Reaction kinetics of carbon dioxide with diethanolamine in polar organic solvents

Separation Science and Technology

Volumn 40, Issue 9, 2005, Pages 1885-1898

  Park, Sang Wook ^a   Lee, Joon Wook ^a   Choi, Byoung Sik ^a   Lee, Jae Wook ^b  

^a Pusan National University   (South Korea)

^b Sogang University   (South Korea)

Author keywords

Absorption; Carbon dioxide; Diethanolamine; Organic solvent

Indexed keywords

ABSORPTION; AMINES; CARBON DIOXIDE; CARBONATES; CORRELATION METHODS; ORGANIC SOLVENTS; RATE CONSTANTS; SOLUBILITY;

DIETHANOAMINE; REACTION MECHANICS; SEMIBATCH STIRRED TANKS; SOLUBILITY PARAMETERS;

REACTION KINETICS;

CARBON DIOXIDE;

EID: 22944475804     PISSN: 01496395     EISSN: None     Source Type: Journal    
DOI: 10.1081/SS-200064536     Document Type: Article

References (30)

1. Astarita, G., Savage, D.W., and Bisio, A. (1983) Gas Treating with Chemical Solvents; John Wiley & Sons: New York, 7-11.
2. 2 in ethanolamines. Chem. Eng. Sci., 34: 443-446.
3. 2 and alkanolamine. Ind. Eng. Chem. Res., 43: 3413-3418.
4. 2 and alkanolamines both in aqueous and non-aqueous solution. An Overview. Chem. Eng. Commun., 144: 113.
5. Davis, R.A. and Sandall, O.C. (1993) Kinetics of the reaction of carbon dioxide with secondary amines in polyethylene glycol. Chem. Eng. Sci., 48: 3187-3193.
6. Pohorecki, R. and Mozenski, C. (1998) A new absorbent for carbon dioxide and hydrogen sulphide absorption process. Chem. Eng. Process., 37: 69-78.
7. Hua, L.Q., Shuo, Y., and Lin, T.J. (1999) A new complex absorbent used for improving propylene carbonate absorbent for carbon dioxide removal. Sep. Pur. Technol., 16: 133-138.
8. Sridharan, K. and Sharma, M.M. (1976) New systems and methods for the measurement of effective interfacial area and mass transfer coefficients in gas-liquid contractors. Chem. Eng. Sci., 31: 767-774.
9. 2 with amines in pseudo m-nth order conditions in polar and viscous organic solutions. Chem. Eng. Sci., 36: 1513-1518.
10. Alvarez-Fuster, C., Midoux, N., Laurent, A., and Charpenter, J.C. (1981) Chemical kinetics of the reaction of carbon dioxide with amines in pseudo m-nth order conditions in aqueous and organic solutions. Chem. Eng. Sci., 36: 1717-1723.
11. Sada, E., Kumazawa, H., Han, Z.Q., and Matsuyama, H. (1985) Chemical Kinetics of the reaction of carbon dioxide with ethnolamines in non-aqueous solvents. AIChE. J., 31: 1297-1303.
12. Sada, E., Kumazawa, H., and Han, Z.Q. (1986) Chemical absorption of carbon dioxide into ethanolamine solutions of polar solvents. AIChE. J., 32: 347-349.
13. 2 and alkanolamine both in aqueous and non-aqueous solutions-I. Primary and secondary amines. Chem. Eng. Sci., 43: 573-585.
14. 2 and alkanolamine both in aqueous and non-aqueous solutions-II. Tertiary amines. Chem. Eng. Sci., 43: 587-591.
15. Sada, E., Kumazawa, H., Ikehara, Y., and Han, Z.Q. (1989) Chemical kinetics of the reaction of carbon dioxide with triethanolamine in non-aqueous solvents. Chem. Eng. J., 40: 7-12.
16. 2 and diethanolamine in aqueous ethylene glycol at 298 K: A viscous gas-liquid reaction system for the determination of interfacial areas in gas-liquid contactors. Chem. Eng. Sci., 45: 3283-3298.
17. Ali, S.H., Merchant, S.Q., and Fahim, M.A. (2000) Kinetic study of reactive absorption of some primary amines with carbon dioxide in ethanol solution. Sep. Pur. Technol., 18: 163-175.
18. 2 and alkanolamines in aqueous solutions. Chem. Eng. Sci., 39: 207-225.
19. Caplow, M. (1968) Kinetics of carbamate formation and breakdown. J. Am. Chem. Soc., 90: 6795-6803.
20. 2 and diethanolamine at 298 K. Chem. Eng. Sci., 44: 1264-1268.
21. Daraiswany, L.K. and Sharma, M.M. (1984) Heterogeneous Reaction: Analysis, Example and Reactor Design; John Wiley & Sons: New York, 17-26.
22. Park, S.W., Cho, H.B., Sohn, I.J., and Kumazawa, H. (2002) Gas absorption into w/o emulsion with aqueous amine liquid droplets. Sep. Sci. Technol., 37: 639-661.
23. Kennard, M.L. and Meisen, A. (1984) Solubility of carbon dioxide in aqueous diethanolamine solutions at elevated temperature and pressures. J. Chem. Eng. Data, 29: 309-312.
24. 2 in jet and falling films of electrolyte solutions with and without chemical reaction. Chem. Eng. Sci., 10: 88-104.
25. Danckwerts, P.V. and Sharma, M.M. (1966) The absorption of carbon dioxide into solutions of alkalis and amines. Chem. Eng., 10: 244-280.
26. Danckwerts, P.V. (1970) Gas-Liquid Reactions; McGraw-Hill Book Co: New York, 15.
27. Weast, R. and Astle, M.J. (1979) CRC Handbook of Chemistry and Physics; CRC Press, Inc.: Florida, E56-E59.
28. Brandrup, J. and Immergut, J.E. (1975) Polymer Handbook, Second Ed.; John Wiley & Sons: New York.
29. Herbrandson, H.F. and Neufeld, F.R. (1966) Organic reactions and the critical energy density of the solvent. The solubility parameter as a new solvent parameter. J. Org. Chem., 31: 1140-1143.
30. Hikita, H., Asai, S., Ishikawa, H., and Honda, H. (1977) The kinetics of reaction of carbon dioxide with monoethanolamie, diethanolamie, and triethanolamie by a rapid mixing method, 13: 7-12.