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0034680629
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0035812358
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16
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32744473674
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note
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2 for 12 h yielded selective formation of 2-nitrobenzaldehyde (17 TON) and 4-nitrobenzaldehyde (19 TON), respectively.
-
-
-
-
17
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-
32744456493
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-
note
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A ∼10% maximum yield is possible at 20 mM polyoxometalate, which represents the boundary of solubility of the catalyst. Dilution of the reaction medium inhibits the reaction.
-
-
-
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18
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32744468439
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note
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D = 4.3 was measured in a comparative experiment. Since the rates are low, the data for a competitive experiment were deemed more accurate.
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-
-
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19
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-
0042820136
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and references therein
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Cristiano, M. L. S.; Gago, D. J. P.; Rocha Gonsalves, A. M. d' A.; Johnstone, R. A. W.; McCaron, M.; Varejão, J. M. T. B. Org. Biomol. Chem, 2003, 1, 565-574 and references therein.
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Cristiano, M.L.S.1
Gago, D.J.P.2
Rocha Gonsalves, A.M.D'A.3
Johnstone, R.A.W.4
McCaron, M.5
Varejão, J.M.T.B.6
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23
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0033602890
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Urbanowicz, P.1
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Pasterny, K.4
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24
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0002112434
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(c) Shlyapochnikov, V. A.; Khaikin, L. S.; Grikina, O. E.; Bock, C. W.; Vilkov, L. V. J. Mol. Struct. 1994, 326, 1-16.
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Shlyapochnikov, V.A.1
Khaikin, L.S.2
Grikina, O.E.3
Bock, C.W.4
Vilkov, L.V.5
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25
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-
32744455683
-
-
note
-
51V(IV), that is associated with a reduced polyoxometalate.
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