Catalytic capabilities of lipase immobilized into organically modified silicates by sol-gel method

Kagaku Kogaku Ronbunshu

Volumn 26, Issue 6, 2000, Pages 885-886

  Furukawa, Shin Ya ^a   Ono, Tsutomu ^a   Ijima, Hiroyuki ^a   Kawakami, Koei ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

Enantioselective esterification; Lipase; Menthol; Organic inorganic hybrid silicate; Sol gel method

Indexed keywords

EID: 24044443656     PISSN: 0386216X     EISSN: None     Source Type: Journal    
DOI: 10.1252/kakoronbunshu.26.882     Document Type: Article

References (13)

1. Avnir, D., S. Braun, O. Lev and M. Ottolenghi ; "Enzyme and Other Proteins Entrapped in Sol-Gel Materials," Chem. Mater., 6, 1605-1614 (1994)
2. Brzozowski, A. M., U. Derewenda, Z. S. Derewenda, Z. S. Dodson, D. M. Lawson, F. Turkenburg, F. Bjorkling, B. Huge-Jensen, S. A. Patkar and L. Thim; "A Model of Interfacial Activation in Lipases from the Structure of a Fungal Lipase-Inhibitor Complex," Nature, 351, 491-494 (1991)
3. Fitzpatrick, P. A. and A. M. Klibanov; "How Can the Solvent Affect Enzyme Enantioselectivity?," J. Am. Chem. Soc., 113, 3166-3171 (1991)
4. Furukawa, S. and K. Kawakami ; "Characterization of Candida rugosa Lipase Entrapped into Organically Modified Silicate in Esterification of Menthol with Butyric Acid," J. Ferment. Bioeng., 85, 240-242 (1998)
5. Grochulski, P., Y. Li, J. D. Schrag, F. Bouthillier, P. Smith, D. Harrison, B. Rubin and M. Cygler ; "Insights into Interfacial Activation from an Open Structure of Candida rugosa Lipase," J. Biol. Chem., 268, 12843-12847 (1993)
6. Heichal-Segal, O., S. Rappoport and S. Braun ; "Immobilization in Alginate-Silicate Sol-Gel Matrix Protects β-Glucosidase Against Thermal and Chemical Denaturation," Biotechnology, 13, 798-800 (1995)
7. Janssen, A. E. M., M. Vaidya and P. J. Halling ; "Substrate Specificity and Kinetics of Candida rugosa Lipase in Organic Media," Enzyme Microb. Technol., 18, 340-346 (1996)
8. Kawakami, K. and S. Yoshida ; "Thermal Stabilization of Lipase by Sol-Gel Entrapment in Organically Modified Silicate Formed on Kiselguhr," J. Fermentt. Bioeng., 82, 239-245 (1996)
9. Kawakami, K. and S. Furukawa ; "Alcohol-Oxidation Activity of Whole Cells of Pichia pastoris Entrapped in Hybrid Gels Composed of Ca-Alginate and Organic Silicate," Appl. Biochem. Biotechnol., 67, 23-31 (1997)
10. Peterson, K. P., C. M. Peterson and E. A. Pope ; "Silica Sol-Gel Encapsulation of Pancreatic Islets," Proceedings of the Society for Experimental Biology and Medicine, 218, 365-369 (1998)
11. Pope, E. A., K. P. Braun and C. M. Peterson ; "Silica Gel Encapsulated Pancreatic Islets for the Treatment of Diabetes," J. Sol-Gel Sci. Technol., 8, 635-639 (1997)
12. Reetz, M. T. ; "Entrapment of Biocatalysts in Hydrophobic Sol-Gel Materials for Use in Organic Chemistry," Adv. Mater., 9, 943-954 (1997)
13. Verger, R. ; "Interfacial Activation of Lipases : Facts and Artifacts," TIBTECH, 15, 32-38 (1997)