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Volumn 127, Issue 28, 2005, Pages 9988-9989

Selective ortho hydroxylation of nitrobenzene with molecular oxygen catalyzed by the H5PV2Mo10O40 polyoxometalate

Author keywords

[No Author keywords available]

Indexed keywords

METAL DERIVATIVE; NITROBENZENE; OXYGEN; POLYOXOMETALLATE; UNCLASSIFIED DRUG;

EID: 22244493033     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja051286g     Document Type: Article
Times cited : (70)

References (26)
  • 1
    • 0002188505 scopus 로고    scopus 로고
    • A known exception is the oxidation of benzene by nitrous oxide cf.: (a) Panov, G. I. CATTECH 2000, 4, 18-32.
    • (2000) CATTECH , vol.4 , pp. 18-32
    • Panov, G.I.1
  • 16
    • 32744473674 scopus 로고    scopus 로고
    • note
    • 2 for 12 h yielded selective formation of 2-nitrobenzaldehyde (17 TON) and 4-nitrobenzaldehyde (19 TON), respectively.
  • 17
    • 32744456493 scopus 로고    scopus 로고
    • note
    • A ∼10% maximum yield is possible at 20 mM polyoxometalate, which represents the boundary of solubility of the catalyst. Dilution of the reaction medium inhibits the reaction.
  • 18
    • 32744468439 scopus 로고    scopus 로고
    • note
    • D = 4.3 was measured in a comparative experiment. Since the rates are low, the data for a competitive experiment were deemed more accurate.
  • 25
    • 32744455683 scopus 로고    scopus 로고
    • note
    • 51V(IV), that is associated with a reduced polyoxometalate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.