Exploring uncharted terrain in nature's structure space using capillary NMR spectroscopy: 13 Steroids from 50 fireflies

Journal of the American Chemical Society

Volumn 127, Issue 31, 2005, Pages 10810-10811

  Gronquist, Matthew ^a   Meinwald, Jerrold ^b   Eisner, Thomas ^b   Schroeder, Frank C ^b  

^a STATE UNIVERSITY OF NEW YORK   (United States)

^b Department of Molecular Biology and Genetics   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LUCIBUFAGIN; NATURAL PRODUCT; PYRONE DERIVATIVE; STEROID; SUCROSE; UNCLASSIFIED DRUG;

ARTHROPOD; ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; HEMOLYMPH; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LUCIDOTA ATRA; MAGNETIC FIELD; NONHUMAN; NUCLEAR OVERHAUSER EFFECT; PREDATOR; PROTON NUCLEAR MAGNETIC RESONANCE; SIGNAL NOISE RATIO; STRUCTURE ANALYSIS;

ANIMALS; BEETLES; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; MAGNETIC RESONANCE SPECTROSCOPY; STEROIDS;

EID: 23744504882     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja053617v     Document Type: Article

References (9)

1. Taggi, A. E.; Meinwald, J.; Schroeder, F. C. J. Am. Chem. Soc. 2004, 126, 10364-10369.
2. (a) Olson, D. L.; Peck T. L.; Webb, A. G.; Magin, R. L.; Sweedler, J. V. Science 1995, 270, 1967-1970.
3. (b) Subramanian, R.; Lam, M. M.; Webb, A. G. J. Magn. Reson. 1998, 133, 227-231.
4. (c) Subramanian, R.; Sweedler, J. V.; Webb, A. G. J. Am. Chem. Soc. 1999, 121, 1, 2333-2334.
5. (a) Meinwald, J.; Wiemer, D. F.; Eisner, T. J. Am. Chem. Soc. 1979, 101, 1, 3055-3060.
6. (b) Steyn, P. S.; van Heerden, F. R. Nat. Prod. Rep. 1998, 397-413.
7. Eldridge, G. R.; Vervoort, H. C.; Lee, C. M.; Cremin, P. A.; Williams, C. T.; Hart, S. M.; Goering, M. G.; O'Neil-Johnson, M.; Zeng, L. Anal. Chem. 2002, 74, 3963-3971.
8. For a comparison of CapNMR and 5 mm HCN probe with Shigemi tube using a 17.2 μg sucrose sample, see Supporting Information.
9. For a detailed description of sample preparation for CapNMR analysis, see Supporting Information.