On the regioselectivity of alkylation of the (trimethylsilyl) tetramethylcyclopentadienide anion. A new approach to the synthesis of 1,2,3,4-tetramethylfulvene

Russian Chemical Bulletin

Volumn 53, Issue 10, 2004, Pages 2182-2186

  Krut'ko, D P ^a   Borzov, M V ^a   Veksler, E N ^b  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

(trimethylsilyl) tetramethylcyclopentadienide anion; 1,2,3,4 tetramethylfulvene; 13C NMR spectroscopy; 1H NMR spectroscopy; Alkylation; C electrophiles; Regioselectivity; Trimethylsilyl substituted cyclopentadienes

Indexed keywords

ALDEHYDE; ALKENE DERIVATIVE; CYCLOPENTADIENE DERIVATIVE; LITHIUM DERIVATIVE;

ALKYLATION; ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM CHEMISTRY; STEREOSPECIFICITY; SYNTHESIS;

EID: 21644445358     PISSN: 10665285     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11172-005-0095-9     Document Type: Article

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