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Volumn 119, Issue 1-4, 1996, Pages 93-112

Polydentate SNXM (X = S,O,N) ligands by selective reduction of organosulfur heterocycles with tributyltin hydride

Author keywords

Chelators; Dithiols; Organosulfur heterocycles; Tributyltin hydride

Indexed keywords


EID: 21944432450     PISSN: 10426507     EISSN: None     Source Type: Journal    
DOI: 10.1080/10426509608043468     Document Type: Article
Times cited : (4)

References (41)
  • 7
    • 0001717104 scopus 로고
    • and references therein
    • S. R. Cooper, Acc. Chem. Res., 21, 141 and references therein, (1988);
    • (1988) Acc. Chem. Res. , vol.21 , pp. 141
    • Cooper, S.R.1
  • 11
    • 4243122310 scopus 로고
    • Ca in liquid ammonia selectively reduces 1,3-dithiolanes and -dithianes to the corresponding b-alkylthioethylmercaptans and g-alkylthiopropylmercaptans (Newman, B. C., and Eliel, E. L. (1970). J. Org. Chem., 35, 3641;
    • (1970) J. Org. Chem. , vol.35 , pp. 3641
    • Newman, B.C.1    Eliel, E.L.2
  • 12
    • 33947294765 scopus 로고
    • and 1,3-oxathiolanes to β-alkoxyethylmercaptans [Eliel, E. L., and Doyle, T. W. (1970). J. Org. Chem., 35, 2716.].
    • (1970) J. Org. Chem. , vol.35 , pp. 2716
    • Eliel, E.L.1    Doyle, T.W.2
  • 18
    • 0343223490 scopus 로고
    • Tris(trimethylsilyl)silane also affords selective reduction of C-S bonds in: (a) dithianes: P. Arya, C. Samson, M. Lesage and D. Griller, J. Org. Chem., 55, 6248, (1990);
    • (1990) J. Org. Chem. , vol.55 , pp. 6248
    • Arya, P.1    Samson, C.2    Lesage, M.3    Griller, D.4
  • 29
    • 21944444227 scopus 로고
    • Tetradentate organosulfur ligands have been prepared from dithianes by a different approach: Wilson, S. R. and Meyers, R. S. Tetrahedron Lett., 3413, (1976).
    • (1976) Tetrahedron Lett. , pp. 3413
    • Wilson, S.R.1    Meyers, R.S.2
  • 33
    • 0001111082 scopus 로고
    • For example, la, has been prepared by the alkylation of the sodium salt of mercaptethanol with 1,3-dibromopropane, and subsequently reacting the intermediate dithiadiol with thiourea in refluxing cone HCl, followed by refluxing in aqueous KOH: T. Rauchfuss, J. S. Shu and D. M. Roundhil Inorg. Chem., 15, 2096, (1976).
    • (1976) Inorg. Chem. , vol.15 , pp. 2096
    • Rauchfuss, T.1    Shu, J.S.2    Roundhil, D.M.3
  • 41
    • 77953682583 scopus 로고
    • Interestingly, unlike 3i which exists as the 2,2′-bi(1,3-dithiolane), the oxygen analog, prepared from the reaction of 2,3-dichloro-1,4-dioxane and ethylene glycol, exists as a mixture of isomers, 2,2′-bi(1,3-dioxolane) and 1,4,5,8-tetraoxadecalin: Hassel, O. and Romming, C., Acta Chem. Scand., 10, 136, (1956).
    • (1956) Acta Chem. Scand. , vol.10 , pp. 136
    • Hassel, O.1    Romming, C.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.