Synthesis and structure of a triruthenium complex containing a perpendicularly coordinated μ3-η2:η2(⊥)- nitrile ligand and its protonation to yield a perpendicularly coordinated iminoacyl ligand

Organometallics

Volumn 24, Issue 14, 2005, Pages 3371-3374

  Takao, Toshiro ^a   Kawashima, Takashi ^a   Matsubara, Kouki ^a   Suzuki, Hiroharu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; SURFACE CHEMISTRY; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; TRANSITION METALS; X RAY DIFFRACTION ANALYSIS;

CARBONYL CLUSTERS; IMINOACYL LIGANDS; TRANSITION METAL COMPLEXES; TRIRUTHENIUM COMPLEX;

ORGANOMETALLICS;

EID: 22444444030     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050320x     Document Type: Article

References (40)

1. (a) Takao, T.; Takaya, Y.; Murotani, E.; Tenjimbayashi, R.; Suzuki, H. Organometalllcs 2004, 23, 6094.
2. (b) Takao, T.; Kakuta, S.; Tenjimbayashi, R.; Takemori, T.; Murotani, E.; Suzuki, H. Organometalllcs 2004, 23, 6090.
3. (a) Schilling, B. E. R.; Hoffmann, R. J. Am. Chem. Soc. 1979, 101, 3456.
4. (b) Hofmann, D. M.; Hofmann, R.; Fisel, C. R. J. Am. Chem. Soc. 1982, 104, 3858.
5. (c) Halet, J. F.; Saillard, J. Y.; Lissillour, R.; McGlinchey, M. J.; Jaouen, G. Inorg. Chem. 1985, 24, 218.
6. Inagaki, A.; Takemori, T.; Suzuki, H. Angew. Chem., Int. Ed. 2000, 39, 404.
7. (a) Muetterties, E. L. J. Organomet. Chem. 1980, 200, 177.
8. (b) Muetterties, E. L.; Rhodin, T. N.; Band, E.; Brucker, C. F.; Pretzer, W. R. Chem. Rev. 1979, 79, 91.
9. (c) Band, E.; Muetterties, E. L. Chem. Rev. 1978, 78, 639.
10. (d) Zaera, F. Chem. Rev. 1995, 95, 2651.
11. (e) Sappa, E.; Tiripicchio, A.; Braunstein, O. Chem. Rev. 1983, 83, 203.
12. See, for example: (a) Michelin, R. A.; Mozzon, M.; Bertani, R. Coord. Chem. Rev. 1996, 147, 299.
13. (b) De Bellefon, C.; Fouilloux, P. Catal. Rev., Sci. Eng. 1994, 36, 459.
14. (c) Storhoff, B. N.; Lewis, H. C., Jr. Coord. Chem. Rev. 1977, 23, 1 and references therein.
15. (a) Chisholm, M. H.; Cotton, F. A.; Extine, M. W.; Rankel, L. A. J. Am. Chem. Soc. 1978, 100, 807.
16. (b) Feng, Q.; Ferrer, M.; Green, M. L. H.; McGowan, P. C.; Mountford, P.; Mtetwa, V. S. B. J. Chem. Soc., Chem. Commun. 1991, 552.
17. (c) Alonso, F. J. G.; Sanz, M. G.; Riera, V.; Abrill, A. A.; Tiripicchio, A.; Ugozzoli, F. Organometallics 1992, 11, 801.
18. (d) Feng, Q.; Ferrer, M.; Green, M. L. H.; Mountford, P.; Mtetwa, V. S. B. J. Chem. Soc., Dalton Trans. 1992, 1205.
19. (e) Eglin, J. L.; Hines, E. M.; Valente, E. J.; Zubkowski, J. D. Inorg. Chim. Acta 1995, 229, 113.
20. (f) Cotton, F. A.; Kühn, F. E. J. Am. Chem. Soc. 1996, 118, 5826.
21. (g) Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Wang, X. Polyhedron 1998, 17, 2781.
22. (a) Andrews, M. A.; Kaesz, H. D. J. Am. Chem. Soc. 1979, 101, 7255.
23. (b) Andrews, M. A.; Kaesz, H. D. J. Am. Chem. Soc. 1979, 101, 7260.
24. (c) Keller, E.; Wolters, D. Chem. Ber. 1984, 117, 1572.
25. (d) Suter, P.; Vahrenkamp, H. Chem. Ber. 1995, 128, 793.
26. (e) Bantel, H.; Hansert, B.; Powell, A. K.; Tasi, M.; Vahrenkamp, H. Angew. Chem., Int. Ed. Engl. 1989, 28, 1059.
27. Tada, K.; Oishi, M.; Suzuki, H. Organometallics 1996, 15, 2422.
28. 5), 96.8 (s, CN).
29. tBu group inside of the Rua core, was also confirmed by the X-ray studies, but precise discussion about the structural parameters was prevented due to the disordered structures around the coordinated nitrile group. The results of the diffraction studies of 3b are given in the Supporting Information.
30. Riehl, J.-F.; Koga, N.; Morokuma, K. Organometallics 1994, 13, 4765.
31. Kukushkin, V. Y.; Pombeiro, A. J. L. Chem. Rev. 2002, 102, 1771.
32. Shin, J. H.; Savage, W.; Murphy, V. J.; Bonanno, J. B.; Churchill, D. G.; Parkin, G. Dalton 2001, 1732.
33. 5), 153.2 (s, CN).
34. (a) Andrews, M. A.; Kaesz, H. D. J. Am. Chem. Soc. 1979, 101, 7238.
35. (b) Andrews, M. A.; Buskirk, G.; Knobler, C. B.; Kaesz, H. D. J. Am. Chem. Soc. 1979, 101, 7245.
36. (b) Adams, R. D.; Katahira, D. A.; Yang, L. J. Organomet. Chem. 1981, 219, 85.
37. (c) Dawoodi, Z.; Mays, M. J.; Raithby, P. R. J. Organomet. Chem. 1981, 219, 103.
38. (d) Banford, J.; Mays, M. J.; Raithby, P. R. J. Chem. Soc., Dalton Trans. 1985, 1355.
39. (e) Berhardt, W.; Schnering, C.; Vahrenkamp, H. Angew. Chem., Int. Ed. Engl. 1986, 25, 279.
40. 3. The final structure for 4a was refined to R1 = 0.0452 and wR2 = 0.0923 for 15 265 observed reflections (I > 2σ) and 889 parameters.