Spinel crystallization in HLW glass melts: Cation exchange systematics and the role of Rh 2O 3 in spinel formation

Ceramic Transactions

Volumn 155, Issue , 2004, Pages 279-288

  Annamalai, Sezhian ^a   Gan, Hao ^a   Chaudhuri, Malabika ^a   Kot, Wing K ^a   Pegg, Ian L ^a  

^a CATHOLIC UNIVERSITY OF AMERICA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GLASS MELTS; LIQUIDUS PHASES; SPINEL PHASERS; WASTE LOADINGS;

CRYSTALLIZATION; GLASS MANUFACTURE; HEAT TRANSFER; ION EXCHANGE; RADIOACTIVE WASTE VITRIFICATION; VOLUME FRACTION;

RADIOACTIVE WASTES;

EID: 23744510263     PISSN: 10421122     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Conference Paper

References (7)

1. W. K. Kot and I. L. Pegg, "Glass Formulation and Testing with RPP-WTP HLW Simulants," Final Report, VSL-01R2540-2, Rev. 0, Vitreous State Laboratory, The Catholic University of America, Washington, D.C., February 16, 2001.
2. S.S. Fu and I.L. Pegg, "Glass Formulation and Testing with TWRS HLW Simulants," Final Report, Vitreous State Laboratory, The Catholic University of America, Washington, DC, January 1998.
3. W. A. Deer, R. A. Howie, and J. Zussman, "An Introduction to the Rock-Forming Minerals," Longman (1992).
4. J.D. Vienna, P. Hrma, J.V. Crum, M. Mika, "Liquidus Temperature-Composition Model for Multi-Component Glasses in the Fe, Cr, Ni, and Mn Spinel Primary Phase Field," J. Non-Cryst. Solids 292 1-24 (2001).
5. R.J. Hill, J.R. Craig, and G.V. Gibbs, "Systematics of the Spinel Structure Type," Phys. Chem. Minerals 4, 317-339 (1979).
6. C. J. Capobianco and M.J. Drake, "Partitioning of Ru, Rh, and Pd Between Spinel and Silicate Melt and Implications for Platinum Group Element Fractionation Trends," Geochim. Cosmochim. Acta, 54, 869-874 (1990).
7. C.J. Capobianco R.L. Hervig and M.J. Drake, "Experiments on Crystal/Liquid Partitioning of Ru, Rh, and Pd for Magnetite and Hematite Solid Solutions Crystallized from Silicate Melt," Chemical Geology, 113, 23-43, (1994).