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Volumn 24, Issue 13, 2005, Pages 3074-3080

Synthesis and structure of a stable 1,3-dihydrotriphosphane and its thermal decomposition leading to the formation of the corresponding phosphine and diphosphene

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; LITHIUM COMPOUNDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; PYROLYSIS; SYNTHESIS (CHEMICAL); THERMOANALYSIS; TOLUENE; X RAY CRYSTALLOGRAPHY;

EID: 23144466910     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0501069     Document Type: Article
Times cited : (18)

References (50)
  • 1
    • 0001598302 scopus 로고
    • For a review on open-chain phosphorus compounds, see: Baudler, M.; Glinka, K. Chem. Rev. 1994, 94, 1273-1297.
    • (1994) Chem. Rev. , vol.94 , pp. 1273-1297
    • Baudler, M.1    Glinka, K.2
  • 38
    • 21644450557 scopus 로고    scopus 로고
    • Structures and reactions of compounds containing heavier main group elements
    • Fueno, T., Ed.; Gordon Science: Amsterdam, Chapter 8
    • 2-hybridized phosphorus atom, bulky substituents on the phosphorus atom are known to stabilize the transition state due to the relief of steric repulsion; see: Nagase, S. Structures and Reactions of Compounds Containing Heavier Main Group Elements. In The Transition State-A Theoretical Approach, Fueno, T., Ed.; Gordon Science: Amsterdam, 1999; Chapter 8.
    • (1999) The Transition State-A Theoretical Approach
    • Nagase, S.1
  • 39
    • 23144445347 scopus 로고    scopus 로고
    • note
    • 2PFc 6a-c have optimized structures as (1S*,3R*), (1R*,3R*), and (1R*,3S*) geometries, respectively. In Figure 2 are shown the relative energies for 6a-c calculated at B3LYP/6-31G(d) level.
  • 40
    • 0000812714 scopus 로고
    • and references therein
    • Baudler, M.; Glinka, K. Chem. Rev. 1993, 93, 1623-1667, and references therein.
    • (1993) Chem. Rev. , vol.93 , pp. 1623-1667
    • Baudler, M.1    Glinka, K.2
  • 49
    • 0004150157 scopus 로고    scopus 로고
    • Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen
    • Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.