Role of boric acids in the formation of pegmatite and hydrothermal minerals: Petrologic consequences of sassolite (H3BO3) discovery in fluid inclusions

Petrology

Volumn 8, Issue 3, 2000, Pages 214-237

  Peretyazhko, I S ^a   Prokof'ev, V Yu ^b   Zagorskii, V E ^a   Smirnov, S Z ^c  

^a VINOGRADOV INSTITUTE OF GEOCHEMISTRY   (Russian Federation)

^b INSTITUTE OF GEOLOGY OF ORE DEPOSITS   (Russian Federation)

^c SOBOLEV INSTITUTE OF GEOLOGY AND MINERALOGY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 23044521225     PISSN: 08695911     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (99)

1. Akhmanova, M.V. and Kuril'chikova, G.E., Study of Ion Speciation in Boron-and Fluor-containing Aqueous Solutions of Potassium and Sodium Compounds by IRS Method, Zh. Neorg. Khim., 1962, vol. 7, no. 3, pp. 516-521.
2. Aleksandrov, S.M., Geokhimiya bora i olova v mestorozhdeniyakh magnezial'no-skarnovoi formatsii (Geochemistry of Boron and Tin in Deposits of the Magnesium Skarn Association), Moscow: Nauka, 1982.
3. 2O at 20°C, Zh. Prikl. Khim., 1969, vol. 42, no. 11, pp. 2583-2584.
4. Bakker, R.J. and Thiry, R., Application of Clatrates to Fluid Inclusion Studies, in Fluid Inclusions in Minerals: Methods and Applications, de Vivo, B. and Frezzotti, M. L., Eds., Pontignano-Siena, 1994, pp. 191-208.
5. Bakumenko, I.T., Smirnov, S.Z., The Study of Late Magmatic Inclusions in Honeycomb Quartz from Granitic Pegmatites, in Termobarogeokhimiya mineraloobrazuyushchikh protsessov. Vyp. 2. Voprosy magmatizma i metamorfizma (Inclusions in Minerals and Mineralization Processes, Issue 2: Problems of Magmatism and Metamorphism), Novosibirsk: Ob"ed. Inst. Geol. Geofiz. Mineral. Sib. Otd. Ross. Akad. Nauk, 1992, pp. 30-47.
6. Bakumenko, I.T. and Konovalenko, S.I., Formation Peculiarities of Miarolitic Pegmatites and Their Position among Granitic Pegmatites, in Termobarogeokhimicheskie issledovaniya protsessov mineraloobrazovaniya (Studies of Inclusions in Minerals with Applications to Mineralization Processes), Novosibirsk: 1988, pp. 123-135.
7. Bassett, R.L., A Critical Evaluation of the Thermodynamic Data for Boron Ions, Ion Pairs, Complexes, and Polyanions in Aqueous Solution at 298.15 K and 1 Bar, Geochim. Cosmochim. Acta, 1980, vol. 44, pp. 1151-1160.
8. 2O-NaCl Fluid Inclusions, in Fluid Inclusions in Minerals: Methods and Applications, de Vivo, B. and Frezzotti, M. L., Eds., Pontignano-Siena: 1994, pp. 117-130.
9. Bol'shoe treshchinnoe Tolbachinskoe izverzhenie (Kamchatka, 1975-1976) (The Great Tolbachik Fissure Eruption, Kamchatka, 1975-1976), Fedotov, S.A., Ed., Moscow: Nauka, 1984.
10. Brown, P.E., FLINCOR: A Fluid Inclusion Data Reduction and Exploration Program, 2nd Biennial Pan-Am. Conf. Res. Fluid Inclusions, 1989, p. 14.
11. 2-NaCl: New Graphical Presentations and Implications for Fluid Inclusion Studies, Geochim. Cosmochim. Acta, 1989, vol. 53, no. 6, pp. 1209-1222.
12. Culberson, C., Kester, D.R., and Pytrowicz, R.M., High-Pressure Dissociation of Carbonic and Boric Acids in Seawater, Science, 1967, vol. 157, no. 3784, pp. 51-53.
13. - in Aqueous Solution at 298-533 K, Geokhimiya, 1982, no. 4, pp. 550-564.
14. Di Giacomo, G., Brandani, P., Brandani, V., and Delre, G., Solubility of Boric Acid in Aqueous Solutions of Chloride Salts, Desalination, 1993, vol. 91, no. 1, pp. 21-23.
15. Dietrich, R.V., The Tourmaline Group, New York: Van Nostrand, 1985.
16. Ermakov, N.P., Geokhimicheskie sistemy vklyuchenii v mineralakh (Geochemical Systems of Inclusions in Minerals), Moscow: Nedra, 1972.
17. Felmy, A.R. and Weare, J.H., The Prediction of Borate Mineral Equilibria in Natural Waters: Application to Searles Lake, California, Geochim. Cosmochim. Acta, 1986, vol. 50, pp. 2771-2783.
18. Fersman, A.E., Izbrannye trudy (Selected Works), Moscow: Akad. Nauk SSSR, 1960, vol. 6.
19. Foord, E.E., London, D., Kampf, A.R., et al., Gem-bearing Pegmatites of San Diego County, California, in Geological Excursions in Southern California and Mexico, A Guidebook. Annu. Meeting Geol. Soc. Am., San Diego, California, 1991, pp. 128-146.
20. 3 Solution and Its Implication in Rock Metamorphism, Am. Mineral., 1957, vol. 42, nos. 11-12, pp. 754-758.
21. Gorbov, A.F., Geokhimiya bora (Geochemistry of Boron), Moscow: Nedra, 1976.
22. Gorbov, A.F., Formation Conditions and Distribution Regularities of Borate Deposits of the Volcanic-Sedimentary Type, Tr. Vsesoyuz. Nauchno-Issled. Inst. Galurgii, 1960, no. 40, pp. 3-69.
23. Grebenshchikov, I.V. and Favorskaya, T.A., Titration of Boric Acid by the Electrometric Method, Zh. Fiz.-Khim. O-va, 1929, vol. 61, no. 4, pp. 561-574.
24. Ishkov, Yu.M. and Reif, F.G., Lazerno-spektral'nyi analiz vklyuchenii rudonosnykh flyuidov v mineralakh (Laser Spectral Analysis of Ore-bearing Fluid Inclusions in Minerals), Novosibirsk: Nauka, 1990.
25. Kalyuzhnyi, V.A., Composition of Minerals from Multi-Phase Inclusions, Mineral. Sb. Lvov. Geol. O-va, 1958a, no. 12, pp. 116-128.
26. Kalyuzhnyi, V.A., Improved Thermal Microscopic Cell for Analysis of Gas-Liquid Inclusions, Tr. Vses. Nauchno-Issled. Inst. P'ezoopt. Miner. Syr'ya, 1958b, vol. 2, no. 2, pp. 43-47.
27. Kalyuzhnyi, V.A., Lyakhov, Yu.V., Gryn'kiv, Z.S., et al., Age Interrelations and Composition of Gas-Liquid Inclusions in Quartz from Volyn' Pegmatites, in Issledovanie mineraloobrazuyushchikh rastvorov (Study of Mineral-forming Solutions), Moscow: Nedra, 1966, pp. 112-120.
28. Keshan, A.D., Sintez boratov v vodnom rastvore i ikh issledovanie (Synthesis of Borates in Aqueous Solution and Their Study), Riga: Akad. Nauk Latv. SSR, 1955.
29. Kol'tgof, I.M. and Stenger, V.A., Ob"emnyi analiz (Volumetrical Analysis), Moscow: Goskhimizdat, 1952, vol. 2.
30. Kosukhin, O.N., Bakumenko, I.T., and Chupin, V.P., Magmaticheskii etap formirovaniya granitnykh pegmatitov (Magmatic Stage in the Formation of Granitic Pegmatites), Novosibirsk: Nauka, 1984.
31. Kovalenko, V.I., Tsareva, G.M., Kononkova, N.N., and Kyune, M., Principal Components, Trace Elements, and Water in Spodumene Granite Magma, Dokl. Ross. Akad. Nauk, 1998, vol. 362, pp. 816-820.
32. Kovalenko, V.I., Tsareva, G.M., Naumov, V.B., et al., Magma of the Volyn' Pegmatites: Composition and Crystallization Parameters, Evidence from the Study of Mineral-forming Media, Petrologiya, 1996, vol. 4, no. 3, pp. 295-309.
33. Kracek, F.C., Morey, G.W., and Merwin, H.E., The System Water-Boron Oxide, Am. J. Sci., Ser. 5, 1938, vol. 35-A, pp. 143-171.
34. Kurshakova, L.D., Fiziko-khimicheskie usloviya obrazovaniya skarnovo-borosilikatnykh mestorozhdenii (Physico-chemical Conditions of Formation of Skarn Borosilicate Deposits), Moscow: Nauka, 1976.
35. Lobanova, V.V. and Avrova, N.P., New Mineral Metaborite - Natural Metaboric Acid, Zap. Vses. Mineral. O-va, 1964, vol. 93, no. 3, pp. 329-334.
36. London, D., Magmatic Hydrothermal Transition in the Tanko Rare-Element Pegmatite: Evidence from Fluid Inclusions and Phase Equilibrium Experiments, Am. Mineral., 1986a, vol. 71, pp. 376-395.
37. London, D., Formation of Tourmaline-rich Gem Pockets in Miarolitic Pegmatites, Am. Mineral., 1986b, vol. 71, nos. 3-4, pp. 396-405.
38. London, D., Stability of Tourmaline in Peraluminous Granite Systems: The Boron Cycle from Anatexis to Hydrothermal Aureoles, Eur. J. Mineral., 1999, vol. 11, no. 2, pp. 253-262.
39. 2 Solubility in Solutions at High Temperatures and Pressures, Geokhimiya, 1975, no. 4, pp. 547-550.
40. Mesmer, R.E., Baes, C.F., and Sweeton, F.H., Acidity Measurements at Elevated Temperatures. VI. Boric Acid Equilibria, Inorg. Chem., 1972, vol. 11, no. 3, pp. 536-543.
41. Mesmer, R.E., Palen, K.M., and Baes, C.F., Fluoborate Equilibria in Aqueous Solution, Inorg. Chem., 1973, vol. 12, no. 1, pp. 89-95.
42. Miarolovye pegmatity (Miarolitic Pegmatites), Zagorskii, V.E., Peretyazhko, I.S., and Shmakin, B.M., Eds., Novosibirsk: Nauka (in press).
43. Mineraly bora (spravochnik) (Boron Minerals. A Handbook), Malinko, S.V., Khaliurin, I.I., Ozol, A.A., and Bocharov, V.M., Eds., Moscow: Nedra, 1991.
44. Moore, J. and Gunderson, R.P., Fluid Inclusion and Isotopic Systematics of an Evolving Magmatic-Hydrothermal System, Geochim. Cosmochim. Acta, 1995, vol. 59, pp. 3887-3907.
45. Morgan, G.B., VI. and London, D., Alteration of Amphibolitic Wallrocks around the Tanco Rare Element Pegmatite, Bernic Lake, Manitoba, Am. Mineral., 1987, vol. 72, pp. 1097-1121.
46. Morgan, G.B., VI. and London, D., Experimental Reactions of Amphibolite with Boron-bearing Aqueous Fluids at 200 MPa: Implications for Tourmaline Stability and Partial Melting in Mafic Rocks, Contrib. Mineral. Petrol., 1989, vol. 102, no. 3, pp. 281-297.
47. Motorina, I.V. and Bakumenko, I.T., On the Tourmaline Genesis in the Pegmatites of the Borshchovochnyi Range, in Mineralogicheskaya termometriya i barometriya (Mineralogical Thermometry and Barometry), Moscow: Nauka, 1968, vol. 2, pp. 196-201.
48. Nemodruk, A.A. and Karalova, Z.K., Analiticheskaya khimiya bora (Analytical Chemistry of Boron), Moscow: Nauka, 1964.
49. Palmer, M.R. and Slack, J.F., Boron Isotopic Composition of Tourmaline from Massive Sulfide Deposits and Tourmaline, Contrib. Mineral. Petrol., 1989, vol. 103, no. 4, pp. 434-451.
50. Palmer, M.R., Boron Isotope of Hydrothermal Fluids and Tourmalines: A Synthesis, Chem. Geol. (Isotope Geosci. Sect.), 1991, vol. 14, no 2, pp. 111-121.
51. 10B between Tourmaline and Aqueous Vapor: A Temperature-and Pressure-dependent Isotopic System, Chem. Geol. (Isotope Geosci. Sect.), 1992, vol. 15, no. 1/2, pp. 123-129.
52. Peretyazhko, I.S., Shmakin, B.M., Zagorskii, V.E., and Bobrov, Yu.D., Alumina-rich Dravites from Pegmatites of Nepal and Central Transbaikalia, Dokl. Akad. Nauk SSSR, 1986, vol. 289, no. 2, pp. 475-479.
53. Peretyazhko, I.S., Zagorskii, V.E., Prokofiev, V.Yu., and Gantimurova, T.P., Miarolitic Pegmatites of the Kukurt Gem Region: Evolution of the Mineralization Conditions of the Amazonitovaya Vein, Geokhimiya, 1999, no. 2, p. 37; pp. 133-152.
54. Peretyazhko, I.S., Zagorsky, V.Ye., Prokof'ev, V.Yu., and Smirnov, S.Z., Boric Acid as the Most Typical Component of Fluid Inclusions in Minerals from Tourmaline-bearing and Topaz-Beryl Miarolitic Pegmatites, Can. Mineral., 1999, vol. 37, no. 4, pp. 823-825.
55. Pichavant, M., An Experimental Study of the Effect of Boron on a Water Saturated Haplogranite at 1 kbar Vapour Pressure, Contrib. Mineral. Petrol., 1981, vol. 76, pp. 430-439.
56. 0 in Hydrothermal Solutions Using a New High-Temperature Solid-Selective Glass Electrode - Implications for Boron Isotopic Fractionation, Chem. Geol., 1995, vol. 124, nos. 3-4, pp. 253-265.
57. Ponomareva, N.I., Krivovichev, V.G., and Butorin, V.V., Physicochemical Conditions of Tourmaline (Schorl) Formation in Rare-Metal Granitic Pegmatites and Their Host Rocks, Vestn, St. Peterb. Univ. Ser. 7, 1997a, no. 2, pp. 18-26.
58. Ponomareva, N.I., Krivovichev, V.G., Sokolov, P.B., et al., Physicochemical Conditions of Tourmaline Formation in Rare-Metal Pegmatites, Vestn. St. Peterb. Univ. Ser. 7, 1997b, no. 4, pp. 88-95.
59. Reardon, E.J., Dissociation Constants for Alkali Earth and Sodium Borate Ion Pairs from 10 to 50°C, Chem. Geol., 1976, vol. 18, no. 4, pp. 309-325.
60. Redkometal'nye pegmatity (Rare-Metal Pegmatites), Zagorskii, V.E., Makagon, V.M., Shmakin, B.M., et al., Eds., Novosibirsk: Nauka, 1997.
61. Reif, F.G. and Bazheev, E.D., Magmaticheskii protsess i vol'framovoe orudenenie (Magmatic Process and Tungsten Ore Mineralization), Novosibirsk: Nauka, 1982.
62. Roedder, E., Fluid Inclusions, Rev. Mineral., Mineral. Soc. Am., Washington, 1984, vol. 12.
63. Rossovskii, L.N., Makagon, V.M., and Kuz'mina, T.M., Peculiarities of Formation of the Kunzile Deposit in Afghanistan, Geol. Geofiz., 1978, no. 11, pp. 102-108.
64. Rossovskii, L.N., Morozov, S.A., and Skrigitil', A.M., Peculiarities of Formation of the Miarolitic Pegmatites in the Eastern Pamirs, Izv. Akad. Nank SSSR, Ser. Geol., 1991, no. 5, pp. 92-103.
65. Ruggieri, G. and Lattanzi, P., Fluid Inclusion Studies on Mt. Capanne Pegmatites, Isola d'Elba, Tuscany, Italy, Eur. J. Mineral., 1992, no. 4, pp. 1085-1096.
66. Ryss, I.G., Slutskaya, M.M., and Vitukhnovskaya, B.S., Equilibrium of the System Sodium Fluoride-Boric Acid-Water at 25°C, Zh. Prikl. Khim., 1952, vol. 25, no. 2, pp. 148-153.
67. Semenov, Yu.V., Malinko, S.V., Kiseleva, I.A., and Khodakovskii, I.L., Thermodynamic Analysis of Formation Conditions of Calcium Endogenic Borosilicates and Borates, Geokhimiya, 1987, no. 8, pp. 1182-1190.
68. Shmakin, B.M., Pegmatitovye mestorozhdeniya zarubezhnykh stran (Pegmatite Deposits of Foreign Countries), Moscow: Nedra, 1987.
69. Simonov, V.A., Petrogenezis ofiolitov (Petrogenesis of Ophiolites), Novosibirsk: Nauka, 1993.
70. Slivko, M.M., Issledovanie turmalinov nekotorykh mestorozhdenii SSSR (Study of Tourmalines from Some Deposits of the USSR), Lvov: Lvov. Gos. Univ., 1955.
71. Slivko, M.M., On the Inclusions of Solutions in Tourmaline Crystals, Tr. Vses. Nauch.-Issled. Inst. P'ezoopt. Miner. Syr'ya, 1958, vol. 2, no. 2, pp. 64-68.
72. 3) in Fluid Inclusions: The First Evidence of Natural Fluids with High Boron Acid Content, Terra Nostra 99/6 ECROFI XV, Abstracts and Program, Potsdam, 1999, pp. 283-285.
73. Smirnov, S.Z. and Ishkov, Yu.M., Fluid Mineralizing Components of Residual Granitic Pegmatites, Evidence from the Pegmatites of the Kent Massif, Central Kazakhstan, in Materialy po geneticheskoi i eksperimental'noi mineralogii (Materials for Genetic and Experimental Mineralogy), Novosibirsk: Ob"ed. Inst. Geol. Geofiz. Mineral. Sib. Otd. Ross. Akad. Nauk, 1995, no. 11, pp. 44-49.
74. 3) in Fluid Inclusions in Minerals, Geol. Geofiz., 2000, no. 2, pp. 194-206.
75. Smith, F.Y., Transport and Deposition of the Non-Sulfide Vein Minerals. 4. Tourmaline, Econ. Geol., 1949, vol. 44, no. 3, pp. 186-192.
76. Smith, M.P. and Yardley, B.W.D., The Isotopic Composition of Tourmaline as a Guide to Fluid Process in the Southwestern England Orefield: An Ion Microprobe Study, Geochim. Cosmochim. Acta, 1996, vol. 60, no. 8, pp. 1415-1427.
77. Spravochnik eksperimental'nykh dannykh po rastvorimosti mnogokomponentnykh vodnosolevykh system (Handbook on Solubility of Multicomponent Water-Salt Systems), Zhdanovskii, B.A., Lekhovskaya, E.I., and Shlimovich, R.E., Eds., Leningrad: Khimiya, 1975.
78. Swihart, G.H. and Moore, P.B., A Reconnaissance of Boron Isotopic Composition of Tourmaline, Geochim. Cosmochim. Acta, 1989, vol. 53, pp. 911-916.
79. 2 from Metasomatic Tourmaline within the Border Unit of the Tanco Zoned Granitic Pegmatite, S.E. Manitoba, Geochim. Cosmochim. Acta, 1988, vol. 52, no. 5, pp. 1065-1075.
80. Thomas, R. and Bauman, L., Ergebnisse von thermometrischen und kryometrischen Untersuchungen an Kassiteriten des Erzgebirges, Z. Geol. Wiss., 1980, vol. 10, pp. 1281-1299.
81. Thomas, R., Webster, J.D., and Heinrich, W., Melt Inclusions in Pegmatite Quartz: Complete Miscibility between Silicate Melts and Hydrous Fluids? Terra Nostra 99/6 ECROFI XV, Abstr. and Program, Potsdam, 1999, pp. 305-307.
82. Tonarini, S., Dini, A., Pezzotta, F., and Leeman, W.P., Boron Isotopic Composition of Zoned (Schorl-Elbaite) Tourmalines, Mt. Capanne Li-Cs Pegmatite, Elba (Italy), Eur. J. Mineral., 1998, vol. 10, pp. 941-951.
83. Trumbull, R.B. and Chaussidon, M., Chemical and Boron Isotopic Composition of Magmatic and Hydrothermal Tourmalines from the Sinceini Granite-Pegmatite System in Swaziland, Chem. Geol., 1999, vol. 153, nos. 1-4, pp. 125-137.
84. Valyashko, M.G. and Gode, G.K., On the Relation between Mode of Borate Deposition from Solutions and Their pH, Zh. Neorg. Khim., 1960, vol. 5, no. 6, pp. 1316-1328.
85. Valyashko, M.G. and Vlasova, E.V., Boron Speciation in Aqueous Solutions: Evidence from Infrared Spectroscopy, Geokhimiya, 1966, no. 7, pp. 818-831.
86. Vinogradov, E.E., Zaitseva, S.N., Samoilov, O. Ya., and Yashkichev, V.I., Effect of Aqueous Solution Composition on Boric Acid Dissociation, Zh. Fiz. Khim., 1966, vol. 40, no. 10, pp. 2519-2521.
87. Vladimirov, A.G., Vystavnoi, S.A., Titov, A.V., et al., Petrology of Early Mesozoic Rare-Metal Granites from the Southern Gornyi Altai: A Contribution to the Problem of Origin of Unusual Melts Enriched in Rare Alkalis and Phosphorus, Geol. Geofiz., 1998, vol. 39, no. 7, pp. 901-916.
88. Vlodavets, V.I., On the Vapor-Hydrosolfathermal Deposits in the Volcanic Areas of Italy, Izv. Akad. Nauk SSSR, Ser. Geol., 1955, no. 5, pp. 109-129.
89. Vorbach, A., Experimental Examinations on Stability of Synthetic Tourmalines in Temperatures from 250 to 750°C and Pressures up to 4 kb, Neues Jahrb. Mineral. Abh., 1989, vol. 161, no. 1, pp. 69-83.
90. Voskresenskaya, I.E. and Barsukova, M.L., Synthesis and Properties of Some Iron-bearing and Iron-free Tourmalines, in Gidrotermal'nyi sintez kristallov (Hydrothermal Synthesis of Crystals), Moscow: Nauka, 1968, pp. 179-192.
91. Webster, J.D., Thomas, R., Rhede, D., et al., Melt Inclusions in Quartz from an Evolved Peraluminous Pegmatite: Geochemical Evidence for Strong Tin Enrichment in Fluorine-rich and Phosphorus-rich Liquids, Geochim. Cosmochim. Acta, 1997, vol. 61, no. 13, pp. 2589-2604.
92. Williams, A.E. and Taylor, M.C., Mass Spectrometric Identification of Boric Acid in Fluid Inclusions, Geochim. Cosmochim. Acta, 1996, vol. 60, pp. 3435-3443.
93. Yakubova, V.V., Studies of Inclusions in Minerals of the Murzinka Pegmatites (Urals), Tr. Mineral. Muzeya Akad. Nauk SSSR, 1952, no. 4, pp. 102-121.
94. Yakubova, V.V., Studies of Inclusions in Minerals of the Murzinka Pegmatites (Urals), Tr. Mineral. Muzeya Akad. Nauk SSSR, 1955, no. 7, pp. 132-150.
95. Yushkov, S.F., Shvartsev, S.L., and Bukaty, M.B., Modes of Boron Migration in the Boron-bearing Mineral Waters of the USSR, in Borosoderzhashchie mineral'nye vody SSSR (Boron-containing Mineral Waters of the USSR), Moscow: 1988, pp. 96-115.
96. Zagorskii, V.E. and Peretyazhko, I.S., Pegmatity s samotsvetami Tsentral'nogo Zabaikal'ya (Gem Pegmatites of Central Transbaikalia), Novosibirsk: Nauka, 1992.
97. Zagorskii, V.E. and Peretyazhko, I.S., Tourmaline Deposits in Russia and Tajikistan, Geol. Geofiz., 1996, vol. 37, no. 10, pp. 36-50.
98. Zagorskii, V.E., Peretyazhko, I.S., and Sapozhnikov, A.N., Boron-rich Micas and Chlorites from Miarolitic Pegmatites, Zap. Vseross. Mineral. O-va, 1998, no. 6, pp. 55-68.
99. Zaraiskii, G.P., Zonal'nost'i usloviya obrazovaniya metasomaticheskikh porod (Zoning and Formation Conditions of Metasomatic Rocks), Moscow: Nauka, 1989.