Reactions of transition metal dihydrogen complexes

Coordination Chemistry Reviews

Volumn 121, Issue C, 1992, Pages 155-284

  Jessop, Philip G ^a   Morris, Robert H ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 2142774500     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/0010-8545(92)80067-2     Document Type: Article

References (340)

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3. Five-co-ordinate molybdenum and tungsten complexes, [M(CO)3(PCy3)2], which reversibly add dinitrogen, dihydrogen, and other small molecules
4. Theoretical study of the hydrogen interaction with iron(0), iron(1+), and iron(1-) atoms
5. NATO ASI Series
6. 1H NMRT1(min) data and structure in a series of rhenium polyhydride complexes and the contribution of M-H dipole-dipole relaxation
7. Chemical bonding of hydrogen molecules to transition metal complexes
8. Coordination of H2 and O2 to[OsHCl(CO)(PiPr3)2]: A Catalytically Active M(η2-H2) Complex
9. Characterisation and properties of the dinuclear ruthenium molecular hydrogen complex [(?2-H2)(dppb)Ru(�-Cl)3RuCl(dppb)]; dppb = Ph2P(CH2)4PPh2
10. Dihydrogen and hydrido complexes via hydrogen addition to d6 five-co-ordinate complexes of ruthenium and osmium with 1,2-bis(dicyclohexylphosphino)ethane
11. Dihydride versus dihydrogen complex; the photochemical reaction of [(?5;-C5H5)M(CO)4](M = V, Nb and Ta) with hydrogen in solution at both cryogenic and room temperatures
12. Flash photolysis of Cr(CO)6 in H2-saturated cyclohexane solution: i.r. spectroscopic evidence for a Cr(CO)5(H2) complex at room temperature
13. The bonding of H2 in W(CO)5(H2), a reactive intermediate stabilized and identified in liquid xenon
14. Photolysis of group 6 metal carbonyl alkene complexes in liquefied noble gases: i.r. evidence for very labile dinitrogen and dihydrogen adducts
15. Organometallic photochemistry in supercritical fluids: the reaction of H2 with [(?5-C5H5)M(CO)3](M ? Re and Mn) and the formation of a ?non-classical?dihydrogen complex of manganese(I)
16. The reversible protonation of rhenium(VII) heptahydrides of type [ReH7(PR3)2] to give ?2-dihydrogen complexes
17. Formation of molecular hydrogen complexes of iron by the reversible protonation of iron dihydrides with alcohols
18. Ionic ruthenium(IV) trihydrides as intermediates in the heterolytic fission of dihydrogen by five-co-ordinate hydridoruthenium(II) cations. Direct evidence for an oxidative addition?reductive elimination pathway
19. Preparation and reactions of a novel five-coordinate ruthenium complex [RuH(BINAP)2]PF6 and formation of the first chiral molecular hydrogen complex [RuH(.ETA.2-H2)(BINAP)2]PF6 (BINAP=(R)-bis(diphenylphosphino)-1,1'-binaphthyl).
20. Chelate size dependence of dihydrogen-hydride exchange in ruthenium(II) molecular hydrogen complexes with diphosphines (RuH(.ETA.2-H2)(P-P)2)PF6 (P-P=Ph2P(CH2)nPPh2; n=2,3,4).
21. [(?5-C5H5)Ru(PPh3)(CNBut)(?-2-H2)]PF6: a cationic molecular hydrogen complex from protonation of a monohydride precursor
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23. Formation of ReCl(H2)(PMePh2)4; a complex containing an ?2-H2 ligand
24. Can Electrochemistry Distinguish Classical from Nonclassical Transition-Metal Polyhydrides?
25. Oxidative versus reductive additions: A 13C NMR study of H2, HX (X = Cl, Br, OR I), and Cl2 additions to some iridium(I) complexes
26. AreneCr(CO)2(?2-HSiHPh2) complexes as catalysts for the Si?H bond activation. Hydrolysis of the Si?H bond and dehydrogenative coupling between diphenylsilane and nucleophiles
27. Übergangsmetall-Stannyl-Komplexe,31) Metall, Wasserstoff, Zinn-Dreizentrenbindung bei Hydrido-Stannyl-Komplexen der 6. Nebengruppe
28. Photochemical reactivity of 2[Ir III HCl2(PPri 3)2]�H2. Formation of monohydrido isomers of Ir III and evidence of photoinduced oxidative addition of H2, to Ir III
29. Solid State and Solution NMR of Nonclassical Transition-Metal Polyhydrides
30. Proton-proton exchange couplings in transition-metal polyhydrides
31. The detection and reactivity of [MoH4(?2-H2)(Ph2PCH2CH2PPh2)2]2+
32. Kinetics of dissociation of H2 from transition-metal polyhydride complexes
33. Carbon-hydrogen and carbon-carbon bond activation with highly electrophilic transition metal complexes
34. Ruthenium hydride complex with 1,1'-bis(diphenylphosphino)ferrocene(dppf). Characterization and molecular structure of (RuH3(dppf)2)PF6.
35. Photoactivation of alkanes by carbonyl(?5-cyclopentadienyl)dihydridoiridium: solution and matrix isolation studies
36. 1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution
37. Direct protonation of the W?H bonds of bis(pentamethylcyclopentadienyl)tungsten dihydride
38. ON THE MECHANISM OF THE OXO REACTION
39. C?H and H?H bond activation; dissociative vs. nondissociative binding to iridium
40. Hydrogen-hydrogen and carbon-hydrogen activation reactions at d0 metal centers
41. Bonding interactions between three adjacent hydrogen ligands. Preparation and spectroscopic properties of the tantalum and niobium complexes [Ta(H)3(C5H5?n R n )2](R = SiMe3, n= 1 or 2) and [Nb(H3)(C5H5?n Rn)2](n= 1, R = Me or SiMe3; n= 2, R = SiMe3)
42. Upon the existence of a trihydrogen ligand. Preparation and spectroscopic studies of the adducts (C5Me5) RuH3P(cyclo-C6H11)3�CuCl and [{(C5Me5)RuH3P(cyclo-C6H11)3}2Cu]PF6
43. Symmetrization Postulate and Nuclear Magnetic Resonance of Reacting Systems
44. Theoretical calculations on niobium and tantalum trihydride complexes. Relations with the problem of quantum mechanical exchange coupling
45. The Influence of Chemical Exchange on NMR Spin Lattice Relaxation
46. Cleavage of an aryl carbon?sulphur bond in hydride?thiolate complexes of molybdenum(IV); X-ray crystal structure of [{Mo(SC6H2Pri 3-2,4,6)(OMe)(PMePh2)}2(�-S)2]
47. The Kinetics and Mechanism of H2–D2Exchange Catalyzed by Hydridochlorotris(triphenylphosphine)ruthenium(II)
48. Characterization of partially deuteriated transition metal polyhydrido complexes by heteronuclear 2D NMR techniques
49. The Challenge of d and f Electrons Theory and Computation
50. Synthesis of the first heterobimetallic rhenium?ruthenium ?2-dihydrogen complexes
51. Formation of metal acetylides via complexes of molecular hydrogen
52. The photochemical synthesis of [Cr(CO)5(H2)]in solution: i.r. evidence for co-ordinated molecular dihydrogen
53. 31P spin-sattice relaxation times of tertiary aryl phosphines and their iridium(I) and gold(I) complexes
54. Solution homolytic bond dissociation energies of organotransition-metal hydrides [Erratum to document cited in CA111(11):97481d]
55. Heterolytic Activation of Hydrogen by Transition Metal Complexes
56. A new class of dihydrogen complexes containing oxygen donor ligands. Preparation of RuH(?2-H2)(OCOCF3)[P(C6H11)3]2 and of the equilibrated mixture RuH2(OCOCF3)2[P(C6H11)3]2/RU(?2-H2)(OCOCF3)2[P(C6H11)3]2
57. [IrH2(H2)2L2]+{L = P(C6H11)3}: A non-classical polyhydride complex
58. The reactions of [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] with allenes and acetylenes, and the reduction of cyclopropane by molybdenum nitrogenases
59. A ruthenium(II) enynyl complex mediates the catalytic dimerization of 1-alkynes to Z-1,4-disubstituted enynes
60. Proc. 21 Congr. Naz. di Chim. Inorg., Bressanone
61. Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of ?,?-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride
62. T 1 values in hydride and new molecular hydrogen phosphite complexes of comparable structure
63. Chemisorption of diatomic molecules (H2, N2, CO) on transition d-metals
64. Six- and five-co-ordinate ruthenium(II) complexes with 1,2-bis(dicyclohexylphosphino)ethane. X-Ray crystal structure of the d 6 five-co-ordinate [RuCl{(C6H11)2PCH2CH2P(C6H11)2}2]PF6
65. X-ray investigation on a five-coordinated iron(II) complex with an intermediate spin state. Crystal field and angular overlap calculations
66. Classical versus non-classical polyhydride complexes: single crystal neutron diffraction study of 1,2-bis(diphenylphosphino)ethaneheptahydridorhenium(VII)[ReH7(dppe)] using a position-sensitive detector
67. Characterization of ruthenium(II) molecular hydrogen complex with (R,R)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (diop).
68. Hydrogen production from ethanol catalysed by Group 8 metal complexes
69. Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature
70. Selective reduction of carbonyl groups with systems composed of (?5-C5H5)2MoH2 and protonic acids: new highly regio- and diastereo-selective reduction of ketones
71. The basicity of phosphines
72. Unusual fluxional and T 1 properties for [ReH4(CO)(PMe2Ph)3]+: a polyhydride with classical and nonclassical tautomers
73. Synthesis and spectroscopic characterization of [ReH5(triphos)] and [ReH6(triphos)]+[triphos = PPh(CH2CH2PPh2)2]
74. Cationic hydride complexes of iron, ruthenium, and osmium, including a triad of molecular nitrogen complexes
75. Molecular hydrogen complexes in catalysis: highly efficient hydrogen production from alcoholic substrates catalysed by ruthenium complexes
76. Mechanism of Ethylene Hydrogenation by the Molecular Hydrogen Complex [Ir(H)2(H2)(PMe2Ph)3]??Characterization of Intermediates