Miscible polyisoprene/polystyrene blends: Distinct segmental dynamics but homogeneous terminal dynamics

Macromolecules

Volumn 38, Issue 14, 2005, Pages 6216-6226

  He, Yiyong ^a   Lutz, T R ^a   Ediger, M D ^a   Pitsikalis, Marines ^b   Hadjichristidis, Nikos ^b   Von Meerwall, Ernst D ^c  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF ATHENS   (Greece)

^c UNIVERSITY OF AKRON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GORDON-TAYLOR MIXING RULE; HOMOGENEOUS TERMINAL DYNAMICS; POLYSTYRENE BLENDS; SEGMENTAL DYNAMICS;

DIFFUSION; MOLECULAR DYNAMICS; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE; POLYBUTADIENES; POLYETHYLENE OXIDES; POLYISOPRENES; POLYMER BLENDS; SOLUBILITY; THERMODYNAMICS;

POLYSTYRENES;

EID: 22944491741     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0505225     Document Type: Article

References (71)

1. Minnick, M. G.; Schrag, J. L. Macromolecules 1980, 13, 1690-1695.
2. Colby, R. H. Polymer 1980, 30, 1275-1278.
3. Roovers, J.; Toporowski, P. M. Macromolecules 1992, 25, 1096-1102.
4. Pathak, J. A.; Colby, R. H.; Floudas, G.; Jerome, R. Macromolecules 1999, 32, 2553-2561.
5. Chung, G. C.; Kornfield, J. A.; Smith, S. D. Macromolecules 1994, 27, 5729-5741.
6. Alegria, A.; Colmenero, J.; Ngai, K. L.; Roland, C. M. Macromolecules 1994, 27, 4486-4492.
7. Zawada, J. A.; Fuller, G. G.; Colby, R. H.; Fetters, L. J.; Roovers, J. Macromolecules 1994, 27, 6861-6870.
8. Adams, S.; Adolf, D. B. Macromolecules 1999, 32, 3136-3145.
9. Doxastakis, M.; Kitsiou, M.; Fytas, G.; Theodorou, D. N.; Hadjichristidis, N.; Meier, G.; Frick, B. J. Chem. Phys. 2000, 112, 8687-8694.
10. Min, B. C.; Qiu, X. H.; Ediger, M. D.; Pitsikalis, M.; Hadjichristidis, N. Macromolecules 2001, 34, 4466-4475.
11. Haley, J. C.; Lodge, T. P.; He, Y. Y.; Ediger, M. D.; von Meerwall, E. D.; Mijovic, J. Macromolecules 2003, 36, 6142-6151.
12. Zetsche, A.; Fischer, E. W. Acta Polym. 1994, 45, 168-175.
13. Cendoya, I.; Alegria, A.; Alberdi, J. M.; Colmenero, J.; Grimm, H.; Richter, D.; Frick, B. Macromolecules 1999, 32, 4065-4078.
14. Urakawa, O.; Sugihara, T.; Adachi, K. Polym. Appl. (Jpn.) 2002, 51, 10-17.
15. Lartigue, C.; Guillermo, A.; CohenAddad, J. P. J. Polym. Sci., Polym. Phys. 1997, 35, 1095-1105.
16. Lutz, T. R.; He, Y. Y.; Ediger, M. D.; Cao, H. H.; Lin, G. X.; Jones, A. A. Macromolecules 2003, 36, 1724-1730.
17. Chin, Y. H.; Inglefield, P. T.; Jones, A. A. Macromolecules 1993, 26, 5372-5378.
18. Composto, R. J.; Kramer, E. J.; White, D. M. Macromolecules 1988, 21, 2580-2588.
19. Kim, E.; Kramer, E. J.; Osby, J. O. Macromolecules 1995, 28, 1979-1989.
20. Urakawa, O.; Fuse, Y.; Hori, H.; Tran-Cong, Q.; Yano, O. Polymer 2001, 42, 765-773.
21. Yang, X. P.; Halasa, A.; Hsu, W. L.; Wang, S. Q. Macromolecules 2001, 34, 8532-8540.
22. Katana, G.; Fischer, E. W.; Hack, T.; Abetz, V.; Kremer, F. Macromolecules 1995, 28, 2714-2722.
23. Haley, J. C.; Lodge, T. P. J. Rheol. 2004, 48, 463-486.
24. Pathak, J. A.; Kumar, S. K.; Colby, R. H. Macromolecules 2004, 37, 6994-7000.
25. Rizos, A. K.; Fytas, G.; Semenov, A. N. J. Chem. Phys. 1995, 102, 6931-6940.
26. He, Y. Y.; Lutz, T. R.; Ediger, M. D. Macromolecules 2004, 37, 9889-9898.
27. Leroy, E.; Alegria, A.; Colmenero, J. Macromolecules 2002, 35, 5587-5590.
28. Ngai, K. L.; Roland, C. M. Rubber Chem. Technol. 2004, 77, 579-590.
29. Roland, C. M. Macromolecules 1987, 20, 2557-2563.
30. Lodge, T. P.; McLeish, T. C. B. Macromolecules 2000, 33, 5278-5284.
31. He, Y. Y.; Lutz, T. R.; Ediger, M. D. J. Chem. Phys. 2003, 119, 9956-9965.
32. He, Y. Y.; Lutz, T. R.; Ediger, M. D.; Lodge, T. P. Macromolecules 2003, 36, 9170-9175.
33. Arendt, B. H.; Krishnamoorti, R.; Kornfield, J. A.; Smith, S. D. Macromolecules 1997, 30, 1127-1137.
34. Zawada, J. A.; Ylitalo, C. M.; Fuller, G. G.; Colby, R. H.; Long, T. E. Macromolecules 1992, 25, 2896-2902.
35. A recent model from Haley et al. based upon the Lodge/ McLeish model is successful in anticipating the experimentally observed curvatures in plots of viscosity vs composition, and the predictions are in reasonable agreement with the data for several systems tested (ref 23).
36. Chapman, B. R.; Hamersky, M. W.; Milhaupt, J. M.; Kostelecky, C.; Lodge, T. P.; von Meerwall, E. D.; Smith, S. D. Macromolecules 1998, 31, 4562-4573.
37. Adachi, K.; Hirano, H. Macromolecules 1998, 31, 3958-3962.
38. Roland, C. M.; Ngai, K. L.; Santangelo, P. G.; Qiu, X. H.; Ediger, M. D.; Plazek, D. J. Macromolecules 2001, 34, 6159-6160.
39. He, Y. Y.; Lutz, T. R.; Ediger, M. D.; Ayyagari, C.; Bedrov, D.; Smith, G. D. Macromolecules 2004, 37, 5032-5039.
40. Hadjichristidis, N.; Iatrou, H.; Pispas, S.; Pitsikalis, M. J. Polym. Sci., Polym. Chem. 2000, 38, 3211-3234.
41. Kaplan, M. L.; Bovey, F. A.; Cheng, H. N. Anal. Chem. 1975, 47, 1703-1705.
42. He, Y. Y.; Lutz, T. R.; Ediger, M. D. Macromolecules 2003, 36, 8040-8048.
43. Lyerla, J. R.; Levy, G. C. Top. Carbon-13 NMR Spectrosc. 1974, 1, 79.
44. Heatley, F. Prog. Nucl. Magn. Reson. Spectrosc. 1979, 13, 47-85.
45. Heatley, F. Annu. Rep. NMR Spectrosc. 1988, 17, 179-230.
46. Gisser, D. J.; Glowinkowski, S.; Ediger, M. D. Macromolecules 1991, 24, 4270-4277.
47. Loewenstein, A. Advances in Nuclear Quadrupole Resonance; John Wiley & Sons: London, 1983; Vol. 5.
48. Bandis, A.; Wen, W. Y.; Jones, E. B.; Kaskan, P.; Zhu, Y.; Jones, A. A.; Inglefield, P. T.; Bendler, J. T. J. Polym. Sci., Polym. Phys. 1994, 32, 1707-1717.
49. Moe, N. E.; Qiu, X. H.; Ediger, M. D. Macromolecules 2000, 33, 2145-2152.
50. Qiu, X. H.; Moe, N. E.; Ediger, M. D.; Fetters, L. J. J. Chem. Phys. 2000, 113, 2918-2926.
51. Tammann, G.; Hesse, W. Z. Anorg. Allg. Chem. 1926, 156, 245.
52. Williams, M. L.; Landel, R. F.; Ferry, J. D. J. Am. Chem. Soc. 1955, 77, 3701-3707.
53. von Meerwall, E. D.; Ferguson, R. D. Comput. Phys. Commun. 1981, 21, 421-429.
54. von Meerwall, E. D.; Kamat, M. J. Magn. Reson. 1989, 83, 309-323.
55. von Meerwall, E. D.; Palunas, P. J. Polym. Sci., Polym. Phys. 1987, 25, 1439-1457.
56. Shim, S. E.; Parr, J. C.; von Meerwall, E.; Isayev, A. I. J. Phys. Chem. B 2002, 106, 12072-12078.
57. g and molecular weight cited in ref 36.
58. For the PS component, no junction effect is included as we assume that there is no significant difference in the segmental dynamics between a free end group and an end group connected to a (much faster) PI chain. For the PI component, we assume that there are four repeat units near the junction point for which the segmental dynamics are significantly slowed by the connected PS chain. In the Lodge/McLeish model we replace eq 13 with eqs 7 and 8 in ref 32.
59. Kant, R.; Kumar, S. K.; Colby, R. H. Macromolecules 2003, 36, 10087-10094.
60. Lutz, T. R.; He, Y. Y.; Ediger, M. D.; Pitsikalis, M.; Hadjichristidis, N. Macromolecules 2004, 37, 6440-6448.
61. Faller, R. Macromolecules 2004, 37, 1095-1101.
62. For PB/PVE, an "object" solution of entangled PB in oligomeric PVE and a "mirror" solution of entangled PVE in oligomeric PB were studied (ref 21), and the friction coefficients of the entangled component in each type of blend were extracted. Thus, the terminal activation energies of PB and PVE in Figure 7 are not from the same blend.
63. Tang, H.; Schweizer, K. S. J. Chem. Phys. 1986, 105, 779-791.
64. Milhaupt, J. M.; Chapman, B. R.; Lodge, T. P.; Smith, S. D. J. Polym. Sci., Polym. Phys. 1998, 36, 3079-3086.
65. Maconnachie, A.; Kambour, R. P.; White, D. M.; Rostami, S.; Walsh, D. J. Macromolecules 1984, 17, 2645-2651.
66. In Figure 7 from left to right, the five systems have thermodynamic interaction parameters (Χ) of -0.004, 0.002, -0.0002. 0.094, and -0.002 (refs 25 and 31).
67. He, Y. Y. Dynamic Properties in Miscible Polymer Blends and Copolymers. Ph.D. Thesis, University of Wisconsin-Madison, 2005.
68. Doxastakis, M.; Chrissopoulou, K.; Aouadi, A.; Frick, B.; Lodge, T. P.; Fytas, G. J. Chem. Phys. 2002, 116, 4707-4714.
69. Friedman, E. M.; Porter, R. S. Trans. Soc. Rheol. 1975, 19, 493.
70. Gordon, M.; Taylor, J. S. J. Appl. Chem. 1982, 2, 493.
71. 0 = 170 K, B = 393 K.