Effect of water content on the kinetics of p-xylene liquid-phase catalytic oxidation to terephthalic acid

Industrial and Engineering Chemistry Research

Volumn 44, Issue 13, 2005, Pages 4518-4522

  Wang, Qinbo ^a   Li, Xi ^a   Wang, Lijun ^a   Cheng, Youwei ^a   Xie, Gang ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; COBALT COMPOUNDS; ELECTRON TRANSITIONS; HYDROGEN; MANGANESE COMPOUNDS; OXIDATION; RATE CONSTANTS; XYLENE;

LIQUID-PHASE OXIDATION; REACTION SYSTEMS; TEREPHTHALIC ACID; WATER CONTENT;

WATER;

XYLENE;

EID: 22444437325     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie048755s     Document Type: Article

References (28)

1. Raghavendrachar, P.; Ramachadran, S. Liquid-phase Catalytic Oxidation of p-Xylene. Ind. Eng. Chem. Res. 1992, 31 (2), 453-462.
2. Brill, W. F. Terephthalic Acid by Single-Stage Oxidation. Ind. Eng. Chem. 1960, 52, 837-810.
3. Heiba, E. I.; Dessau, R. M.; Koehl, W. J. Oxidation by Metal Salts. Am. Chem. Soc., Div. Petrol. Chem. 1969, 14 (2), A44-A56.
4. Hanotier, J.; Hanotier-Bridoux, M. Mechanism of the Liquid-Phase Homogeneous Oxidation of Alkylaromatic Hydrocarbons by Cobalt Salts. J. Mol. Catal. 1981, 12 (2), 133-147.
5. Sheldon, R. A.; Kochi, J. K. Metal Catalyzed Oxidation of Organic Compounds; Academic Press: New York, 1981.
6. Kamiya Y. Catalysis by Cobalt and Bromide Ions in the Autoxidation of Alkyl Benzenes in Acetic Acid. J. Catal. 1974, 33, 480-485.
7. Hendriks, C.; Beek, H.; Heertjes, P. The Oxidation of Substituted Toluenes by Cobalt(III) Acetate in Acetic Acid Solution. Ind. Eng. Chem. Prod. Res. Dev. 1978, 17, 256-264.
8. Czytko, M. P.; Bub, G. K. Oxidation of Toluene by Cobalt(III) Acetate in Acetic Acid Solution. Influence of Water. Ind. Eng. Chem. Prod. Res. Dev. 1981, 20, 481-486.
9. Emanuel, N. M.; Gal, D. Modelling of Oxidation Processes; Akademiai Kiado: Budapest, Hungary, 1986.
10. Cavalieri d'Oro, P.; Danoczy, E.; Roffia, P. On the Low-Temperature Oxidation ofp-Xylene. Oxidation Commun. 1980, 1, 153-155.
11. Yan, X.; Du, W.; Qian, F. Development of a Kinetic Model for Industrial Oxidation of p-Xylene by RBF-PLS and CCA. AIChE J. 2004, 50 (6), 1169-1176.
12. Cao, G.; Pisu, M.; Morbidelli, M. A Lumped Kinetic Model for Liquid-phase Catalytic Oxidation of p-Xylene to Terephthalic Acid. Chem. Eng. Sci. 1994, 49 (24), 5775-5788.
13. Cao, G.; Servida, A.; Pisu, M. Kinetics of p-Xylene Liquid-phase Catalytic Oxidation. AIChE J. 1994, 40 (7), 1156-1166.
14. Cincotti, A.; Orrù, R.; Bori, A.; Cao, G. Effect of Catalyst Concentration and Simulation of Precipitation Processes on Liquid-phase Catalytic Oxidation of p-Xylene to Terephthalic Acid. Chem. Eng. Sci. 1997, 52 (21), 4205-4213.
15. Cincotti, A.; Orrù, R.; Cao, G. Kinetics and Related Engineering Aspects of Catalytic Liquid-phase Oxidation of p-Xylene to Terephthalic Acid. Catal Today 1999, 52, 331-347.
16. Wang, L. Studies on the Kinetics of p-Xylene Oxidation and the Reactor Simulation. MS Thesis, Zhejiang University, China, 2001.
17. Wang, Q.; Li, X.; Xie, G.; Cheng, Y.; Dai, W. Modeling of p-Xylene Oxidation Reactor-Condenser. J. Zhejiang Univ., Eng. Sci. 2004, 38(8), 1029-1034.
18. Wang, Q.; Li, X.; Wang, L.; Cheng, Y.; Xie, G. Kinetics of p-Xylene Liquid-Phase Catalytic Oxidation to Terephthalic Acid. Ind. Eng. Chem. Res. 2005, 44 (2), 261-266.
19. Hronec, M.; Cvengrosova, Z.; Ilsvsky, J. Kinetic and Mechanistic of Cobalt-Catalyzed Oxidation of p-Xylene in the Presence of Water. Ind. Eng. Chem. Prod. Res. Dev. 1985, 24, 787-794.
20. Aleksandrov, V. N. Effect of Water on the Catalytic Oxidation of Some Methyl-aromatic hydrocarbons in Acetic Acid at Elevated Temperatures. Kinet. Katal. 1979, 20 (2), 357-361.
21. Partenheimer, W. Methodology and Scope of Metal/ Bromide Autoxidation of Hydrocarbons. Catal. Today 1995, 23, 69-158.
22. Jones, G. H. A Kinetic and Mechanistic Study of the Redox Chemistry of Cobalt Acetate in Aqueous Acetic Acid. J. Chem. Res., Synop. 1981, 8, 228-229.
23. Jones, G. H. p-Xylene Autoxidation Studies. Oxidation of Cobalt(II) and Manganese(II) Acetates by Peracids. J. Chem. Soc., Chem. Commun. 1979, 12, 536-537.
24. Jones, G. H. A Mechanistic Study of the Origin of Synergy and Antagonism in the Co(OAc)Br- and Mn(OAc)Br-Catalyzed Autoxidation of p-Xylene. J. Chem. Res., Synop. 1982, 8, 207.
25. Partenheimer, W. The Structure of Metal/Bromide Catalysts in Acid/Water Mixtures and its Significance in Autoxidation. J. Mol. Catal. A: Chem. 2001, 174, 29-33.
26. Cheng, Y.; Zhang, L.; Xie, G.; Li, X. Experiment Technique of p-Xylene Liquid-phase Oxidation. Chem. React. Eng. Technol. (China) 2003, 19 (2), 182-186.
27. Dai, W.; Chen, X.; Cheng, Y.; Li, X. Effect of Water Content on Rate of Catalytic Oxidation of p-Xylene. Petrochemical Technol. (China) 2003, 32 (11), 933-936.
28. Adamyan, V. A.; Geletii, Yu. V.; Hronec, M.; Zakharov, I. V. Effect of Solvation on the Catalytic Activity of Co(II) in the Liquid-Phase Oxidation of Hydrocarbons in the Presence of Cobalt-Bromide Catalyst. Kinet. Katal. 1993, 34 (4), 646-650.