Functionalisation of wood by reaction with 3- isocyanatopropyltriethoxysilane: Grafting and hydrolysis of the triethoxysilane end groups

Holzforschung

Volumn 59, Issue 4, 2005, Pages 397-404

  Tingaut, Philippe ^a   Weigenand, Oliver ^b   Militz, Holger ^b   De Jé, Bernard ^a   Sèbe, Gilles ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

3 isocynatopropyltriethoxysilane; 13C and 29Si nuclear magnetic resonance cross polarisation with magic angle spinning (NMR CP MAS) spectroscopy; Chemical modification; Fourier transform infrared spectroscopy; Silane; Wood

Indexed keywords

CHEMICAL BONDS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GRAFTING (CHEMICAL); HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; SCANNING ELECTRON MICROSCOPY; SILANES; SILICON; X RAY DIFFRACTION ANALYSIS;

3-ISOCYANATOPROPYLTRIETHOXYSILANE (IPTES); MARITIME PINE SAPWOOD; NUCLEAR MAGNETIC RESONANCE CROSS-POLARIZATION; URETHANE LINKAGE;

WOOD;

CHEMICAL BONDS; COPOLYMERIZATION; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; PINUS PINASTER; SILANES; SILICON;

PINUS PINASTER;

EID: 21844471017     PISSN: 00183830     EISSN: None     Source Type: Trade Journal    
DOI: 10.1515/HF.2005.065     Document Type: Article

References (24)

1. Arkles, B. (1977) Tailoring surfaces with silanes. Chemtech 7:766-778.
2. Bazant, V., Chvalovsky, V., Rathowsky, J. Organosilicon Compounds. Academic Press, New York, 1965.
3. Cai, M., Ho, M., Pemberton, J.E. (2000) Surface vibrational spectroscopy of alkylsilane layers covalently bonded to monolayers of (3-mercaptopropyl) trimethoxysilane on Ag substrates. Langmuir 16:3446-3453.
4. Denes, A.R., Tshabalala, M.A., Rowell, R., Denes, F., Young, R.A. (1999) Hexamethyldisiloxane-plasma coating of wood surfaces for creating water repellent characteristics. Holzforschung 53:318-326.
5. 29Si CP/ MAS NMR) spectroscopy to the characterization of alkenyltrialkoxysilane and trialkoxysilyl-terminated polyisoprene grafting onto silica microparticles. J. Polym. Sci. A Polym. Chem. 36:437-453.
6. Douskey, M.C., Gebhard, M.S., McCormick, A.V., Lange, B.C., Whitman, D.W., Schure, M.R., Beshah, K. (2002) Spectroscopic studies of a novel cyclic oligomer with pendant alkoxysilane groups. Prog. Org. Coat. 45:145-157.
7. Cho, D.L., Sjoblom, E. (1990) Plasma treatment of wood. J. Appl. Polym. Sci. Appl. Polym. Symp. 46:461-472.
8. Hellgren, J.M., Olofsson, K., Sundberg B. (2004) Patterns of auxin distribution during gravitational induction of reaction wood in poplar and pine. Plant Physiol. 135:212-220.
9. Hill, C.A.S., Farahani, M.R.M., Hale, M.D.C. (2004) The use of organo alkoxysilane coupling agents for wood preservation. Holzforschung 58:316-325.
10. Hon, D.N.-S. - Chemical Modification of Lignocellulosic Materials. Marcel Dekker, New York, 1996.
11. 29Si NMR study of the sol-gel polymerisation rates of substituted ethoxysilanes. J. Non-Cryst. Solids 195:1-15.
12. Lu, J.Z., Wu, Q., McNabb, H.S. (2000) Chemical coupling in wood fiber and polymer composites: a review of coupling agents and treatments. Wood Fiber Sci. 32(1):88-104.
13. Mai, C., Militz, H. (2004) Modification of wood with silicon compounds. Treatment systems based on organic silicon compounds - a review. Wood Sci. Technol. 37:453-461.
14. Miyashita, H., Suzuki, M. (1999) Improvement of dimensional stability and fire retardancy by γ-methacryloxypropyl trimethoxysilane for Cryptomeria japonica D. Don and its application to durability of adhesive bond plywood. Mokuzai Gakkaishi 45(3):251-260.
15. Miyashita, H., Ohmi, M., Tominaga, H., Sawatari, A., Suzuki, M., Kawarada, K., Mizumoto, K. (2000) Distribution of silicon atoms in sugi wood treated with γ-methacryloxypropyl trimethoxysilane and its fire retardancy. Mokuzai Gakkaishi 46(5):449-455.
16. Ogiso, K., Saka, S. (1994) Wood-inorganic composites prepared by sol-gel process III. Effects of chemical bonds between wood and inorganic substances on property enhancement. Mokuzai Gakkaishi 40:1100-1106.
17. Oyane, A., Minoda, M., Miyamoto, T., Takahashi, R., Nakanishi, K., Kim, H.-M., Kokubo, T., Nakamura, T. (1999) Apatite formation on ethylene-vinyl alcohol copolymer modified with silanol groups. J. Biomater. Mater. Res. 47(3):367-373.
18. Oyane, A., Kawashita, M., Nakanishi, K., Nakanishi, K., Kokubo, T., Minoda, M., Miyamoto, T., Nakamura, T. (2003) Bonelike apatite formation on ethylene-vinyl alcohol copolymer modified with silane coupling agent and calcium silicate solutions. Biomaterials 24:1729-1735.
19. Rowell, R.M. The Chemistry of Solid Wood. Advances in Chemistry Series No. 207. American Chemical Society, New York, 1984.
20. Saka, S., Yakake, Y. (1993) Wood-inorganic composites prepared by sol-gel process III. Chemically modified woodinorganic composites. Mokuzai Gakkaishi 75:308-314.
21. Sèbe, G., De Jéso, B. (2000) The dimensional stabilisation of maritime pine sapwood (Pinus pinaster) by chemical reaction with organosilicon compounds. Holzforschung 54:474-480.
22. Sèbe, G., Brook, M.A. (2001) Hydrophobization of wood surfaces: covalent grafting of silicone polymers.Wood Sci. Technol. 35(3):269-282.
23. Sèbe, G., Tingaut, P., Safou-Tchiama, R, Pétraud, M., Grelier, S., De Jéso, B. (2004) Chemical reaction of maritime pine sapwood (Pinus pinaster Soland) with alkoxysilane molecules: A study of chemical pathways. Holzforschung 58:511-518.
24. Tissot, I., Reymond, J.P., Lebfevre, F., Bourgeat-Lami, E. (2002) SiOH-functionalized polystyrene latexes. A step toward the synthesis of hollow silica nanoparticles. Chem. Mater. 14:1325-1331.