Geminate charge recombination with distance-dependent intrinsic reaction rate: Escape probability and its electric field effect

Radiation Physics and Chemistry

Volumn 74, Issue 3-4, 2005, Pages 132-138

  Wojcik, Mariusz ^a   Tachiya, M ^b  

^a LODZ UNIVERSITY OF TECHNOLOGY   (Poland)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CHARGE; PARTIAL DIFFERENTIAL EQUATIONS; PROBABILITY; RATE CONSTANTS;

CHARGE RECOMBINATION; ELECTRIC FIELD DEPENDENCE; FINITE-REACTIVITY; INTRINSIC REACTION RATE;

ELECTRIC FIELD EFFECTS;

ANALYTIC METHOD; ARTICLE; CALCULATION; DATA ANALYSIS; ELECTRIC FIELD; ELECTRICITY; EXPERIMENT; MATHEMATICAL ANALYSIS; PROBABILITY; REACTION ANALYSIS;

EID: 23944463428     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2005.04.005     Document Type: Article

References (17)

1. G.C. Abell, and K. Funabashi The simple exponential distribution for initial electron-positive ion separation distances as seen in the γ radiolysis of alkanes J. Chem. Phys. 58 3 1973 1079 1085
2. S. Barth, and H. Bässler Intrinsic photoconduction in PPV-type conjugated polymers Phys. Rev. Lett. 79 22 1997 4445 4448
3. F.C. Collins, and G.E. Kimball Diffusion-controlled reaction rates J. Colloid. Sci. 4 1949 425 437
4. G.R. Freeman Ionization and charge separation in irradiated materials G.R. Freeman Kinetics of Nonhomogeneous Processes 1987 Wiley New York 19 87
5. T.E. Goliber, and J.H. Perlstein Analysis of photogeneration in a doped polymer system in terms of a kinetic model for electric-field assisted dissociation of charge-transfer states J. Chem. Phys. 80 9 1984 4162 4167
6. D. Hertel, E.V. Soh, H. Bässler, and L.J. Rothberg Electric field dependent generation of geminate electron-hole pairs in a ladder-type π-conjugated polymer probed by fluorescence quenching and delayed field collection of charge carriers Chem. Phys. Lett. 361 1-2 2002 99 105
7. K.M. Hong, and J. Noolandi Solution of the time-dependent Onsager problem J. Chem. Phys. 69 11 1978 5026 5039
8. R.A. Marcus Chemical and electrochemical electron-transfer theory Ann. Rev. Phys. Chem. 15 1964 155 196
9. A. Mozumder Effect of an external electric field on the yield of free ions I General results from the Onsager theory. J. Chem. Phys. 60 11 1974 4300 4304
10. L. Onsager Initial recombination of ions Phys. Rev. 54 8 1938 554 557
11. J. Pan, U. Scherf, A. Schreiber, and D. Haarer Xerographic study on a ladder-type poly(para-phenylene) J. Chem. Phys. 112 9 2000 4305 4309
12. Z.D. Popovic, and E.R. Menzel Electric field-induced fluorescence quenching in organic photoconductors J. Chem. Phys. 71 12 1979 5090 5096
13. W.H. Press, S.A. Teukolsky, W.T. Vetterlink, and B.P. Flannery Numerical Recipes in Fortran second ed 1994 Cambridge University Press Cambridge
14. W. Que, and J.A. Rowlands X-ray photogeneration in amorphous selenium: geminate versus columnar recombination Phys. Rev. B 51 16 1995 10500 10507
15. H. Sano, and M. Tachiya Partially diffusion-controlled recombination J. Chem. Phys. 71 3 1979 1276 1282
16. M. Tachiya General method for calculating the escape probability in diffusion-controlled reactions J. Chem. Phys. 69 6 1978 2375 2376
17. M. Tachiya Theory of diffusion-controlled reactions: formulation of the bulk rate constant in terms of the pair probability Radiat. Phys. Chem. 21 1,2 1983 167 175