Phase equilibria and kinetic behavior of CO2 hydrate in electrolyte and porous media solutions: Application to ocean sequestration of CO2

Korean Journal of Chemical Engineering

Volumn 19, Issue 4, 2002, Pages 673-678

  Lee, Jong Won ^a   Chun, Moon Kyoon ^a   Lee, Kyung Min ^a   Kim, Yu Jeong ^a   Lee, Huen ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

Carbon dioxide; Equilibrium; Hydrate; Kinetics; Sequestration

Indexed keywords

EID: 23044532975     PISSN: 02561115     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02699316     Document Type: Article

References (17)

1. Bishnoi, P. R and Natarajan, V., "Formation and Decomposition of Gas Hydrate", Fluid Phase Equilib., 117, 168(1996).
2. Chun, M.-K. and Lee, H., "Kinetics of Formation of Carbon Dioxide Clathrate Hydrates", Korean J. Chem. Eng., 13, 620 (1996).
3. Dholabhai, P. D., Kalogerakis, N. and Bishnoi, P. R, "Kinetics of Methane Hydrate Formation in Aqueous-electrolyte Solutions" Can. J. Chem. Eng., 71, 6S (1993).
4. Englezos, P., "Clathrate Hydrates", Ind. Eng. Chem. Res., 32, 1251 (1993).
5. Englezos, P., Kalogerakis, N., Dholabhai, P. D. and Bishnoi, P. R., "Kinetics of Formation of Methane and Ethane Gas Hydrates", Chem. Eng. Sci., 42(11), 2647 (1987).
6. Huron, M.-J. and Vidal, J., "New Mixing Rules in Simple Equations of State for Representing Vapor-Liquid Equilibria of Strongly Non-ideal Mixtures", Fluid Phase Equilib., 3, 255 (1979).
7. Makogon, Y. E, "Hydrates of Hydrocarbons", PennWelL Tulsa (1997).
8. Malegaonkar, M. B., Dholabhai, P. D. and Bishnoi, P. R., "Kinetics of Carbon Dioxide and Methane Hydrate Formation," Can. J. Chem. Eng., 75, 1090(1997).
9. Natarajan, V, Bishnoi, P. R. and Kalogerakis, N., "Induction Phenomena in Gas Hydrate Nucleation", Chem. Eng. Sci., 49(13), 2075 (1994).
10. Pitzer, K. S., "Thermodynamics of Electrolytes I. Theoretical Basis and General Equations", J. Phys. Chem., 77, 268 (1973).
11. Seo, Y.-T, Kang, S.-R, Lee, H, Lee, C.-S. and Sung, W.-M, "Hydrate Phase Equilibria for Gas Mixtures Containing Carbon Dioxide: A Proof-of-Concept to Carbon Dioxide Recovery from Multi-component Gas Stream", Korean J. Chem. Eng., 17, 659 (2000).
12. 2 Hydrate", Energy Convers. Mgmt., 34, 1073 (1993).
13. Sloan, Jr. E. D., "Clathrate Hydrates of Natural Gases", Marcel Dekker, New York (1998).
14. Sloan, Jr. E. D. and Fleyfel, E, "A Molecular Mechanism for Gas Hydrate Nucleation from Icq", AIChE J., 37, 1281 (1991).
15. Soave, G., "Equilibrium Constants from a Modified Redlich-Kwong Equation of State", Chem. Eng. Sci., 27, 1197 (1972).
16. Sung, W.-M., Huh, D.-G., Ryu, B.-J. and Lee, H.-S., "Development and Application of Gas Hydrate Reservoir Simulator Based on Depres- surizing Mechanism", Korean J. Chem. Eng., 17, 344 (2000).
17. 2 Droplet in High-pressure, Low-temperature Water", Chem. Eng. Sci., 50, 559 (1995).