Cadmium and mercury uptake by galena crystals under hydrothermal growth: A spectroscopic and element thermo-release atomic absorption study

European Journal of Mineralogy

Volumn 17, Issue 4, 2005, Pages 599-610

  Tauson, Vladimir L ^a   Parkhomenko, Irina Yu ^a   Babkin, Dmitriy N ^a   Men'shikov, Vitaliy I ^a   Lustenberg, Esfir E ^a  

^a VINOGRADOV INSTITUTE OF GEOCHEMISTRY   (Russian Federation)

Author keywords

AES; Atomic absorption spectrometry; Cadmium; Distribution coefficients; Element thermo release speciation; Galena; Hydrothermal growth; Mercury; XPS

Indexed keywords

ABSORPTION SPECTROSCOPY; ATOMIC ABSORPTION SPECTROMETRY; ATOMS; AUGER ELECTRON SPECTROSCOPY; BINDING ENERGY; CADMIUM; CADMIUM METALLOGRAPHY; CHLORINE COMPOUNDS; CRYSTAL IMPURITIES; CRYSTALS; LEAD COMPOUNDS; SPECTROSCOPIC ANALYSIS; SULFUR; SULFUR COMPOUNDS; SURFACE DEFECTS; TRACE ELEMENTS; X RAY PHOTOELECTRON SPECTROSCOPY;

BULK DISTRIBUTION COEFFICIENTS; DIFFERENT MECHANISMS; DISTRIBUTION COEFFICIENT; ELEMENT THERMO-RELEASE SPECIATION; GALENA; HYDROTHERMAL CONDITIONS; HYDROTHERMAL GROWTH; X-RAY PHOTOELECTRONS;

MERCURY (METAL);

ADSORPTION; CADMIUM; GALENA; HYDROTHERMAL DEPOSIT; MERCURY (ELEMENT);

EID: 23044432107     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2005/0017-0599     Document Type: Article

References (42)

1. Bethke, P.M. & Barton, P.B. (1971): Sub-solidus relations in the system PbS-CdS. Am. Miner., 56, 2034-2039.
2. Biester, H. & Scholz, C. (1997): Determination of mercury binding forms in contaminated soils: Mercury pyrolysis versus sequential extraction. Environ. Sci. Technol., 31, 233-239.
3. 2. Geochim. Cosmochim. Acta, 64, 247-255.
4. Briggs, D. & Riviere, J.C. (1983): Spectra interpretation. in "Practical surface analysis by Auger and X-ray photoelectron spectroscopy", D. Briggs & M.P. Seach, eds. John Wiley, Chichester e.a., 87-140.
5. Brown, J.R., Bancroft, G.M., Fyfe, W.S. (1979): Mercury removal from water by iron sulfide minerals. An electron spectroscopy for chemical analysis (ESCA) study. Environ. Sci. Technol., 13, 1142-1144.
6. Buckley, A.N. & Woods, R. (1984): An X-ray photoelectron spectroscopic study of the oxidation of galena. Appl. Surf. Sci., 17, 401-414.
7. Charnock, J.M., Moyes, L.N., Pattrick, R.A.D., Mosselmans, J.F.W., Vaughan, D.J., Livens, F.R. (2003): The structural evolution of mercury sulfide precipitates: An XAS and XRD study. Am. Miner., 88, 1197-1203.
8. De Giudici, G. & Zuddas, P. (2001): In situ investigation of galena dissolution in oxygen saturated solution: Evolution of surface features and kinetic rate. Geochim. Cosmochim. Acta, 65, 1381-1389.
9. Defay, R. & Prigogine, I. (1951): Tension superficielle et adsorption. Ed. Desoer, Liège.
10. Forssberg, K.S.E. & Jonsson, H. (1981): Adsorption of heavy metal ions on pyrrhotite. Scand. J. Met., 10, 225-230.
11. Genin, F., Alnot, M., Ehrhardt, J.J. (2001): Interaction of vapours of mercury with PbS (001): a study by X-ray photoelectron spectroscopy, RHEED and X-ray absorption spectroscopy. Appl. Surf. Sci., 173, 44-53.
12. Hyland, M.M., Jean, G.E., Bancroft, G.M. (1990): XPS and AES studies of Hg(II) sorption and desorption reactions on sulphide minerals. Geochim. Cosmochim. Acta, 54, 1957-1967.
13. Ikornikova, N.Yu., Egorov, V.M., Vasenin, A.R. (1970): Experimental PTFC-diagrams of ammonium chloride aqua solutions. Dokl. Akad. Nauk, SSSR, 192, 407-409 (in Russian).
14. Jean, G.E. & Bancroft, G.M. (1986): Heavy metal adsorption by sulphide mineral surfaces. Geochim. Cosmochim. Acta, 50, 1455-1463.
15. Karpov, I.K., Chudnenko, K.V., Kulik, D.A. (1997): Modeling chemical mass transfer in geochemical processes: Thermodynamic relations, conditions of equilibria, and numerical algorithms. Am. J. Sci., 297, 767-806.
16. Kim, C.S., Brown, G.E., Jr., Rytuba, J.J. (2000): Characterization and speciation of mercury-bearing mine wastes using X-ray absorption spectroscopy. Sci. Tot. Environ., 261, 157-168.
17. Manocha, A.S. & Park, R.L. (1977): Flotation related ESCA studies on PbS surfaces. Appl. Surf. Sci., 1, 129-141.
18. Mikhlin, Yu.L., Kuklinskiy, A.V., Pavlenko, N.I., Varnek, V.A., Asanov, I.P., Okotrub, A.V., Selyutin, G.E., Solovyev, L.A. (2002): Spectroscopic and XRD studies of the degradation of acid-reacted pyrrhotites. Geochim. Cosmochim. Acta, 66, 4057-4067.
19. Moulder, J.F., Stickle, W.F., Sobol, P.E., Bomben, K.D. (1992): Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corporation, Minnesota, 132 p.
20. Navrotsky, A. (1978): Thermodynamics of element partitioning: (1) Systematics of transition metals in crystalline and molten silicates and (2) Defect chemistry and "The Henry's law problem". Geochim. Cosmochim. Acta, 42, 887-902.
21. Nowak, P. & Laajalehto, K. (2000): Oxidation of galena surface - an XPS study of the formation of sulfoxy species. Appl. Surf. Sci., 157, 101-111.
22. Phillips, H.O. & Kraus, K.A. (1965): Adsorption on inorganic materials. VI. Reaction of insoluble sulfides with metal ions in aqueous media. J. Chromatogr., 17, 549-557.
23. Rabenau, A. (1973): Hydrothermal synthesis in acid solutions. in "Crystal growth: an introduction", P. Hartman, ed. North-Holland Publ. Co., Amsterdam, 198-209.
24. Rusanov, A.I. (1967): Phase equilibria and surface phenomena. Khimia, Leningrad (in Russian).
25. Seals, R.D., Alexander, R., Taylor, L.T., Dillard J.G. (1973): Core electron binding energy study of group IIb-VIIa compounds. Inorg. Chem., 12, 2485-2487.
26. Tauson, V.L. (1999): Gold solubility in the common gold-bearing minerals: Experimental evaluation and application to pyrite. Eur. J. Mineral., 11, 937-947.
27. Tauson, V.L., Paradina, L.F., Andrulaitis, L.D. (1986): The entry of mercury into galena and the new galena-sphalerite geothermometer. Geochem. Int., 23, 55-61.
28. Tauson, V.L., Men'shikov, V.I., Andrulaitis, L.D. (1989): Mercury in galena: Analysis of the forms of incorporation with respect to calibration of the sphalerite-galena geothermometer. Geokhimiya, 7, 936-949 (in Russian).
29. Tauson, V.L., Zubkov, V.S., Men'shikov, V.I. (1994): Mercury occurrence forms in the minerals of mercury ore formation. Geologia i Geofizika, 35, 54-69 (in Russian).
30. Tauson, V.L., Gelety, V.F., Men'shikov, V.I. (1996): Mercury speciation in mineral matter as an indicator of sources of contamination. in "Global and regional mercury cycles: Sources, fluxes and mass balances", W. Baeyens et al., eds. Kluwer Academic Publishers, Dordrecht, 441-452.
31. Tauson, V.L., Parkhomenko, I. Yu., Men'shikov, V.I. (1998): Determination of cadmium speciation in mineral matter. Russian Geology and Geophysics, 39, 474-479.
32. Tauson, V.L., Parkhomenko, I. Yu., Men'shikov, V.I., Nepomnyashchikh, K.V. (2002): The mechanism of incompatible element up-take during crystal growth. Russian Geology and Geophysics, 43, 171-176.
33. Tossell, J.V. & Vaughan, D.J. (1987): Electronic structure and the chemical reactivity of the surface of galena. Can. Mineral., 25, 381-392.
34. Toulmin, P., III & Barton, P.B., Jr. (1964): A thermodynamic study of pyrite and pyrrhotite. Geochim. Cosmochim. Acta, 28, 641-671.
35. Urusov, V.S. & Dudnikova, V.B. (1998): The trace-component trapping effect: Experimental evidence, theoretical interpretation, and geochemical applications. Geochim. Cosmochim. Acta, 62, 1233-1240.
36. Urusov, V.S., Tauson, V.L., Akimov, V.V. (1997): Geochemistry of solids. GEOS, Moscow.
37. Van den Broek, W.M.G.T. & De Galan, L. (1977): Supply and removal of sample vapor in graphite thermal atomizers. Anal. Chem., 49, 2176-2186.
38. Varekamp, J.C. & Buseck, P.R. (1984): The speciation of mercury in hydrothermal systems, with application to ore deposition. Geochim. Cosmochim. Acta, 48, 177-185.
39. Wagner, C.D., Naumkin, A.V., Kraut-Vass, A., Allison, J.W., Powell, C.J., Rumble, J.R., Jr. (2000): NIST X-ray Photoelectron Database, Ver.3.0 (Web version).
40. Watson, E.B. (1996): Surface enrichment and trace-element uptake during crystal growth. Geochim. Cosmochim. Acta, 60, 5013-5020.
41. Watson, E.B. & Liang, Y. (1995): A simple model for sector zoning in slowly grown crystals: Implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks. Am. Miner., 80, 1179-1187.
42. Widler, A.M. & Seward, T.M. (2002): The adsorption of gold (I) hydrosulphide complexes by iron sulfide surfaces. Geochim. Cosmochim. Acta, 66, 383-402.