Ammonium polyphosphate-aluminum trihydroxide antagonism in fire retarded butadiene-styrene block copolymer

European Polymer Journal

Volumn 41, Issue 9, 2005, Pages 2023-2033

  Castrovinci, A ^a   Camino, G ^a   Drevelle, C ^b   Duquesne, S ^b,c   Magniez, C ^d   Vouters, M ^d  

^a POLITECNICO DI TORINO   (Italy)

^b Ecole Nationale Superieure de Chimie de Lille   (France)

^c CREPIM Centre de Recherche et d'Etude sur les Procedes d'Ignifugation des Materiaux   (France)

^d Institut Textile de France   (France)

Author keywords

Aluminum trihydroxide; Ammonium polyphosphate; Flame retardancy; In situ ceramization; Styrene butadiene rubber; Surface protection

Indexed keywords

ALUMINUM COMPOUNDS; BUTADIENE; COMBUSTION; FLAME RETARDANTS; MOLECULAR STRUCTURE; STYRENE; SURFACE PROPERTIES; SYNTHETIC RUBBER;

ALUMINUM TRIHYDROXIDE; AMMONIUM POLYPHOSPHATE; FLAME RETARDANCY; IN SITU CERAMIZATION; STYRENE BUTADIENE RUBBER (SBR); SURFACE PROTECTION;

BLOCK COPOLYMERS;

EID: 22144434435     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2005.03.010     Document Type: Article

References (15)

1. C. Drevelle, S. Duquesne, M. Le Bras, J. Lefebvre, R. Delobel, and A. Castrovinci Influence of ammonium polyphosphate on the mechanism of thermal degradation of an acrylic binder resin J Appl Polym Sci 94 2 2004 717 729
2. J. Lefebvre, M. Le Bras, B. Lefort, C. Drevelle, S. Duquesne, and M. Vouters Effect of bonding resins on the flammability properties and thermal behaviour of cotton and cotton/PESFR woven fabrics J Ind Textiles 33 1 2003 55 72
3. S.M. Lomakin, and G.E. Zaikov New type of ecologically safe flame retardant based on polymer char former Polym Degrad Stab 54 1996 223 233
4. M. Lewin M. Le Bras G. Camino S. Bourbigot R. Delobel Physical and chemical mechanisms of flame retarding of polymers 1998 The Royal Society of Chemistry Cambridge 3 32
5. M. Le Bras, and S. Bourbigot M. Le Bras G. Camino S. Bourbigot R. Delobel Fire retarded intumescent thermoplastics formulations, synergy and synergistic agent-a review 1998 The Royal Society of Chemistry Cambridge 64 75
6. G. Camino, and M.P. Luda M. Le Bras G. Camino S. Bourbigot R. Delobel Mechanistic study on intumescence 1998 The Royal Society of Chemistry Cambridge 48 63
7. S. Bourbigot, M. Le Bras, R. Leeuwendal, K.K. Shen, and D. Schubert Recent advances in the use of zinc borates in flame retardancy of EVA Polym Degrad Stab 64 1999 419 425
8. Evans K. Thermally active fire retardants: aluminum hydroxide. In: Proceedings of the IMRA symposium "Flame retardant chemicals, market and trends", London, December 1986.
9. W.E. Horn A.F. Grand C.A. Wilkie Inorganic hydroxides and hydroxycarbonates: their function and use as flame retardant additives 2000 Marcel Dekker Inc New York 285 352
10. G. Camino, A. Riva, D. Vizzini, P. Amigouët, P. Bras Pereira, and A. Castrovinci M. Le Bras C. Wilkie S. Duquesne C. Jama S. Bourbigot Effect of magnesium hydroxide on fire retardance mechanism of intumescent EVA composition 2005 The Royal Society of Chemistry Oxford
11. J. Hacaloglu, T. Ersen, N. Ertugrul, M.M. Fares, and S. Suze Pyrolysis mass spectrometric analysis of styrene-butadiene block and random copolymers Eur Polym J 33 2 1997 199 203
12. S.-S. Choi Characteristics of the pyrolysis patterns of styrene-butadiene rubbers with differing microstructures J Anal Appl Pyrol 62 2 2002 319 330
13. S.V. Levchik, G. Camino, and L. Costa Mechanism of action of phosphorous-based flame retardants in Nylon 6. I: Ammonium polyphosphate Fire Mat. 19 1 1995 1 10
14. C.Y. Shen, N.E. Stahlheber, and D.R. Dyroff Preparation and characterization of crystalline long-chain ammonium polyphosphate J Am Chem Soc 91 1 1969 62 67
15. M. Vippola, S. Ahmaniemi, J. Keränen, P. Vuoristo, T. Lepisto, and T. Mäntylä Aluminum phosphate sealed alumina coating: characterisation of microstructure Mater Sci Eng A 323 1-2 2002 1 8