Arsenic speciation analysis in water samples: A review of the hyphenated techniques

Environmental Monitoring and Assessment

Volumn 107, Issue 1-3, 2005, Pages 259-284

  Terlecka, Ewa ^a  

^a INSTITUTE OF METEOROLOGY AND WATER MANAGEMENT   (Poland)

Author keywords

Arsenic speciation; Hydride generation; Hyphenated techniques; Water analysis

Indexed keywords

ARSENIC; ATOMIC SPECTROSCOPY; HYDRIDES; INDUCTIVELY COUPLED PLASMA; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; OXIDATION; TOXIC MATERIALS;

ARSENIC SPECIFICATION; HYDRIDE GENERATION; HYPHENATED TECHNIQUES; PLASMA MASS SPECTROMETRY;

WATER QUALITY;

ARSENIC; LIPID;

ANALYTICAL METHOD; ARSENIC; SPECIATION (CHEMISTRY); WATER POLLUTION;

ANALYTIC METHOD; CONCENTRATION RESPONSE; METABOLITE; OXIDATION; REVIEW; SENSITIVITY ANALYSIS; WATER ANALYSIS; WATER CONTAMINATION; WATER SAMPLING;

ARSENATES; ARSENICALS; ENVIRONMENTAL MONITORING; LIPIDS; MASS SPECTROMETRY; MONOSACCHARIDES; ORGANIC CHEMICALS; REPRODUCIBILITY OF RESULTS; SENSITIVITY AND SPECIFICITY; WATER POLLUTANTS, CHEMICAL;

EID: 24044450266     PISSN: 01676369     EISSN: 15732959     Source Type: Journal    
DOI: 10.1007/s10661-005-3109-z     Document Type: Review

References (148)

1. Abdullah, M. I., Shiyu, Z. and Mosgren, K.: 1995, 'Arsenic and selenium species in the oxic and anoxic waters of the Oslofjord, Norway', Mar. Pollut. Bull. 31, 116-126. 10.1016/0025-326X(95)00082-X
2. Aggett, J. and Boyes, G.: 1989, 'Investigation of the contribution of metal ion enhancement of the rate of hydrolysis of sodium tetraborate to interferences in the determination of As(III) by hydride generation atomic absorption spectrometry, Analyst 114, 1159-1161. 10.1039/ an9891401159
3. Ali, I. and Aboul-Enein, H.: 2002, 'Speciation of arsenic and chromium metal ions by reversed phase high performance liquid chromatography', Chemosphere 48(3), 275-278. 10.1016/S0045-6535(02)00085-1
4. Andreae, M. O.: 1979, 'Arsenic speciation in seawater and interstitial waters: The influence of biological-chemical interactions on the chemistry of a trace element', Limnol. Oceanogr. 24, 440-452.
5. Andreae, M. O. and Andreae, T. W.: 1989, 'Dissolved arsenic species in the Schelde estuary and watershed', Belgium Estuar. Coast. Shelf Sci. 29, 421-433. 10.1016/0272-7714(89)90077-2
6. Azcue, J. M. and Nriagu, J. O.: 1995, 'Impact of abandoned mine tailings on the arsenic concentrations in Moira Lake, Ontario', J. Geochem. Explor. 52, 81-89. 10.1016/0375-6742(94)00032-7
7. Ballin, U., Kruse, R. and Ruessel, H. A.: 1994, 'Determination of total arsenic and speciation of arsenobetaine in marine fish by means of reaction-headspace gas chromatography utilising flame ionisation detection and element specific spectrophotometric determination', Fresenius J. Anal. Chem. 350, 54-61. 10.1007/BF00326253
8. Basu, A., Mahata, J., Gupta, S. and Giri, A. K.: 2001, 'Genetic toxicology of a paradoxical human carcinogen, arsenic: A review', Mutat. Res. 488(2), 171-194. 11344043
9. Bednar, A. J., Garbarino, J. R., Burkhardt, M. R., Ranville, J. F. and Wildeman, T. R.: 2004, 'Field and laboratory arsenic speciation methods and their application to natural-water analysis', Water Res. 38, 355-364. 10.1016/j.watres.2003.09.034
10. Braman, R. S. and Foreback, C. C.: 1973, 'Methylated forms of arsenic in the environment', Science 182(118), 1247-1249. 4800529
11. Branch, S., Ebdon, L. and O'Neill, P.: 1994, 'Determination of arsenic species in fish by directly coupled high performance liquid chromatography-induced coupled plasma mass spectrometry', J. Anal. Atom. Spectrom. 9, 33-37. 10.1039/ja9940900033
12. D. G. Brookins 1988 Eh-pH Diagrams for Geochemistry Springer-Verlag Berlin
13. Burguera, M. and Burguera, J. L.: 1997, 'Analytical methodology for speciation of arsenic in environmental and biological samples', Talanta 44, 1581-1604. 10.1016/S0039-9140(97)00064-7
14. Cabon, J. Y. and Cabon, N.: 2000, 'Speciation of major arsenic species in seawater by flow injection hydride generation atomic absorption spectometry', Fresenius J. Anal. Chem. 368(5), 484-489. 10.1007/ s002160000526
15. Capelo, J. L., Lavilla, I. and Bendicho, C.: 2001, 'Utlrasonic extraction followed by sonolysis-ozonolysis as a sample pretreatment method for determination of reactive arsenic toward sodium tetrahydroborate by flow-injection-hydride generation AAS', Anal. Chem. 73, 3732-3736. 10.1021/ac010193o
16. Carrero, P., Malave, A., Burguera, J. L., Burguera, M. and Rondon, C.: 2001, 'Determination of various arsenic species by flow injection hydride generatuin atomic absorption spectrometry: Investigation of the effects of the acid concentration of different reaction on the generation of arsines', Anal. Chim. Acta 438(1-2), 195-204. 10.1016/ S0003-2670(01)00796-6
17. Chatterjee, A., Das, D., Mandal, B. K., Chowdhury, T. R., Samanta, G. and Chakraborty, D.: 1995, 'Arsenic in groundwater in six districts of West Bengal, India: The biggest arsenic calamity in the world. Part 1. Arsenic species in drinking water and urine of the affected people', Analyst 120, 643-656. 10.1039/an9952000643
18. Chausseau, M., Roussel, C., Gilon, N. and Mermet, J. M.: 2000, 'Optimization of HPLC-ICP-AES for the determination of arsenic species', Fresenius' J. Anal. Chem. 366(5), 476-480. 10.1007/s002160050096
19. Chen, S. L., Yeh, S. J., Yang, M. H. and Lin, T. H.: 1995, 'Trace element concentration and arsenic speciation in the well water of a Taiwan area with endemic Blackfoot disease', Biol. Trace Elem. Res. 48, 263-274. 9398946
20. Code of Federal Regulations, 40 CFR 141.23. Available from: http://www.epa.gov/safe-water/ars/monovr.html
21. W. R. Cullen, K. J. Reimer. 1989; 'Arsenic speciation in the environment' 89, 713-764. 10.1021/cr00094a002
22. Cullen, W. R. and Reimer, K. J.: 1989, 'Arsenic speciation in the environment', Chem. Rev. 89, 713-764. 10.1016/S0967-0645(01)00023-6
23. Cutter, G. A., Cutter, L. S., Featherstone, A. M. and Lohrenz, S. E.: 2001 'Antimony and arsenic biogeochemistry in the western Atlantic Ocean' Deep-Sea Res. Part II - Topical Stud. Oceanog. 48 2895-2915.
24. Del Razo, L. M., Styblo, M., Cullen, W. R. and Thomas, D. J.: 2001, 'Determination of trivalent methylated arsenicals in biological matrices', Toxicol. Appl. Pharmacol. 174(3), 282-293. 10.1006/ taap.2001.9226
25. Demesmay, C., Olle, M. and Porthault, M.: 1994, 'Arsenic speciation by coupling high performance liquid chromatography with induced coupled plasma mass spectrometry', Fresenius J. Anal. Chem. 348, 205-210. 10.1007/BF00325361
26. Dasgupta, P. K., Hyang, H., Zhang, G. and Cobb, G.: 2002, 'Photometric measurement of trace As(III) and As(V) in drinking water', Talanta 58, 153-164. 10.1016/S0039-9140(02)00264-3
27. Do, B., Robinet, S., Pradeau, D. and Guyon, F.: 2001, 'Speciation of arsenic and selenium compounds by ion-pair reversed-phase chromatigraphy with electrothermic atomic absorption spectrometry', J. Chromatogr. A. 918(1), 87-98. 10.1016/S0021-9673(01)00723-3
28. Dojlido, J. and Świetlik, R.: 1998, 'Analiza śladowa wody', in: A. Kabata-Pendias and B. Szteke (eds), Quality Problems in Trace Analysis in Environmental Studies, Warszawa, Poland, pp. 215-238.
29. DPHE-BGS/MML: 1999, Groundwater Studies for Arsenic Contamination in Bangladesh. Phase I: Rapid Investigation Phase. BGS/MML Technical Report to Department for International Development, UK, 6 volumes.
30. Emett, M. T. and Khoe, G. H.: 2001, 'Photochemical oxidation of arsenic by oxygen and iron in acidic solutions', Water Res. 35, 649-656. 10.1016/ S0043-1354(00)00294-3
31. EPA.: 2001, 'National Primary Drinking Water Regulations; arsenic and clarifications to compliance and newsource contaminants monitoring', Fed. Register 66, 6975-7066.
32. Featherstone, A. M., Boult, P. R., O'Grady, B. V. and Butler, E. C. V.: 2000, 'A shipboard method for arsenic speciation using semi-automated hydride generation atomic fluorescence spectroscopy', Anal. Chim. Acta 409, 215-226. 10.1016/S0003-2670(99)00862-4
33. Feeney, R. and Kounaves, S. P.: 2000, 'On site analysis of arsenic in groundwater using a microfabricated gold ultramicroelectrode array', Anal. Chem. 72 (10), 2222-2228. 10.1021/ac991185z
34. Gallagher, P. A., Schwegel, C. A., Wei, X. and Creed, J. T.: 2001, 'Speciation and preservation of inorganic arsenic in drinking water sources using EDTA with IC separation and ICP-MS detection', J. Environ. Monit. 3(4), 371-376. 10.1039/b101658j
35. Gallagher, P. A., Shoemaker, J. A., Wei, X., Brockho-Schwegel, C. A. and Creed, J. T.: 2001, 'Extraction and detection of arsenicals in seaweed via accelerated solvent extraction with ion-chromatographic separation and ICP-MS detection', Fresenius J. Anal. Chem. 369, 71-80. 10.1007/ s002160000585
36. Gettar, R. T., Garavaglia, R. N., Gautier, E. A. and Batistoni, D. A.: 2000, 'Determination of inorganic and organic anionic arsenic species in water by ion chromatography coupled to hydride generation-inductively coupled plasma atomic emission spectrometry', J. Chromatogr. A 884 (1-2), 211-221. 10.1016/S0021-9673(00)00279-X
37. Gomez-Ariza, J. L., Sanchez-Rodas, D. and Giraldez, I.: 1998, 'Selective extraction of iron oxide associated arsenic species from sediments for speciation with coupled HPLC-HG-AAS', J. Anal. Atom. Spectrom. 13, 1375-1379. 10.1039/a806111d
38. Gong, Z., Lu X., Ma, M., Watt, C. and Le, X. C.: 2002, August 16, 'Arsenic speciation analysis', Talanta 58(1), 77-96.
39. Guerin, T., Astruc, A. and Astruc, M.: 1999, 'Speciation of arsenic and selenium compounds by HPLC hyphenated to specific detectors: A review of the main separation techniques', Talanta 50(1), 1-24. 1-24 10.1016/ S0039-9140(99)00140-X
40. Hall, G. E. M., Pelchat, J. C. and Gauthier, G.: 1999, 'Stability of inorganic arsenic(III) and arsenic(V) in water samples', J. Anal. Atom. Spectrom. 14, 205-213. 10.1039/a807498d
41. Hasegawa, H., Matsui, M., Okamura, S., Hojo, M., Iwasaki, N. and Sohrin, Y.: 1999, 'Arsenic speciation including 'hidden' arsenic in natural waters', Appl. Organometal. Chem. 13, 113-119. 10.1002/ (SICI)1099-0739(199902)13:2<113::AID-AOC837>3.3.CO;2-1
42. He, B., Jiang, G. B. and Xu, X.: 2000, 'Arsenic speciation based on ion exchange high-performance liquid chromatography hyphenated with hydride generation atomic fluorescence and on-line UV photo oxidation', Fresenius J. Anal. Chem. 368(8), 803-808. 10.1007/s002160000597
43. He, Y., Zheng, Y., Ramnaraine, M. and Locke, D.: 2004, 'Differential pulse cathodic stripping voltammetric speciation of trace level inorganic arsenic compounds in natural water samples', Anal. Chim. Acta 511, 55-61. 10.1016/j.aca.2004.01.036
44. Hemmings, M. J. and Jones, E. A.: 1991, 'The speciation of arsenic(V) and arsenic(III) by ion exchange chromatography in solutions containing iron and sulphuric acid', Talanta 38, 151-156. 10.1016/ 0039-9140(91)80123-H
45. Hindmarsh, J. T. and McCurdy, R. F.: 1986, 'Clinical and environmental aspects of arsenic toxicity', Crit. Rev. Clin. Lab. Sci. 23(4) 315-347. 3524997
46. Howard, A. G., Apte, S. C., Comber, S. D. W. and Morris, R. J.: 1988, 'Biogeochemical control of the summer distribution and speciation of arsenic in the Tamar estuary', Estuar. Coast. Shelf Sci. 27, 427-443. 10.1016/0272-7714(88)90098-4
47. Howard, A. G. and Comber, S. D. W.: 1992, 'Hydride trapping techniques for the speciation of arsenic', Mikrochim. Acta 109, 27-33. 10.1007/ BF01243206
48. Howard, A. G., Hunt, L. E. and Salou, C.: 1999, 'Evidence supporting the presence of dissolved dimethylarsinate in the marine environment', Appl. Organometal. Chem. 13, 39-46. 10.1002/ (SICI)1099-0739(199901)13:1<39::AID-AOC811>3.0.CO;2-Z
49. Huang, J.-H. and Ilgen, G.: 2004, 'Blank values, adsorption, pre-concentration, and sample preservation for arsenic speciation of environmental water samples', Anal. Chim. Acta 512, 1-10. 10.1016/ j.aca.2004.02.043
50. Huang, Y. M. and Whang, C. W.: 1998, 'Capillary electrophoresis of arsenic compounds with indirect fluorescence detection', Electrophoresis 19(12), 2140-2144. 10.1002/elps.1150191217
51. Inoue, Y., Kawabata, K., Takahashi, H. and Endo, G.: 1994, 'Determination of arsenic compounds using inductively coupled plasma mass spectrometry with ion chromatography', J. Chromatogr. 675A, 149-154. 10.1016/0021-9673(94)85269-3
52. K. J. Irgolic 1992 Arsenic in: M. Stoeppler (ed), Hazardous Metals in the Environment Elsevier Amsterdam pp. 288-350
53. Irgolic, K. J., Greschonig, H. and Howard, A. G.: 1995, 'Arsenic' in: A. Townshend (ed), The Encyclopedia of Analytical Science, Academic Press, pp. 168-184.
54. Jain, C. K. and Ali, I.: 2000, 'Arsenic: Occurrence, toxicity and speciation techniques', Water Res. 34(17), 4304-4312. 10.1016/ S0043-1354(00)00182-2
55. Jay, J. A., Blute, N. K., Hemond, H. F. and Durant, J. L.: 2004, 'Arsenic-sulfides confound anion exchange resin speciation of aqueous arsenic', Water Res. 38, 1155-1158. 10.1016/j.watres.2003.11.014
56. Jokai, Z., Hegoczki, J. and Fodor, P.: 1998, 'Stability and optimization of extraction of four arsenic species', Microchem. J. 59(1), 117-124. 10.1006/mchj.1998.1571
57. Jurica, L., Manova, A., Dzurov, J., Beinrohr, E. and Broekaert, J. A. C.: 2000, 'Calibrationless flow-through stripping coulometric determination of arsenic(III) and total arsenic in contaminated water samples after microwave assisted reduction of arsenic(V)', Fresenius J. Anal. Chem. 366(3), 260-266. 10.1007/s002160050051
58. A. Kabata-Pendias B. Szteke 1998 'Quality Problems in Trace Analysis in Environmental Studies' Wydawnictwa Edukacyjne, Warsaw, Poland
59. Klaue, B. and Blum, J. D.: 1999, 'Trace analyses of arsenic in drinking water by inductively coupled plasma mass spectrometry: High versus hydride generation', Anal. Chem. 71(7) 1408-1414. 10.1021/ac980846+
60. Kim, M. J.: 2001, 'Separation of inorganic arsenic species in groundwater using ion exchange method', Bull. Environ. Contam. Toxicol. 67(1), 46-51. 11381311
61. Kim, M. J., Nriagu, J. and Haack, S.: 2002, 'Arsenic species and chemistry in groundwater of southeast Michigan', Environ. Pollut. 120, 379-390. 10.1016/S0269-7491(02)00114-8
62. Kuhn, A. and Sigg, L.: 1993, 'Arsenic cycling in eutrophic Lake Greifen, Switzerland - Infuence of seasonal redox processes', Limnol. Oceanogr. 38, 1052-1059.
63. Lamble, K. J., Sperling, M. and Welz, B.: 1996, 'Arsenic speciation in biological samples by on-line high performance liquid chromatography-microwave digestion-hydride generation-atomic absorption spectrometry', Anal. Chim. Acta 334(3), 261-270. 10.1016/ S0003-2670(96)00348-0
64. Larsen, E. H.: 1998, 'Method optimization and quality assurance in speciation analysis using high performance liquid chromatography with detection by inductively coupled plasma mass spectrometry', Spectrochim. Acta. Part B: Atom. Spectro. 53(2), 253. 10.1016/S0584-8547(97)00137-7
65. Le, X. C., Cullen, W. R. and Reimer, K. J.: 1994, 'Speciation of arsenic compounds by HPLC with hydride generation atomic absorption spectrometry and induced coupled plasma mass spectrometry detection', Talanta 41, 495-502. 10.1016/0039-9140(93)E0012-3
66. Le, X. C., Li, X. F., Lai, V., Ma, M., Yalcin, S. and Feldmann, J.: 1998, 'Simultaneous speciation of selenium and arsenic using elevated temperature liquid chromatography separation with inductively coupled plasma mass spectrometry detection', Spectrochim. Acta B 53 (6-8), 899-909. 10.1016/S0584-8547(98)00105-0
67. Le, X. C. and Ma, M.: 1998, 'Short-column liquid chromatography with hydride generation atomic fluorescence detection for the speciation of arsenic', Anal. Chem. 70(9), 1926-1933. 10.1021/ac971247q
68. Le, X. C., Yalcin, S. and Ma, M.: 2000, 'Speciation of submicrogram per liter levels of arsenic in water on-site species separation integrated with sample collection', Environ. Sci. Technol. 34, 2342-2347. 10.1021/ es991203u
69. Li, Z. L., Mou, S., Ni, Z. and Riviello, J. M.: 1995, 'Sequential determination of arsenic and arsenate by ion chromatography', Anal. Chim. Acta 307, 79-87. 10.1016/0003-2670(95)00030-4
70. Lindemann, T., Prange, A., Dannecker, W. and Neidhart. B.: 2000, 'Stability studies of arsenic, selenium, antimony and tellurium species in water, urine, fish and soil extracts using HPLC/ICP-MS', Fresenius J. Anal. Chem. 368(2-3), 214-220. 10.1007/s002160000475
71. Lobiniski, R. and Adams, F.: 1993, 'Recent advances in speciation analysis by capillary gas chromatography microwave induced plasma atomic emission spectrometry', Trends Anal. Chem. 12, 41-49. 10.1016/ 0165-9936(93)87050-8
72. Lopez, M. A., Gomez, M. M., Placio, M. A. and Camara, C.: 1993, 'Determination of six arsenic species by high performance liquid chromatography-hydride generation atomic absorption spectrometry with on-line thermoxidation', Fresenius J. Anal. Chem. 346, 643-647. 10.1007/ BF00321263
73. Maity, S., Chakravarty, S., Thakur, P., Gupta, K. K., Bhattacharjee, S. and Roy, B. C.: 2004, 'Evaluation and standardisation of a simple HG-AAS method for rapid speciation of As(III) and As(V) in some contaminated groundwater samples of West Bengal, India', Chemosphere 54, 1199-1206. 10.1016/j.chemosphere.2003.09.035
74. Mandal, B. K., Kazno, T. and Suzuki K. T.: 2002, 'Arsenic round the world: A review', Talanta 58, 201-235. 10.1016/S0039-9140(02)00268-0
75. Mandal, B. K., Ogra, Y. and Suzuki, K. T.: 2001, 'Identification of dimethylarsinous and monomethylarsonous acids in human urine of the arsenic-affected areas in West Bengal, India', Chem. Res. Toxicol. 14, 371-375. 10.1021/tx000246h
76. Martinez-Bravo, Y., Roig-Navarro, A. F., Lopez, F. J. and Hernandez, F.: 2001, 'Multielemental determination of arsenic, selenium and chromium(IV) species in water by high-performance liquid chromatography inductively coupled plasma mass spectrometry', J. Chromatogr. A 926(2), 265-724. 10.1016/S0021-9673(01)01062-7
77. Martin, I., Lopez-Gonzalvez, M. A., Gomez, M., Camara, C. and Palacios, M. A.: 1995, 'Evaluation of high-performance liquid chromatography for the separation and determination of arsenic species by on-line high-performance liquid chromatographic-hydride generation-atomic absorption spectrometry', J. Chromatogr. B: Biomed. Appl. 666(1), 101-109. 10.1016/0378-4347(94)00567-O
78. McCleskey, R. B., Nordstrom, D. K. and Maest, A. S.: 2004, 'Preservation of water samples for arsenic(III/V) determinations: An evaluation of literature and new analytical results', Appl. Geochem. 19, 995-1009. 10.1016/j.apgeochem.2004.01.003
79. McSheehy, S., Pohl, R., Lobinski, R. and Szpunar, J.: 2001, 'Complementarity of multidimensional HPLC-ICP-MS and electrospray MS-MS for speciation analysis of arsenic in algae', Anal. Chim. Acta 440, 3-15. 10.1016/S0003-2670(01)00906-0
80. McSheehy, S., Pohl, P., Lobinski, R. and Szpunar, J.: 2001, 'Investigation of arsenic speciation in oyster test reference material by multidimensional HPLC-ICP-MS and electrospray tandem mass spectrometry (ES-MS-MS)', Analyst 126(7), 1055-1062. 10.1039/b102225n
81. Mester, Z., Woller, A. and Fodor, P.: 1996, 'Determination of arsenic species by high-performance liquid chromatography-hydride generation-(ultrasonic nebulizer)-atomic fluorescence spectrometry', Microchem. J. 54(3), 184-194. 10.1006/mchj.1996.0094
82. Michalke, B. and Schramel, P.: 1998, 'Capillary electrophoresis interfaced to inductively coupled plasma mass spectrometry for element selective detection in arsenic speciation', Electrophoresis 19 (12), 2220-2225. 10.1002/elps.1150191229
83. Miller, G. P., Norman, D. L. and Frisch, P. L.: 2000, 'A coment on arsenic species sepatation using ion exchange', Water Res. 34(4), 1397-1400. 10.1016/S0043-1354(99)00257-2
84. Milstein, L. S., Essader, A., Pellizzari, E. D., Fernando, R. A. and Kiubo, O.A.: 2002, 'Selection of a suitable mobile phase for the speciation of four arsenic compounds in drinking water samples using ion-exchange chromatography coupled to inductively coupled plasma mass spectrometry', Environ. Int. 28, 277-283. 10.1016/S0160-4120(02)00035-1
85. Moldovan, M., Gomez, M. M., Palacios, M. A. and Camara, C.: 1998, 'Arsenic speciation in water and human urine by HPLC-ICP-MS and HPLC-MO-HG-AAS', Microchem. J. 59(1), 89-99. 10.1006/mchj.1997.1556
86. Montes-Bayon, M., DeNicola, K. and Caruso, J. A.: 2003, 'Liquid chromatography-inductively coupled plasma mass spectrometry', J. Chromatogr. A 1000, 457-476. 10.1016/S0021-9673(03)00527-2
87. Morita, M. and Edmonds, J. S.: 1992, 'Determination of arsenic in environmental and biological samples', Pure Appl. Chem. 64, 575-590.
88. Munoz, O., Velez, D. and Montoro, R.: 1999, 'Optimization of the solubilization, extraction and determination of inorganic arsenic [As(III) + As(V)] in seafood products by acid digestion, solvent extraction and hydride generation atomic absorption spectrometry', Analyst 124(4), 601-607. 10.1039/a809426h
89. Nakazato, T., Tao, H., Taniguchi, T. and Isshiki, K.: 2002, 'Determination of arsenite, arsenate and monomethylarsonic acid in seawater by ion-exclusion chromatography combined with inductively coupled plasma mass spectometry using reaction cell and hydride generation technique', Talanta 58(1), 121-132. 10.1016/ S0039-9140(02)00261-8
90. National Research Council Arsenic in Drinking Water: 1999, National Academy Press, Washington, DC.
91. Neff, J. M.: 1997, 'Ecotoxicology of arsenic in the marine environment', Environ. Toxicol. Chem. 16, 917-927. 10.1897/ 1551-5028(1997)016<0917:EOAITM>2.3.CO;2
92. Niedzielski, P.: 2002, 'Analiza specjacyjna arsenu antymonu i selenu technika generowania wodorków', Analityka 4, 4-7.
93. Niedzielski, P.: 2002, 'Arsen, antymon i selen jako mikroskładniki wód', LAB 5, 34-38.
94. Niedzielski, P.: 2003, 'Źródła błȩdów w technice generowania wodorków', LAB 1, 18.
95. Palacios, M. A., Gomez, M., Camara, C. and Lopez, M. A.: 1997, 'Stability studies of arsenate, monomethylarsonate, dimethylarsinate, arsenobetaine and arsenocholine in deionized water, urine and clean-up dry residue from urine samples and determination by liquid chromatography with microwave-assisted oxidation-hydride generation atomic absorption spectrometric detection', Anal. Chim. Acta 340 (1-3), 209-220. 10.1016/S0003-2670(96)00525-9
96. Pedersen, S. N. and Francesconi, K. A.: 2000, 'Liquid chromatography electrospray mass spectrometry with variable fragmentor voltages gives simultaneous elemental and molecular detection of arsenic compounds', Rapid Commun. Mass Spectrom. 14(8), 641-645. 10.1002/ (SICI)1097-0231(20000430)14:8<641::AID-RCM923>3.0.CO;2-V
97. Peterson, M. L. and Carpenter, R.: 1983, 'Biogeochemical processes affecting total arsenic and arsenic species distributions in an intermittently anoxic Fjord', Mar. Chem. 12, 295-321. 10.1016/ 0304-4203(83)90058-0
98. Pettine, M., Camusso, M. and Martinotti, W.: 1992, 'Dissolved and particulate transport of arsenic and chromium in the Po River, Italy', Sci. Total Environ. 119, 253-280. 10.1016/0048-9697(92)90268-W
99. Pohl, P.: 2004, 'Hydride generation - Recent advances in atomic emission spectrometry', Trends Anal. Chem. 23(2), 87-101. 10.1016/ S0165-9936(04)00306-1
100. Pohl, P. and Prusisz, B.: 2004, 'Ion-exchange column chromatography - An attempt to speciate arsenic', Trends Anal. Chem. 23(1), 63-69. 10.1016/ S0165-9936(04)00108-6
101. Pohl, P. and Szpunar, J.: 2001, 'Techniki sprzȩżone w analizie specjacyjnej' LAB 4, 13-15.
102. Prange, A., Pepelnik, R. and Leonhard, P.: 2001, Proceedings of the Agilent 7500c ICP-MS Seminar, Yokogawa Analytical Systems Inc., Japan, p. 1.
103. Prest, J. E., Baldock, S. J., Fielden, P. R., Goddard, N. J. and Treves Brown, B. J.: 2003, 'Miniaturised isotachophoretic analysis of inorganic arsenic speciation using a planar polymer chip with integrated conductivity detection', J. Chromatogr. A 990, 325-334. 10.1016/ S0021-9673(02)01968-4
104. Raessler, M., Michalke, B., Schramel, P., Schulte-Hostede, S. and Kettrup, A.: 1998, 'The capability of ultrafiltration of arsenic and selenium species in ground water samples with high concentrations of iron, manganese and sulfur', Fresenius J. Anal. Chem. 362, 281-284. 10.1007/s002160051074
105. Raessler, M., Michalke, B., Schulte-Hostede, S. and Kettrup, A.: 2000, 'Long-term monitoring of arsenic and selenium species in contaminated groundwater by HPLC and HG-AAS', Sci. Total Environ. 258(3), 171-181. 10.1016/S0048-9697(00)00535-0
106. Raposo, J. C., Sanz, J., Zuloaga, O., Olazabal, A. and Madariaga, J. M.: 2004, 'Validation of the thermodynamic model of inorganic arsenic in non polluted river waters of the Basque country (Spain)', Talanta 63, 683-690. 10.1016/j.talanta.2003.12.021
107. Rauret, G., Rubio, R. and Padro, A.: 1991, 'Arsenic speciation using HPLC hydride generation ICP AES with gas liquid separator', Fresenius J. Anal. Chem. 340, 157-160. 10.1007/BF00324472
108. Riedel, G. F.: 1993, 'The annual cycle of arsenic in a temperate estuary', Estuaries 16, 533-540.
109. Roig-Navarro, A. F., Martinez-Bravo, Y., Lopez, F. J. and Hernandez, F.: 2001, 'Simultaneous determination of arsenic species and chromium(V) by high-performance liquid chromatography-inductively coupled plasma-mass spectrometry', J. Chromatogr. A 912(2), 319-327. 10.1016/ S0021-9673(01)00572-6
110. Rosen, A. L. and Hieftje, G. M.: 2004, 'Inductively coupled plasma mass spectrometry and electrospray mass spectrometry for speciation analysis: Applications and instrumentation', Spectrochim. Acta. Part B 59, 135-146. 10.1016/j.sab.2003.09.004
111. Rozporza̧dzenie Ministra Zdrowia z dnia 19 listopada.: 2002r. w sprawie wymagań dotycza̧cych jakości wody przeznaczonej do spożycia przez ludzi.
112. Rupasinghe, T., Cardwell, T. J., Cattrall, R. W., Potter, I. and Kolev, S. D.: 2004, 'Determination of arsenic by pervaporation-flow injection hydride generation and permanganate spectrophotometric detection', Anal. Chim. Acta 510, 225-230. 10.1016/j.aca.2004.01.006
113. Russeva, E.: 1995, 'Speciation analysis, specularities and requirements', Anal. Lab. 4(3), 143-148.
114. Saeki, K., Sakakibara, H., Sakai, H., Kunito, T. and Tanabe, S.: 2000, 'Arsenic accumulation in three species of sea turtles', Biometals 13(3), 241-250. 10.1023/A:1009266520680
115. Scott, D. L., Ramanathan, S., Shi, W., Rosen, B. P. and Daunert, S.: 1997, 'Genetically engineered bacteria: Electrochemical sensing systems for antimonite and arsenite', Anal. Chem. 69(1), 16-20. 10.1021/ac960788x
116. Segal, A., Gorecki, T., Mussche, P., Lips, J. and Pawliszyn, J.: 2000, 'Development of membrane extraction with a sorbent interface-micro gas chromatography system for field analysis', J. Chromatogr. A 873(1), 13-27. 10.1016/S0021-9673(99)01318-7
117. Seyler, P. and Martin, J. M.: 1990, 'Distribution of arsenite and total dissolved arsenic in major French estuaries: Dependence on biogeochemical processes and anthropogenic inputs', Mar. Chem. 29, 277-294. 10.1016/0304-4203(90)90018-8
118. Sheppared, B. S., Caruso, J. A., Heitkemper, D. T. and Wolnik, K. A.: 1992, 'Arsenic speciation by ion chromatography with induced coupled plasma mass spectrometry detection', Analyst 117, 971-975. 10.1039/ an9921700971
119. Shraim, A., Chiswell, B. and Olszowy, H.: 2000, 'Use of perchloric acid as a reaction medium for speciation of arsenic by hydride generation-atomic absorption spectrometry', Analyst 125(5), 949-953. 10.1039/a907103b
120. Shum, S., Nedderson, R. and Houk, R.S.: 1992, 'Elemental speciation by liquid chromatography induced coupled plasma spectrometry with direct injection nebulization', Analyst 117, 577-582. 10.1039/an9921700577
121. Sima, J., Rychlovsky, P. and Dedina, J.: 2004, 'The efficiency of the electrochemical generation of volatile hydrides studied by radiometry and atomic absorption spectrometry', Spectrochim. Acta. Part B 59, 125-133. 10.1016/j.sab.2003.11.005
122. Simon, S., Tran, H., Pannier, F. and Potin-Gautier, M.: 2004, 'Simultaneous determination of twelve inorganic and organic arsenic compounds by liquid chromatography-ultraviolet irradiation-hydride generation atomic fluorescence spectrometry' J. Chromatogr. A 1024, 105-113. 10.1016/j.chroma.2003.09.068
123. Slejkovec, Z., van Elteren, J. and Byrne, A. R.: 1998, 'A dual arsenic speciation system combining liquid chromatographic and purge and trap-gas chromatographic separation with atomic fluorescence spectrometric detection', Anal. Chim. Acta 358(1), 51-60. 10.1016/ S0003-2670(97)00582-5
124. Slejkovec, Z., van Elteren, J. and Woroniecka. U. D.: 2001, 'Underestimation of the total arsenic concentration by hydride generation techniques as a consequence of the incomplete mineralization of arsenobetaine in acid digestion procedures', Anal. Chim. Acta 443, 277-282. 10.1016/S0003-2670(01)01223-5
125. P. L. Smedley W. M. Edmunds K. B. Peling-Ba J. D. Appleton R. Fuge G. J. H. McCall 1996 'Mobility of Arsenic in Groundwater in the Obuasi Area of Ghana', in: Environmental Geochemistry and Health, Vol. 113 Geological Society Special Publication London, pp. 163-181
126. Smedley, P. L. and Kinniburgh, D. G.: 2002, 'A review of the source, behaviour and distribution of arsenic in natural waters', Appl. Geochem. 17, 517-568. 10.1016/S0883-2927(02)00018-5
127. P. L. Smedley D. G. Kinniburgh I. Huq Z. Luo H. B. Nicolli 2001 'International Perspective on Naturally Occurring Arsenic Problems in Groundwater', in: W. R. Chappell C. O. Abernathy R. L. Calderon (eds), Arsenic Exposure and Health Effects, vol. IV Elsevier Amsterdam pp. 9-25
128. P. L. Smedley M. Zhang G. Zhang Z. Luo 2001 'Arsenic and Other Redox-sensitive Elements in Groundwater from the Huhhot Basin, Inner Mongolia' in: R. Cidu (ed), Water-Rock Interaction, Vol. 1 Swets & Zeitlinger, Lisse pp. 581-584
129. Sun, B., Macka, M. and Haddad, P. R.: 2004, 'Speciation of arsenic and selenium by capillary electrophoresis', J. Chromatogr. A 1039, 201-208. 10.1016/j.chroma.2004.03.045
130. Taniguchi, T., Tao, H., Tominaga, M. and Miyazaki, A.: 1999, 'Sensitive determination of three arsenic species in water by ion exclusion chromatography-hydride generation-inductively coupled plasma mass spectrometry', J. Anal. Atom. Spectrom. 14, 651-655. 10.1039/a809606f
131. Timerbaev, A. R.: 2000, 'Elemental speciation analysis by capillary electrophoresis', Talanta 52(4), 573-606. 10.1016/S0039-9140(00)00364-7
132. Timerbaev, A. R.: 2001, 'Elemental speciation analysis by capillary electrophoresis: What are the hints on becoming a standard analytical methodology?', Anal. Chim. Acta 433(2), 165-180. 10.1016/ S0003-2670(01)00788-7
133. Tomlinson, M. J., Lin, L. and Caruso, J. A.: 1995, 'Plasma mass spectrometry as a detector for chemical speciation studies', Analyst 120(3), 583-589. 10.1039/an9952000583
134. Tsalev, D. L., Sperling, M. and Welz, B.: 2000, 'Flow-injection hydride generation atomic absorption spectrometric study of the automated on-line pre-reduction of arsenate, methylarsonate and dimethylarsinate and high-performance liquid chromatographic separation of their L-cysteine complexes', Talanta 51(6), 1059-1068. 10.1016/ S0039-9140(00)00297-6
135. United Nations Syntesis Report on Arsenic in Drinking Water: 2001.
136. Van Elteren, J. T. Stibilj, V. and Slejkovec, Z.: 2002, 'Speciation of inorganic arsenic in some bottled Slovene mineral waters using HPLC-HGAFS and selective coprecipitation combined with FI-HGAFS' Water Res. 36(12), 2967-2974. 10.1016/S0043-1354(01)00527-9
137. Van Holderbeke, M., Zhao, Y., Vanhaecke, F., Moens. L., Dams, R. and Sandra, P.: 1999, 'Speciation of six arsenic compounds using capillary electrophoresis inductively coupled plasma mass spectrometry', J. Anal. Atom. Spectrom. 14, 229-234. 10.1039/a807480a
138. Velitchkova, N., Pentcheva, E. N. and Daskalowa, N.: 2004, 'Determination of arsenic, mercury, selenium, thallium, tin and bismuth in environmental materials by inductively coupled plasma emission spectrometry', Spectrochim. Acta. Part B 59, 871-882. 10.1016/ j.sab.2004.03.004
139. Vilano, M., Padro, A. and Rubio, R.: 2000, 'Coupled techniques based on liquid chromatography and atomic fluorescence detection for arsenic speciation', Anal. Chim. Acta 411, 71-139. 10.1016/S0003-2670(00)00712-1
140. Weber, G.: 1993, 'Investigation of the stability of metal species with respect to liquid chromatographic separations', Fresenius J. Anal. Chem. 346, 639-642. 10.1007/BF00321262
141. Weeger, W., Lievremont, D., Perret, M., Lagarde, F., Hubert, J. C., Leroy, M. and Lett, M. C.: 1999, 'Oxidation of arsenite to arsenate by a bacterium isolated from an aquatic environment', Biometals 12(2), 141-149. 10.1023/A:1009255012328
142. WHO Arsenic Compounds: 2001, Environmental Criteria, Vol. 224, 2nd ed., World Health Organisation, Geneva.
143. Welch, A. H., Westjohn, D. B., Helsel, D. R. and Wanty, R. B.: 2000, 'Arsenic in ground water of the United States: Occurance and geochemistry', Ground Water 38, 589-604. 10.1111/ j.1745-6584.2000.tb00251.x
144. Yan, X. P., Kerrich, R. and Hendry, M. J.: 2000, 'Distribution of arsenic(III), arsenic(V) and total inorganic arsenic in porewaters from a thick till and clay-rich aquitard sequence, Saskatchewan, Canada', Geochim. Cosmochim. Acta 64, 2637-2648. 10.1016/S0016-7037(00)00380-X
145. Yan, X. P., Yin, X. B., He, X. W. and Jiang, Y.: 2002, 'Flow injection on-line sorption preconcentration coupled with hydride generation atomic fluorescence spectrometry for determination of (ultra)trace amounds of arsenic(III) and arsenic(V) in natural water samples', Anal. Chem. 74(9), 2162-2166. 10.1021/ac0157019
146. Zhang, Q., Minami, H., Inoue, S. and Atsuya, I.: 2001, 'Preconcentration by coprecipitation of arsenic and tin in natural waters with a Ni-pyrrolidine dithiocarbamate complex and their direct determination by solid-sampling atomic-absorption spectrometry', Fresenius J. Anal. Chem. 370(7), 860-864. 10.1007/s002160100857
147. Zhang, Q., Minami, H., Inoue, S. and Atsuya, I.: 2004, 'Differential determination of trace amounts of arsenic(III) and arsenic(V) in seawater by solid sampling atomic absorption spectrometry after preconcentration by coprecipitation with a nickel-pyrrolidine dithiocarbamate complex', Anal. Chim. Acta 508, 99-105. 10.1016/ j.aca.2003.11.053
148. Zhang, P., Xu, G., Xiong, J., Zheng, Y., Yang, O. and Wei, F.: 2001, 'Determination of arsenic species by capillary zone electrophoresis with large-volume field-amplified stacking injection', Electrophoresis