Ion dynamics in 0.3[xM2O.(1-x)Me2O].0.7B 2O3 (M, Me=Li, Na, K) mixed alkali glasses

Physics and Chemistry of Glasses

Volumn 46, Issue 2, 2005, Pages 182-186

  Gao, Y ^a   Cramer, C ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

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EID: 22844446912     PISSN: 00319090     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Conference Paper

References (48)

1. Funke, K. & Cramer, C. Conductivity spectroscopy. Curr. Opin. Solid State Chem. Sci., 1997, 2, 483;
2. Funke, K. & Cramer, C. Encyclopedia of Materials, Science and Technology. Edited by K. H. Buschow, R. W. Cahn, M. C. Flemings. B. Ilschner, E. J. Kramer & S. Mahajan. Elsevier, Oxford, Vol. 1, 189-94.
3. Isard, J. O. The mixed alkali effect in glass. J. Non-Cryst. Solids, 1969, 1, 235.
4. Day, D. E. Mixed alkali glasses - their properties and uses. J. Non-Cryst. Solids, 1976, 21, 343.
5. Stebbins, J. F. Cation sites in mixed-alkali oxide glasses: correlations of NMR chemical shift data with site size and bond distance. Solid State Ionics, 1998, 112, 137.
6. Uchino, T. & Yoko, T. Sodium and lithium environments in single- and mixed-alkali silicate glasses, an ab initio molecular orbital study. J. Phys. Chem. B, 1999, 103, 1854.
7. Schoo, U., Cramer, C. & Mehrer, H. Tracer diffusion in sodium-rubidium borate glasses - an unconventional mixed alkali effect. Solid State Ionics, 2000, 138, 105.
8. Bruce, J. A., Howie, R. A. & Ingram, M. D. Mechanisms of mixed cation effects in β-alumina. Solid State Ionics, 1986, 18-19, 1129.
9. Kleppa, O. J. & Hersh, L. S. Heats of mixing in liquid alkali nitrate systems. J. Chem. Phys., 1961, 34, 351;
10. 3 systems. Z. Naturforsch. A, 1974, 29, 497.
11. Jain, H., Dowing, H. L. & Peterson, N. L. The mixed alkali effect in lithium-sodium borate glasses. J. Non-Cryst. Solids, 1984, 64, 335.
12. 3 mixed alkali glasses. Phys. Chem. Chem. Phys., 2002, 4, 3219;
13. 3. J. Non-Cryst. Solids, 2004, 333, 231.
14. 5 glasses. Solid State Ionics, 1992, 53-56, 1194;
15. Jain, H. & Lu, X. Is there a mixed alkali effect in the low temperature ac conductivity of glasses. J. Non-Cryst. Solids, 1996, 196, 285;
16. Shelby, J. E. Properties of alkali-alkaline earth metaphosphate glasses. J. Non-Cryst. Solids, 2000, 263-264, 271;
17. 3 glasses. Phys. Rev. B, 2003, 68, 64202.
18. 3. J. Phys. Chem. Solids, 1988, 49, 35.
19. Hakim, R. M. & Uhlmann, D. R. On the mixed alkali effect in glasses. Phys. Chem. Glasses, 1967, 8(5), 174-7.
20. Gemert, W. J. Th., van Ass, H. M. J. M. & Stevels, J. M. Internal friction and dielectric losses of mixed alkali borate glasses. J. Non-Cryst. Solids, 1974, 16, 281.
21. Downing, H. L., Peterson, N. L. & Jain, H. Mixed isotope electrical conductivity in lithium borate glasses. J. Non-Cryst. Solids, 1982, 50, 203.
22. 3 glasses: a structure and dielectric investigation. Phys. Chem. Glasses, 2000, 41 (5), 242-6.
23. Han, Y. H., Kreidl, N. J. & Day, D. E. Alkali diffusion and electrical conductivity in sodium borate glasses. J. Non-Cryst. Solids, 1979, 30 (3), 241.
24. Shelby, Jnr., J. E. & Day, D. E. Mechanical relaxations in mixed alkali silicate glasses. Part 1. Results. J. Am. Ceram. Soc., 1969, 52 (4), 169;
25. Shelby, Jnr., J. E. & Day, D. E. Mechanical relaxations in mixed alkali silicate glasses. Part 2. Discussion. J. Am. Ceram. Soc., 1969, 52 (4), 169.
26. Ratai, E., Janssen, M. & Eckert, H. Spatial distribution and chemical environment of cations in single- and mixed-alkali borate glasses: evidence from solid state NMR. Solid State Ionics, 1998, 105, 25;
27. Ratai, E., Chan, J. C. C. & Eckert, H. Local coordination and spatial distribution of cations in mixed-alkali borate glasses. Phys. Chem. Chem. Phys., 2002, 4, 3198.
28. Jonscher, A. K. Dielectric Relaxation in Solids. Chelsea Dielectric, London, 1983;
29. Jonscher, A. K. The 'universal' dielectric response. Nature, 1977, 267, 673.
30. Almond, D. P. & West, A. R. Mobile ion concentrations in solid state electrolytes from an analysis of ac conductivity. Solid State Ionics, 1983, 9-10, 277.
31. Lee, W.-K., Liu, J. F. & Nowick, A. S. Limiting behaviour of ac conductivity in ionically conducting crystals and glasses: a new universality. Phys. Rev. Lett., 1991, 67, 1559;
32. Nowick, S., Vaysleyb, A. V. & Liu, W. Identification of distinctive regimes of behaviour in the ac electrical response of glasses. Solid State Ionics, 1998, 105, 121.
33. Funke, K., Roling, B. & Lange, M. Dynamics of mobile ions in crystals, glasses and melts. Solid State Ionics, 1998, 105, 195;
34. Schroøder, T. B. & Dyre, J. C. Scaling and universality of ac conduction in disordered solids. Phys. Rev. Lett., 2000, 84, 310.
35. Summerfield, S. & Butcher, P. N. Universal behaviour of ac hopping conductivity in disordered systems. J. Non-Cryst. Solids, 1985, 77-78, 135.
36. Cramer, C., Brückner, S., Gao, Y. & Funke, K. Ion dynamics in mixed alkali glasses. Phys. Chem. Chem. Phys., 2002, 4, 3214.
37. Roling, B., Funke, K., Happe, A. & Ingram, M. D. Carrier concentrations and relaxation spectroscopy: new information from scaling properties of conductivity spectra in ionically conducting glasses. Phys. Rev. Lett., 1997, 78, 2160.
38. Bunde, A., Ingran, M. D., Maass, P. & Ngai, K. L. Diffusion with memory: a model for mixed alkali effects in vitreous ionic conductors. J. Phys. A, 1991, 24, L881;
39. Bunde, A., Ingram, M. D., Maass, P. & Ngai, K. L. Mixed alkali effect in ionic conductors: a new model and computer simulations. J. Non-Cryst. Solids, 1991, 131, 1109;
40. Bunde, A., Ingram, M. D. & Maass, P. The dynamic structure model for ion transport in glasses. J. Non-Cryst. Solids, 1994, 172-174, 1222.
41. Greaves, G. N., Catlow, C. R. A., Vessal, B., Charnock, J., Henderson, C. M. B., Zhu, R., Qiao, S., Wang, Y., Gurman, S. J. & Houde-Walter, S. Proc. Second Int. Symp on New Materials and Their Applications. Edited by D. Holland, IOP Conf. Proc., Institute of Physics and Physical Society, London, 1990, No. 111, p. 411.
42. Pauling, L. Die Nature der Chemischen Bindung. Verlag Chemie, Weinheim, 1962;
43. Spice, J. E. Chemische Bindung und Struktur. Akademische Verlagsgesellschaft, Geest & Portg, K.-G., Leipzig, 1971;
44. Kelly, A. & Groves, G. W. Crystallography and Crystal Defects. J. W. Arrowsmith Ltd, Longman Group, Bristol, 1973.
45. Cotton, F. A. & Wilkinson, G. Anorganische Chemie. VEB Deutscher Verlag der Wissenschaften, Berlin, 1970.
46. Tennert, R. M. Science Data Book. Oliver and Boyd, Longman Group, Edinburgh, 1986.
47. 3 glasses: evidence for a new matrix-mediated coupling mechanism in mixed-cation glasses. Phys. Chem. Chem. Phys., 2002, 4, 320;
48. Ingram, M. D. & Roling, B. The concept of matrix-mediated coupling: a new interpretation of mixed-cation effects in glass. J. Phys.: Condens. Matter, 2003, 15, S1595.