode.
  • 39
    • 24344497485 scopus 로고    scopus 로고
    • note
    • -1. This observation suggests inhomogeneous charge distributions.
  • 43
    • 24344500552 scopus 로고    scopus 로고
    • note
    • -1, is comparable to the resolution of the spectrometer. Therefore, the frequency shift due to the thermal contraction is negligibly small.
  • 44
    • 24344459188 scopus 로고    scopus 로고
    • note
    • -1 band are designated as the 82 band in ref 6 and the x3 band in ref 4, respectively.
  • 45
    • 24344502074 scopus 로고    scopus 로고
    • note
    • -1 for ρ = 0.
  • 47
    • 24344478913 scopus 로고    scopus 로고
    • note
    • + (bands 7 and 8 in Figure 8a).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.