Origin of facial diastereoselection in 2-adamantyl cations. Theoretical evidence against the Felkin-Anh and the Cieplak models

Tetrahedron Letters

Volumn 45, Issue 23, 2004, Pages 4559-4562

  Kaneno, Daisuke ^a   Tomoda, Shuji ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Ab initio molecular calculation; Adamantyl cation; Cieplak model; Facial diastereoselectivity; Felkin Anh model

Indexed keywords

ADAMANTANE DERIVATIVE; CARBON; CATION; CHLORINE DERIVATIVE; METHANOL;

CHEMICAL BOND; CONFERENCE PAPER; CONFORMATION; EQUILIBRIUM CONSTANT; MOLECULAR STABILITY; PHASE TRANSITION; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; STEREOCHEMISTRY; THEORETICAL MODEL;

EID: 2342471812     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.04.036     Document Type: Conference Paper

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