The first example of an ansa-bis(cyclopentadienyl)aluminum compound. X-ray crystallographic characterization of [Me4C2(C 5H4)2Al-μ-Cl]2 and its monomeric THF and t-BuNC adducts. NMR spectroscopic characterization of the structures and fluxional behavior of these compounds in solution

Polyhedron

Volumn 24, Issue 11, 2005, Pages 1366-1381

  Shapiro, Pamela J ^a   Lee, Suh Jane ^a   Perrotin, Philippe ^a   Cantrell, Timothy ^a   Blumenfeld, Alexander ^a   Twamley, Brendan ^a  

^a UNIVERSITY OF IDAHO   (United States)

Author keywords

2 D NMR; Ansa aluminocene; Ansa magnesocene; Fluxional; NMR line shape analysis; Sigmatropic rearrangements

Indexed keywords

ACTIVATION ANALYSIS; ALUMINUM CHLORIDE; ALUMINUM HYDROXIDE; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

2-D NMR; ANSA-ALUMINOCENE; ANSA-MAGNESOCENE; CYCLOPENTADIENYL RINGS; FLUXIONAL; MAGNESOCENE; MONOMERICS; NMR LINE SHAPE ANALYSIS; SIGMATROPIC REARRANGEMENTS; STRUCTURE BEHAVIOR;

X RAY CRYSTALLOGRAPHY;

EID: 22844441736     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2005.04.014     Document Type: Article

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