The influence of natural convection on the temporal development of the temperature and concentration fields for Sal'nikov's reaction, P → A → B, occurring batchwise in the gas phase in a closed vessel

Chemical Engineering Science

Volumn 60, Issue 21, 2005, Pages 5705-5717

  Campbell, A N ^a   Cardoso, S S S ^a   Hayhurst, A N ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

Cool flame; Kinetics; Modelling; Natural convection; Oscillations; Sal'nikov's reaction

Indexed keywords

ACTIVATION ENERGY; CONCENTRATION (PROCESS); DIFFUSION; HEAT TRANSFER; NUMERICAL METHODS; REACTION KINETICS;

EXOTHERMIC REACTIONS; RAYLEIGH NUMBERS; THERMOKINETIC OSCILLATIONS; ZERO ACTIVATION ENERGY;

NATURAL CONVECTION;

CONVECTION;

EID: 22244492277     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2005.04.062     Document Type: Article

References (19)

1. Campbell, A.N., Cardoso, S.S.S., Hayhurst, A.N., 2005. A scaling analysis of Sal'nikov's reaction, P → A → B, in the presence of natural convection and the diffusion of heat and matter. Proceedings of the Royal Society A, in press, doi: 10.1098/rspa.2005.1459.
2. S.S.S. Cardoso, P.C. Kan, K.K. Savjani, A.N. Hayhurst, and J.F. Griffiths The computation of the velocity, concentration and temperature fields during a gas-phase oscillatory reaction in a closed vessel with natural convection Combustion and Flame 136 2004 241 245
3. S.S.S. Cardoso, P.C. Kan, K.K. Savjani, A.N. Hayhurst, and J.F. Griffiths The effect of natural convection on the gas-phase Sal'nikov reaction in a closed vessel Physical Chemistry Chemical Physics 6 2004 1687 1696
4. R. Fairlie, and J.F. Griffiths A numerical study of spatial structure during oscillatory combustion in closed vessels in microgravity Faraday Discussions 120 2001 147 164
5. R. Fairlie, and J.F. Griffiths Oscillatory combustion in closed vessels under microgravity Mathematical and Computer Modelling 36 2002 245 257
6. Fastflo Tutorial Guide, (version 3) 2000. July 1999 (online), CSIRO, Australia.
7. L.K. Forbes Limit-cycle behaviour in a model chemical reaction: the Sal'nikov thermokinetic oscillator Proceedings of the Royal Society A 430 1990 641 651
8. Gray, B.F., 1975. Kinetics of oscillatory reactions, in: Specialist Periodical Reports, vol 1. The Chemical Society, London, pp. 309-386.
9. P. Gray, and J.F. Griffiths Thermokinetic combustion oscillations as an alternative to thermal explosion Combustion and Flame 78 1989 87 98
10. B.F. Gray, and M.J. Roberts Analysis of chemical kinetic systems over the entire parameter space I. The Sal'nikov thermokinetic oscillator Proceedings of the Royal Society A 416 1988 391 402
11. Gray, P., Scott, S.K., 1990. Chemical Oscillations and Instabilities. Clarendon Press, Oxford, pp. 83-111, 264-291.
12. P. Gray, S.R. Kay, and S.K. Scott Oscillations of an exothermic reaction in a closed system I. Approximate (exponential) representation of Arrhenius temperature-dependence Proceedings of the Royal Society A 416 1988 321 341
13. Griffiths, J.F., Barnard, J.A., 1995. Flame and Combustion, third ed. Blackie, Glasgow, pp. 181-205.
14. Griffiths, J.F., Kay, S.R., Scott, S.K., 1988. Oscillatory combustion in closed vessels: theoretical foundations and their experimental verification, in: Twenty-second Symposium (International) on Combustion. The Combustion Institute, Pittsburgh, PA, pp. 1597-1607.
15. S.R. Kay, and S.K. Scott Oscillations of simple exothermic reactions in a closed system. II. Exact Arrhenius kinetics Proceedings of the Royal Society A 416 1988 343 359
16. J.H. Knox The interpretation of cool flame and low-temperature combustion phenomena P.G. Ashmore F.S. Dainton T.M. Sugden Photochemistry and Reaction Kinetics 1967 Cambridge University Press Cambridge 250 286
17. H. Pearlman Low-temperature oxidation reactions and cool flames at Earth and reduced gravity Combustion and Flame 121 2000 390 393
18. I.E. Sal'nikov Contribution to the theory of the periodic homogeneous chemical reactions Zhurnal Fizicheskoi Khimii 23 1949 258 272
19. Turner, J.S., 1979. Buoyancy Effects in Fluids. Cambridge University Press, Cambridge, pp. 207-250.