High-frequency and -field EPR investigation of a manganese(III) N-confused porphyrin complex, [Mn(NCTPP)(py)2]

Inorganic Chemistry

Volumn 44, Issue 13, 2005, Pages 4451-4453

  Harvey, John D ^a   Ziegler, Christopher J ^a   Telser, Joshua ^b   Ozarowski, Andrew ^c   Krzystek, J ^c  

^a UNIVERSITY OF AKRON   (United States)

^b ROOSEVELT UNIVERSITY   (United States)

^c FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 22544467468     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0506759     Document Type: Article

References (31)

1. Abbreviations used: EPR, electron paramagnetic resonance; HFEPR, high-frequency and -field EPR; AOM, angular overlap model; bpea, N,N′-bis(2-pyridylmethyl)ethylamine; dbm, anion of 1,3-diphenyl-1,3- propanedione (dibenzoylmethane); DEHMC, trianion of 8,12-diethyl-2,3,7,13,17,18- hexamethylcorrole; DFT, density functional theory; NCP, N-confused porphyrin; NCTPP, trianion of 5,10,15,20-tetraphenyl-N-confused porphyrin; py, pyridine; terpy, 2,2′:6′,2″-terpyridine; zfs, zero-field splitting.
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