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0027228087
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85132983776
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1 H-NMR (CDCl 3) δ 0.88 (6H, t, J=5.7 Hz), 1.25 - 1.59 (52H, m), 3.32 (9H, s, N-Me 3), 3.76 (2H, m, -CH 2 -N), 3.98 (2H, m, -O-CH 2 -CH 2 -N-), 4.10-4.25 (2H, m, CH 2 -O), 4.30 (2H, brs, CH 2 O-), 4.30 - 4.44 (1H, m, CH-OOH), 5.23 (1H, m, CH-O), 5.38 (1H, dd, J=13.1,6.7 Hz, =CH-CHOOH), 5.66(1H, dt, J=13.1, 6.1 Hz, CH=CH-CHOOH), FAB-MS m/z: 827 (M+K), 812 (M+Na), 789 (M)
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2O-), 4.30 - 4.44 (1H, m, CH-OOH), 5.23 (1H, m, CH-O), 5.38 (1H, dd, J=13.1,6.7 Hz, =CH-CHOOH), 5.66(1H, dt, J=13.1, 6.1 Hz, CH=CH-CHOOH), FAB-MS m/z: 827 (M+K), 812 (M+Na), 789 (M).
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15
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85133019791
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1 H-NMR (CDC1 3) δ; 0.88, 0.89 (3H, t, J=7.3 Hz), 1.20-1.63 (22H, m), 2.09, 2.07 (2H, d, J=7.3 Hz), 2.30, 2.31 (2H, t, J=7.6 Hz), 3.67, 3.67 (3H, s, O-Me), 4.26-4.27 (1H, m, -CH=CH-CHOOH), 5.36, 5.36 (1H, dd, 7=15.3, 8.5 Hz, -CH=CH-CHOOH), 5.76, 5.77 (1H, m, -CH=CH-CHOOH), 7.67, 7.75 (1H, s, CH=CH-CHOOH), FAB-MS m/z. 311 (M-OH), 295 (M-OOH)
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3) δ; 0.88, 0.89 (3H, t, J=7.3 Hz), 1.20-1.63 (22H, m), 2.09, 2.07 (2H, d, J=7.3 Hz), 2.30, 2.31 (2H, t, J=7.6 Hz), 3.67, 3.67 (3H, s, O-Me), 4.26-4.27 (1H, m, -CH=CH-CHOOH), 5.36, 5.36 (1H, dd, 7=15.3, 8.5 Hz, -CH=CH-CHOOH), 5.76, 5.77 (1H, m, -CH=CH-CHOOH), 7.67, 7.75 (1H, s, CH=CH-CHOOH), FAB-MS m/z. 311 (M-OH), 295 (M-OOH).
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17
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0024529102
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Y. Nishinaka, Y. Aramaki, H. Yoshida, H. Masuya, T. Sugawara and Y. Ichimori, Biochem. Biophys. Res. Commun., 193, 554 (1993). DOI: 10.1006/bbrc.1993.1659
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