The Solvent-initiated Photolysis of Dichloro(2,2′ -bipyridine)platinum(II) in Chloroform

Photochemistry and Photobiology

Volumn 79, Issue 4, 2004, Pages 356-359

  Whang, Sharon ^a   Estrada, Toño ^a   Hoggard, Patrick E ^a  

^a SANTA CLARA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CHLORINE; CHLOROFORM; DICHLORO(2,2' BIPYRIDINE)PLATINUM; METAL COMPLEX; PLATINUM DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; COMPLEX FORMATION; LIGHT ABSORPTION; PHOTOLYSIS; PHOTOOXIDATION; PROTON TRANSPORT; QUANTUM CHEMISTRY; RADIATION EXPOSURE; REACTION ANALYSIS; SPECIES DIFFERENTIATION;

EID: 2342453296     PISSN: 00318655     EISSN: None     Source Type: Journal    
DOI: 10.1562/2003-12-05-RA.1     Document Type: Article

References (20)

1. Vogler, A. and H. Kunkely (1989) Photochemical oxidative addition of chlorine from chloroform to 2,2′-bipyridyldichloroplatinum(II). Inorg. Chim. Acta 163, 207-208.
2. Sathiyabalan, S. and P. E. Hoggard (1995) Kinetics and mechanism of the photooxidation of bis(bipyridine)dichloromthenium(II) and the photoreduction of bis(bipyridine)ruthenium(III) in chloroform. Inorg. Chem. 34, 4562-4571.
3. Stegge, J. M., S. M. Woessner and P. E. Hoggard (1996) The solvent-initiated photochemistry of tris(N,N-diethyldithiocarbamato)iron(III). Inorg. Chim. Acta 250, 385-388.
4. Phan, S. L., K. J. Cendak and P. E. Hoggard (2001) A kinetic study of the photolysis of tris(2,4-pendanedionato)cobalt(III) and bis(2,4-pentanedionato)cobalt(II) in chloroform. Inorg. React. Mech. 3, 137-146.
5. Ng, W. and P. E. Hoggard (2001) Kinetics of the photoreduction of bis(2,4-pentanedionato)copper(II) in chloroform. Inorg. Chim. Acta 321, 1-4.
6. Orazem, E. L. and P. E. Hoggard (2001) The photolysis of bis(benzene)chromium(I) in chloroform. Inorg. Chem. Commun. 4, 157-159.
7. Hoggard, P. E. and A. Vogler (2003) The photooxidation of tetrachloroplatinate(II) in chloroform. Inorg. Chim. Acta 348, 229-232.
8. Nguyen, T. H., P. J. Shannon and P. E. Hoggard (1999) Kinetics of the photooxidation of tris(bipyridine)iron(II) in chloroform. Inorg. Chim. Acta 291, 136-141.
9. Jaryszak, E. M. and P. E. Hoggard (1998) Kinetics of the photolysis of bis(triethylphosphine)dichloroplatinum(II) in chloroform. Inorg. Chim. Acta 282, 217-221.
10. Hoggard, P. E. (1997) Solvent-initiated photochemistry of transition metal complexes. Coord. Chem. Rev. 159, 235-243.
11. Watt, G. W. and D. G. Upchurch (1966) A novel synthesis of bipyridyl(ethylenediamine)platinum(II) iodide. Inorg. Nucl. Chem. Lett. 2, 363-364.
12. 3 and ClO radical formation. J. Photochem. 14, 157-165.
13. Murgulescu, I. G. and M. Weissmann (1976) The effects of methane on the thermal decomposition of chloroform. I. The first three reaction steps. Rev. Roum. Chim. 21, 1275-1286.
14. Alfassi, Z. B. (1980) The rate constant for combination of a trichloromethyl radical with cyclohexyl or n-hexyl radicals. An evidence for the value of the rate constant for a chlorine atom transfer. Int. J. Chem. Kinet. 12, 217-223.
15. Traverso, O. and F. Scandola (1970) Photooxidation of ferrocene in halocarbon solvents. Inorg. Chim. Acta 4, 493-498.
16. 3OO radical. Evidence for a first-order transition. J. Phys. Chem. 93, 553-557.
17. Gäb, S. and W. V. Turner (1985) Photooxidation of chloroform: isolation and characterization of trichloromethyl hydroperoxide. Angew. Chem. 97, 48.
18. Mosseri, S., Z. B. Alfassi and P. Neta (1987) Absolute rate constants for hydrogen abstraction from hydrocarbons by the trichloromethylperoxy radical. Int. J. Chem. Kinet. 19, 309-317.
19. - equilibrium in alcohol/water mixtures. Phys. Chem. Chem. Phys. 5, 2783-2789.
20. 2+. J. Inorg. Biochem. 91, 199-204.