Kinetic experiments and modeling of a complex DeNO system: Decane selective catalytic reduction of NOx in the gas phase and over an Fe-MFI type zeolite catalyst

Industrial and Engineering Chemistry Research

Volumn 44, Issue 13, 2005, Pages 4523-4533

  Vradman, Leonid ^a   Herskowitz, Moti ^b   Čapek, Libor ^c   Wichterlova, Blanka ^c   Brosius, Roald ^d   Martens, Johan A ^d  

^a SAMI SHAMOON COLLEGE OF ENGINEERING   (Israel)

^b BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^d UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CONCENTRATION (PROCESS); HYDROCARBONS; ION EXCHANGE; KINETIC THEORY; OXIDATION;

GAS PHASE; REACTION CONDITIONS; SPACE VELOCITIES; ZEOLITE CATALYSTS;

ZEOLITES;

REDUCTION;

CATALYSTS; CONCENTRATION; HYDROCARBONS; ION EXCHANGE; KINETIC ENERGY; OXIDATION; ZEOLITES;

EID: 22444432591     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050337f     Document Type: Article

References (29)

1. Held, W.; König, A.; Richter, T.; Puppe, L. Catalytic nitrogen oxide (NOx) reduction in net oxidizing exhaust gas. SAE Trans. 1990, Section 4, No. 900, 209, 496.
2. Held, W.; König, A. (assigned to Volkswagen AG). Method and apparatus for reducing nitrogen oxides. German Patent Application 3642018, June 25, 1987.
3. 2 over copper ion-exchanged zeolites. Shokubai 1990, 32, 430.
4. Brosius, R.; Martens, J. A. Top. Catal. 2004, 28, 119.
5. Traa, Y.; Burger, B.; Weitkamp, J. Zeolite-based materials for the selective catalytic reduction of NOx with hydrocarbons. Microporous Mesoporous Mater. 1999, 30, 3.
6. Holma, T.; Palmqvist, A.; Skoglundh, M.; Jobson, E. Continuous lean NOx reduction with hydrocarbons over dual pore system catalysts. Appl. Catal. B 2004, 48, 95.
7. Ohtsuka, H.; Tabata, T.; Okada, O.; Sabatino, L. M. F.; Bellussi, G. A study on selective reduction of NOx by propane on Co-Beta. Catal. Lett. 1997, 44, 265.
8. Lukyanov, D. B.; Still, G.; d'Itri, J. L.; Hall, W. K. Comparison of Catalyzed and Homogeneous Reactions of Hydrocarbons for Selective Catalytic Reduction (SCR) of NOx. J. Catal. 1995, 153, 265.
9. Phillips, J.; Smith, J. Homogeneous Chemistry in Lean-Burn Exhaust Mixtures. J. Phys. Chem. A 1997, 101, 9157.
10. Cheung, C. C.; Kung, M. C. Influence of homogeneous decane oxidation on the catalytic performance of lean NOx catalysts. Catal. Lett. 1999, 61, 131.
11. Yokoyama, C.; Misono, M. Catalytic Reduction of Nitrogen Oxides by Propene in the Presence of Oxygen over Cerium Ion-Exchanged Zeolites: II. Mechanistic Study of Roles of Oxygen and Doped Metals. J. Catal. 1994, 150, 9.
12. Cordoba, L. F.; Flytzani-Stephanopoulos, M.; Montes de Correa, C. Lean NOx reduction with dodecane over cerium and palladium loaded mordenite. Appl. Catal. B 2001, 33, 25.
13. Yogo, K.; Umeno, M.; Watanabe, H.; Kikuchi, E. Selective reduction of nitric oxide by methane of H-form zeolite catalysts in oxygen-rich atmosphere. Catal. Lett. 1993, 19, 131.
14. Hamada, H.; Kintaichi, Y.; Sasaki, M.; Ito, T.; Tabata, M. Selective reduction of nitrogen monoxide with propane over alumina and HZSM-5 zeolite: effect of oxygen and nitrogen dioxide intermediate. Appl. Catal. 1991, 70, L15.
15. 2 over silver-containing zeolite catalysts. Angew. Chem. Int. Ed. Engl. 1998, 37, 1901.
16. Li, Z.; Flytzani-Stephanopoulos, M. On the Promotion of Ag-ZSM-5 by Cerium for the SCR of NO by Methane. J. Catal. 1999, 182, 313.
17. Kikuchi, E.; Ogura, M.; Terasaki, I.; Goto, Y. Selective Reduction of Nitric Oxide with Methane on Gallium and Indium Containing H-ZSM-5 Catalysts: Formation of Active Sites by Solid-State Ion Exchange. J. Catal. 1996, 161, 465.
18. 2 on the oxidation of NO over Fe-MFI and Feferrierite catalysts made by solid-state ion exchange. Appl. Catal. B 2000, 25, 75.
19. Misono, M.; Hirao, Y.; Yokoyama, C. Reduction of nitrogen oxides with hydrocarbons catalyzed by bifunctional catalysts. Catal. Today 1997, 38, 157.
20. 2-ferrierite. Chem. Commun. 2002, 948.
21. Martens, J. A.; Cauvel, A.; Jayat, F.; Vergne, S.; Jobson, E. Molecule sieving catalysts for NO reduction with hydrocarbons in exhaust of lean burn gasoline and diesel engines. Appl. Catal. B 2001, 29, 299.
22. Feng, X.; Hall, W. K. Fe/ZSM-5: A Durable SCR Catalyst for NOx Removal from Combustion Streams. J. Catal. 1997, 166, 368.
23. Chen, H.-Y.; Sachtier, W. M. H. Activity and durability of Fe/ZSM-5 catalysts for lean burn NOx reduction in the presence of water vapor. Catal. Today 1998, 42, 73.
24. Boulard, S.; Gilot, P.; Habermacher, D.; Brosius, R.; Martens, J. A. Perturbation and Tracer Chromatography Study of Hydrocarbon Adsorption from Simulated Exhaust Gas on Fe-MFI and MOR Type Zeolite Catalysts. Top. Catal. 2004, 30-37, 49.
25. Čapek, L.; Dědeček, J.; Wichterlová, B. Co-beta zeolite highly active in propane-SCR-NOx in the presence of watervapor: effect of zeolite preparation and Al distribution in the framework. J. Catal. 2004, 227, 352.
26. Brosius, R.; Habermacher, D.; Martens, J. A.; Vradman, L.; Herskowitz, M.; Čapek, L.; Sobalík, Z.; Dědeček, J.; Wichter-lova, B.; Tokarová, V.; Gonsiorová, O. NO Oxidation Kinetics on Iron Zeolites: Influence of Framework Type and Iron Speciation. Top. Catal. 2004, 30/31, 333.
27. Reid, R. C.; Prauznitz, J. H.; Shervood, T. K. The Properties of Gases and Liquids, 4th ed.; McGraw-Hill: New York, 1987.
28. Smith, J. M. Chemical Engineering Kinetics, 3th ed.; McGraw-Hill: Tokyo, 1981.
29. Froment, G. F.; Bischoff, K. B. Chemical reactors analysis and design, 2nd ed.; John Wiley & Sons: New York, 1990.