Stability and solvation of 1:1 complexes of dibenzo-21-crown-7 with alkali metal ions in polar solvents

Journal of Chemical and Engineering Data

Volumn 50, Issue 4, 2005, Pages 1313-1318

  Katsuta, Shoichi ^a   Kuwano, Tetsuyuki ^a   Ito, Yusuke ^a   Takeda, Yasuyuki ^a  

^a CHIBA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; CRYSTALLIZATION; ELECTROPHORESIS; IONS; ORGANIC SOLVENTS; SOLUTIONS; THERMAL EFFECTS;

ALKALI METAL IONS; IONIC SIZE; POLAR SOLVENTS; SOLVATION;

CROWN ETHERS;

EID: 23044444205     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je050045l     Document Type: Article

References (18)

1. Katsuta, S.; Ito, Y.; Takeda, Y. Stabilities in Nitromethane of Alkali Metal Ion Complexes with Dibenzo-18-crown-6 and Dibenzo-24-crown-8 and Their Transfer from Nitromethane to Other Solvents. Inorg. Chim. Acta 2004, 357, 541-547.
2. Katsuta, S.; Tachibana, H.; Takeda, Y. Stabilities in Water of Alkali Metal Ion Complexes with Dibenzo-24-crown-8 and Dibenzo-18-crown-6 and Their Transfer Activity Coefficients from Water to Nonaqueous Solvents. J. Solution Chem. 2002, 31, 499-510.
3. Frensdorff, H. K. Stability Constants of Cyclic Polyether Complexes with Univalent Cations. J. Am. Chem. Soc. 1971, 93, 600-606.
4. Chantooni, M. K., Jr.; Roland, G.; Kolthoff, I. M. Transfer Activity Coefficients of Crown Ethers and Their Complexes with Univalent Metal Ions between Pairs of Polar Organic Solvents. J. Solution Chem. 1988, 17, 175-189.
5. Izatt, R. M.; Clark, G. A.; Lamb, J. D.; King, J. E.; Christensen, J. J. Log K, ΔH, and TΔS Values for the Reaction of Several Uniand Bivalent Metal Ions with Several Unsubstituted Cyclic Polyethers and Their Benzo-substituted Derivatives. Thermochim. Acta 1986, 97, 115-126.
6. Harris, E. J.; Zaba, B.; Truter, M. R.; Parsons, D. G.; Wingfield, J. N. Specificities of Cation Permeabilities Induced by Some Crown Ethers in Mitochondria. Arch. Biochem. Biophys. 1977, 182, 311-320.
7. Goff, C. M.; Matchette, M. A.; Shabestary, N.; Khazaeli, S. Complexation of Cesium and Rubidium Cations with Crown Ethers in N,N-Dimethylformamide. Polyhedron 1996, 15, 3897-3903.
8. Kolthoff, I. M.; Chantooni, M. K., Jr. Transfer Activity Coefficients in Various Solvents of Several Univalent Cations Complexed with Dibenzo-18-crown-6. Anal. Chem. 1980, 52, 1039-1044.
9. 4B Convention. J. Chem. Soc., Faraday Trans. 1 1984, 80, 2843-2849.
10. Pauling, L. The Nature of the Chemical Bond, 3rd ed.; Cornell University Press: Ithaca, NY, 1960.
11. Kirchnerová, J.; Cave, G. C. B. The Solubility of Water in Low-dielectric Solvents. Can. J. Chem. 1976, 54, 3909-3916.
12. Barton, A. F. M. CRC Handbook of Solubility Parameters and Other Cohesion Parameters, 2nd ed.; CRC Press: Boca Raton, FL, 1991.
13. Yajima, S.; Yahata, T.; Takeda, Y. Extraction of Alkali Metal (NaCs) Picrates with Dibenzo-18-crown-6 into Various Organic Solvents. Elucidation of Fundamental Equilibria which Govern the Extraction-ability and -selectivity. J. Inclusion Phenom. 2000, 38, 305-322.
14. Takeda, Y.; Taguchi, R.; Katsuta, S. Study on Solute-Solvent and Solute-Solute Interactions for the Dibenzo-24-crown-8-Alkali Metal Picrate Extraction System. J. Mol. Liq. 2004, 115, 139-147
15. Riddick, J. A.; Bunger, W. B.; Sakano, T. K. Organic Solvents: Physical Properties and Methods of Purification, 4th ed.; Wiley: New York, 1986.
16. Cox, B. G.; Garcia-Rosas, J.; Schneider, H. Solvent Dependence of the Stability of Cryptate Complexes. J. Am. Chem. Soc. 1981, 103, 1384-1389.
17. Danil de Namor, A. F.; Ghousseini, L. Thermodynamics of Metal-ion Cryptates and Cryptand 222 in N,N-Dimethylformamide and Dimethyl Sulphoxide. J. Chem. Soc., Faraday Trans. 1 1984, 80, 2349-2360.
18. Chantooni, M. K., Jr.; Kolthoff, I. M. Relation between Stability Constants of Metal Ion Cryptates in Two Solvents and the Transfer Activity Coefficients of the Metal Ions. J. Solution Chem. 1985, 14, 1-12.