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[1a], p. 99-166
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0001603937
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17
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0000308248
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Diethylbenzene is an industrial product, however, the commercial mixture contains only traces of 1,2-diethenylbenzene (3a). Heck reported for the same reaction 78% of diethenylbenzene apart from 12% of 2-bromostyrene (2a-Br): J. E. Plevyak, R. F. Heck, J. Org. Chem. 1978, 43, 2454-2456.
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22
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2742535738
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note
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With a chiral, nonracemic catalyst an enantioselective synthesis of 12 is conceivable. Further work along these lines is in progress.
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23
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0030603097
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27
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2742589389
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-
note
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Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100030. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code + (1223) 336-033; e-mail: deposit@ccdc.cam.ac.uk).
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0001303316
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0040012647
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2742517016
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0342826148
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The procedure was modified from a published one: [21a] S. Hibino, E. Sugino, Y. Adachi, K. Nomi, K. Sato, K. Fukumoto, Heterocycles 1989, 28, 275-282.
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Hibino, S.1
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43
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2742581779
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o-Iodostyrene 2a-I has been prepared from o-iodobenzaldehyde, but experimental details were not disclosed: R. Morrin Acheson, G. C. M. Lee, J. Chem. Soc., Perkin Trans. 1 1987, 2321-2332. Compound 2a-I has also been prepared by dehydration of 1-(2-iodophenyl)ethanol: M. M. Koton, E. M. Moskwina, Zh Prikl. Khim. (Leningrad) 1953, 26, 660; J. Appl Chem. USSR (Engl. Transl.) 1953, 26, 617.
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Morrin Acheson, R.1
Lee, G.C.M.2
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44
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2742544589
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Leningrad
-
o-Iodostyrene 2a-I has been prepared from o-iodobenzaldehyde, but experimental details were not disclosed: R. Morrin Acheson, G. C. M. Lee, J. Chem. Soc., Perkin Trans. 1 1987, 2321-2332. Compound 2a-I has also been prepared by dehydration of 1-(2-iodophenyl)ethanol: M. M. Koton, E. M. Moskwina, Zh Prikl. Khim. (Leningrad) 1953, 26, 660; J. Appl Chem. USSR (Engl. Transl.) 1953, 26, 617.
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Zh Prikl. Khim.
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Koton, M.M.1
Moskwina, E.M.2
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45
-
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2742597223
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o-Iodostyrene 2a-I has been prepared from o-iodobenzaldehyde, but experimental details were not disclosed: R. Morrin Acheson, G. C. M. Lee, J. Chem. Soc., Perkin Trans. 1 1987, 2321-2332. Compound 2a-I has also been prepared by dehydration of 1-(2-iodophenyl)ethanol: M. M. Koton, E. M. Moskwina, Zh Prikl. Khim. (Leningrad) 1953, 26, 660; J. Appl Chem. USSR (Engl. Transl.) 1953, 26, 617.
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-
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49
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0001249590
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1,2-Dipropenylbenzene was previously obtained as a mixture of cis,cis, cis,trans and trans,trans isomers by Wittig olefination of phthalicdialdehyde; pure isomers could only be obtained by tedious separation: [26a] H. Heimgartner, L. Ulrich, H.-J. Hansen, H. Schmid, Helv. Chim. Acta 1971, 54, 2313-2354.
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Heimgartner, H.1
Ulrich, L.2
Hansen, H.-J.3
Schmid, H.4
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