Synthesis of a Silene from 1,1-Dilithiosilole and 2-Adamantanone

Journal of the American Chemical Society

Volumn 126, Issue 17, 2004, Pages 5336-5337

  Toulokhonova, Irina S ^a   Guzei, Ilia A ^a   West, Robert ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,1 DILITHIOSILOLE; 2 ADAMANTANONE DERIVATIVE; SILENE DERIVATIVE; SILICONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; MOLECULAR INTERACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 2342627230     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0318176     Document Type: Article

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13. 29Si. Reaction mixtures were purified by column and thin-layer chromatography using silica gel 60 Geduran from EM Science and silica gel GF (uniplate 1500 mm) from Analtech.
14. 3, R(F) = 4.34% for 5801 [R(int) = 0.0310] independent reflections (1.80 ≤ θ 26.39°).
15. 3, R(F) = 5.15% for 7220 (R(int) = 0.0310] independent reflections (2.06 ≤ θ ≤ 26.38°).
16. 3, R(F) = 8.49% for 10989 [R(int) = 0.0598] independent reflections (1.12 ≤ θ ≤ 24.00°).
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