Photocatalytic oxidation of hydrosulfide ions by molecular oxygen over cadmium sulfide nanoparticles

Journal of Nanoparticle Research

Volumn 6, Issue 2, 2004, Pages 149-158

  Raevskaya, A E ^a   Stroyuk, A L ^a   Kuchmii, S Ya ^a  

^a L V PISARZHEVSKII INSTITUTE OF PHYSICAL CHEMISTRY   (Ukraine)

Author keywords

CdS; Hydrogen sulfide; Hydrosulfide; Photocatalysis; Photooxidation; Semiconductor nanoparticles

Indexed keywords

EID: 21644490346     PISSN: 13880764     EISSN: None     Source Type: Journal    
DOI: 10.1023/b:nano.0000034719.30620.d3     Document Type: Article

References (37)

1. Awatani T. & A.J. McQuillan., 1998. Adsorbed thiosulfate intermediate of cadmium sulfide aqueous photocorrosion detected and characterized by in situ infrared spectroscopy. J. Phys. Chem. 102, 4110-4113.
2. Beydoun D., R. Amal, G. Low & S. McEvoy, 1999. Role of nanoparticles in photocatalysis. J. Nanoparticles Res. 1, 439-458.
3. Benjamin D., & D. Huppert, 1988. Surface recombination velocity measurements of CdS single crystals immersed in electrolytes. A picosecond photoluminescence study. J. Phys. Chem. 92, 4676-4679.
4. Chariot G., 1961. Les méthodes de la chimie analytique (Analyse quantitative minerale). Masson ed., Paris, France.
5. Chestnoy N., T.D. Harris, R. Hull & L.E. Brus, 1986. Luminescence and Photophysics of CdS semiconductor clusters: The nature of the emitting electronic state. J. Phys. Chem. 90, 3393-3399.
6. 2- in Aqueous Solution. J. Phys. Chem. 94, 2191-2198.
7. Ermakov A.N., G.A. Poskrebyshev & A.P. Purmal, 1997. Sulfite oxidation-modern state of the problem. Kinetics and Catalysis 38, 325-338.
8. Holzbecher Z., L. Diviš, L. Šůcha & F. Vlàčil, 1975. Organickà èinidla v anorganické analýze. SNTL, Praha.
9. Emelyanova G.I., L.E. Gorlenko, L.V. Voronova, M.P. Zverev & V.V. Lunin, 1999. Low-temperature hydrogen sulfide oxidation to sulfur over metal-containing vion fibers. Kinetics and Catalysis 40, 90-96.
10. Fendler J.H. (ed.), 1998. Nanoparticles and Nanostructured films: preparation, Characterization and Application. Wein- heim, New York, USA.
11. Giggenbach W., 1972. Optical Spectra and Equilibrium Distribution of Polysulfide Ions in Aqueous Solution at 20 °C. Inorg. Chem. 11, 1201-1207.
12. Grätzel M. (ed.), 1983. Energy Resources through Photochemistry and Catalysis. Academic Press, New York, USA.
13. Hoyer P. & H. Weller, 1995. Potential-Dependent Electron Injection in Nanoporous Colloidal ZnO Films. J. Phys. Chem. 99, 14096-14100.
14. Khairutdinov R.F., 1998. Chemistry of semiconductor nanoparticles. Uspechi chimii (russ. ed.) 67, 125-139.
15. Kryukov A.I., S.Ya. Kuchmii & V.D. Pokhodenko, 2000. Energetics of electronic processes in semiconductor photocatalytic systems. Theoret. Experim. Chem. (Engl, ed.) 36,69-87.
16. Kovach S.K., V.S. Vorobets & A.T. Vas'ko, 1988. Determination of the second dissociation constant of hydrogen sulfide with the use of sulfide-selective electrode. Ukrain. chim. zhurnal. (Russ. ed.) 54, 150-154.
17. Kamat P.V. & N.M. Dimitrijevic, 1989. Dynamic Burstein-Moss Shift in Semiconductor Colloids. J. Phys. Chem. 93, 2873-2875.
18. Licht S., G. Hodes, & J. Manassen, 1986. Numerical analysis of aqueous polysulfide solutions and its application to cadmium chalcogenide/polysulfide photoelectrochemical solar cells. Inorg. Chem. 25, 2485-2489.
19. Liu C.-Y., & Bard A. J., 1989. Effect of Excess charge on band energetics (optical absorbtion edge and carrier redox potential) in Small Semiconductor Particles. J. Phys. Chem. 93, 3232-3237.
20. Meissner D., R. Memming & B. Kastening, 1988. Photoelect- rochemistry of cadmium sulfide. 1. Reanalysis of photocorrosion and flat-band potential. J. Phys. Chem. 92, 3476-3483.
21. Mills G., M.S. Schmidt, M.S. Matheson & D. Meisel, 1987. Thermal and photochemical reactions of sulfhydryl radicals. Implications for colloid photo-corrosion. J. Phys. Chem. 91, 1590-1596.
22. Magomedov M.A., R.N. Gasanova, A.M. Kurbanova & Kh.A. Magomedov, 1999. Characteristic parameters of oxygen photoadsorbtion on epitaxial layers of cadmium chalcoge- nides (CdS, CdSe, n-CdTe) Zhurnal fiz. chimii (Russ. ed.) 73, 1122-1124.
23. Nosaka Y. & M.A. Fox, 1986. Effect of light intensity on the quantum yield of photoinduced electron transfer from colloidal cadmium sulfide to methylviologen. J. Phys. Chem. 90, 6521-6522.
24. Nosaka Y., N. Ohta & H. Miyama, 1990. Photochemical kinetics of ultrasmall semiconductor particles in solution: effect of size on the quantum yield of electron transfer. J. Phys. Chem. 94, 3753-3755.
25. Raevskaya A.E., A.L. Stroyuk & S. Ya. Kuchmii, 2003a. Optical properties of colloidal CdS nanoparticles stabilized with the sodium polyphosphate and their behaviour under pulse photoexcitation. Theoret. Experim. Chem. (Engl, ed.) 39, 153-160.
26. Raevskaya A.E., A.L. Stroyuk & S. Ya. Kuchmii, 2003b. Photocatalytic activity of CdS nanoparticles in sulfite ions chain oxidation by molecular oxygen. Theoret. Experim. Chem. (Russ. ed.) 39, 230-235.
27. Rao C.N.R. & A.K. Cheetham, 2001. Science and technology of nanomaterials: current and future prospects. J. Mater. Chem. 11, 2887-2894.
28. 2 oscillator: mechanistic proposal and periodic perturbation. J. Phys. Chem. 93, 2783-2791.
29. Schubert R, 1991. Lehrbuch der Ökologie. Ganz Fischer Verlag, Leipzig, Germany.
30. Shiragami T., S. Fukami, Y. Wada & S. Yanagida, 1993. Semiconductor Photo-catalysis: Effect of light intensity on nanoscale CdS-catalyzed photolysis of organic solvents. J. Phys. Chem. 97, 12882-12887.
31. Tolkachev N.N., A.Yu. Stacheev, L.M. Kustov & L.A. Bondar, 2001. Spectral properties of CdS nanoparticles incapsulated in silica micropores. Zhurnal fiz. chimii (Russ. ed.) 75, 1679-1683.
32. Wang Y. & N. Herron, 1991. Nanometer-sized semiconductor clusters: Materials synthesis, quantum size effects, and photophysical properties. J. Phys. Chem. 95, 525-532.
33. Zakhalyavko, G.A., N.V. Gorokhovatskaya & V.V. Goncharuk, 1987. Utilization of carboxylic cationite for the purification of waters polluted by hydrogen sulfide. Chem. Technol. Water. (Russ. ed.) 9, 459-460.
34. Zakhalyavko G.A., S.S. Stavisskaya, I.A. Tarkovskaya, N.V. Gorokhovatskaya & V.V. Goncharuk 1989. Liquid-phase sulfide ions air oxidation in aqueous solutions over modified oxidized carbons. Chem. Technol. Water. (Russ. ed.) 11, 982-984.
35. Zhang Y.-X. & R.J. Field, 1991. Simplification of a mechanism of the methylene blue - HS- - O2 CSTR oscillator: A homogeneous oscillatory mechanism with nonlinearities but no autocatalysis. J. Phys. Chem. 95, 723-727.
36. Zhang J.Z., 2000. Interfacial charge carrier dynamics of colloidal semiconductor nanoparticles. J. Phys. Chem. B. 104, 7239-7253.
37. Zhang J.Z., R.H. O'Neil & T.W. Roberti, 1994. Femtosecond studies of photoinduced electron dynamics at the liquid-solid interface of aqueous CdS Colloids. J. Phys. Chem. 98, 3859-3864