Two new tetranor-cycloartane glycosides from Cimicifuga Rhizome

Chemical and Pharmaceutical Bulletin

Volumn 51, Issue 9, 2003, Pages 1117-1118

  Nishida, Makiko ^a   Yoshimitsu, Hitoshi ^a   Nohara, Toshihiro ^b  

^a KYUSHU KYORITSU UNIVERSITY   (Japan)

^b KUMAMOTO UNIVERSITY   (Japan)

Author keywords

Cimicifuga Rhizome; Cimicifuga sp.; Cycloartane glycoside; Ranunculaceae

Indexed keywords

CIMICIFUGOSIDE; GLYCOSIDE; LACTONE; UNCLASSIFIED DRUG; PHYTOSTEROL; TETRANOR CYCLOARTANE GLYCOSIDE; TETRANOR-CYCLOARTANE GLYCOSIDE;

ARTICLE; CHIRALITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RHIZOME; SPECTROSCOPY; CHEMISTRY; CIMICIFUGA; FAST ATOM BOMBARDMENT MASS SPECTROMETRY; GAS CHROMATOGRAPHY;

CHROMATOGRAPHY, GAS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; CIMICIFUGA; GLYCOSIDES; MAGNETIC RESONANCE SPECTROSCOPY; PHYTOSTEROLS; SPECTROMETRY, MASS, FAST ATOM BOMBARDMENT;

EID: 2142808701     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.51.1117     Document Type: Article

References (4)

1. Kusano A., Takahira M., Shibano M., In Y., Ishida T., Miyase T., Kusano G., Chem. Pharm. Bull., 46, 467-472 (1998).
2. 5) δ: 32.0 (C-1), 30.0 (C-2), 88.1 (C-3), 41.3 (C-4), 47.1 (C-5), 20.5 (C-6), 25.7 (C-7), 46.0 (C-8), 20.3 (C-9), 27.0 (C-10), 36.5 (C-11), 76.7 (C-12), 48.7 (C-13), 48.4 (C-14), 43.9 (C-15), 80.4 (C-16), 53.7 (C-17), 13.4 (C-18), 29.7 (C-19), 26.9 (C-20), 22.1 (C-21), 38.7 (C-22), 173.5 (C-23), 19.6 (C-28), 25.8 (C-29), 15.4 (C-30), 21.5 (Ac), 170.5 (Ac), 107.6 (xyl C-1), 75.6 (xyl C-2), 78.7 (xyl C-3), 71.3 (xyl C-4), 67.2 (xyl C-5).
3. 5) δ: 30.3 (C-1), 29.6 (C-2), 87.8 (C-3), 40.5 (C-4), 42.4 (C-5), 21.9 (C-6), 114.5 (C-7), 147.2 (C-8), 21.4 (C-9), 28.5 (C-10), 36.4 (C-11), 76.3 (C-12), 47.9 (C-13), 50.9 (C-14), 42.8 (C-15), 80.5 (C-16), 54.1 (C-17), 14.8 (C-18), 29.1 (C-19), 26.9 (C-20), 22.0 (C-21), 38.6 (C-22), 173.4 (C-23), 26.8 (C-28), 25.8 (C-29), 14.3 (C-30), 21.5 (Ac), 170.6 (Ac), 107.5 (xyl C-1), 75.7 (xyl C-2), 78.7 (xyl C-3), 71.3 (xyl C-4), 67.2 (xyl C-5).
4. Nafady A. M., El-Shanawany M. A., Mohamed M. H., Hassanean H. A.-H., Zhu X.-H., Yoshihira T., Okawa M., Ikeda T., Nohara T., Tetrahedron Lett., 44, 3509-3511 (2003).