Solvent-free methylthiomethyllithium [LiCH2SMe]∞: Solid state structure and thermal decomposition

Chemical Communications

Volumn , Issue 27, 2005, Pages 3442-3444

  Ruth, Kai ^a   Dinnebier, Robert E ^b   Tonnes, Stefan W ^a   Alig, Edith ^a   Sänger, Ingeborg ^a   Lerner, Hans Wolfram ^a   Wagner, Matthias ^a  

^a GOETHE UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ARGON; LITHIUM DERIVATIVE; METHYLTHIOMETHYLLITHIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; DECOMPOSITION; EXPLOSION; HEATING; SOLID STATE; SOLVENT EFFECT; THERMOSTABILITY;

EID: 23044450781     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b505096k     Document Type: Article

References (17)

1. P. Ge, B. S. Haggerty, A. L. Rheingold and C. G. Riordan, J. Am. Chem. Soc., 1994, 116, 8406.
2. H. W. Yim, L. M. Tran, E. D. Dobbin, D. Rabinovich, L. M. Liable-Sands, C. D. Incarvito, K.-C. Lam and A. L. Rheingold. Inorg. Chem. 1999, 38, 2211.
3. D. Morales, J. Pérez, L. Riera, V. Riera and D. Miguel. Organometallics, 2001, 20, 4517.
4. R. Krishnan, J. K. Voo, C. G. Riordan, L. Zahkarov and A. L. Rheingold, J. Am. Chem. Soc., 2003, 125, 4422.
5. M. M. Maye, S. C. Chun, L. Han, D. Rabinovich and C.-J. Zhong, J. Am. Chem. Sac., 2002, 124, 4958.
6. T. Rüffer, C. Bruhn, E. Rusanov, K. Nordhoff and D. Steinborn, Z. Anorg. Allg. Chem., 2002, 628, 421.
7. F. Becke, T. Rüffer, R. Boese, D. Bläser and D. Steinborn, J. Organomet. Chem., 1997, 545-546, 169.
8. D. J. Peterson, J. Org. Chem., 1967, 32, 1717.
9. C. Lustig and N. W. Mitzel, Organometallics, 2002, 21, 3471.
10. D. J. Peterson, J. Organomet. Chem., 1971, 26, 215.
11. F. Becke, F. W. Heinemann and D. Steinborn, Organometallics, 1997, 16, 2736.
12. T. Rüffer, C. Bruhn, A. H. Maulitz, D. Ströhl and D. Steinborn, Organometallics, 2000, 19, 2829.
13. R. Amstutz, T. Laube, W. B. Schweizer, D. Seebach and J. D. Dunitz, Helv. Chim. Acta, 1984, 67, 224.
14. Only a few other solvent-free organolithium compounds have been structurally characterized; see: T. Kottke and D. Stalke, Angew. Chem., Int. Ed Engl., 1993,32, 580;
15. R. E. Dinnebier, U. Behrens and F. Olbrich, J. Am. Chem. Soc., 1998, 120, 1430;
16. X. Tian, M. Woski, C. Lustig, T. Pape, R. Fröhlich, D. Le Van, K. Bergander and N. W. Mitzel, Organometallics, 2005, 24, 82.
17. P. v. R. Schleyer, T. Clark, A. J. Kos, G. W. Spitznagel, C. Rohde, D. Arad, K. N. Houk and N. G. Rondan, J. Am. Chem. Soc., 1984, 106, 6467.