Stable Optically Pure Phosphino(silyl)carbenes: Reagents for Highly Enantioselective Cyclopropanation Reactions

Chemistry - A European Journal

Volumn 10, Issue 8, 2004, Pages 1982-1986

  Krysiak, Jerzy ^a,b   Lyon, Céline ^a   Baceiredo, Antoine ^a   Gornitzka, Heinz ^a   Mikolajczyk, Marian ^b   Bertrand, Guy ^a,c  

^a UNIVERSITÉ PAUL SABATIER   (France)

^b CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Asymmetric synthesis; Carbenes; Cycloaddition; Diazo compounds; Phosphorus

Indexed keywords

AMINES; DIMERIZATION; REACTION KINETICS; STEREOCHEMISTRY;

DIASTEREOSELECTIVITY; STERIC HINDRANCE;

OLEFINS;

1,3 DIPHOSPHATE; CARBENOID; CYCLOHEXANE DERIVATIVE; DIAMINE DERIVATIVE; N,N' DIISOPROPYL 1,2 ETHANEDIAMINE; N,N' DIISOPROPYLCYCLOHEXANE 1,2 DIAMINE; NITROGEN; PHOSPHINE DERIVATIVE; PHOSPHINO(SILYL)CARBENE; PHOSPHORUS; PHOSPHORUS DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CYCLOADDITION; CYCLOPROPANATION; DIMERIZATION; ENANTIOMER; ENANTIOSELECTIVITY; N,N' DI TERT BUTYL 1,2 DIPHENYL 1,2 ETHANEDIAMINE; OPTICS; STEREOCHEMISTRY;

EID: 2342427282     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305722     Document Type: Article

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