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We are indebted to the late Emeritus Professor M. S. Newman for this suggestion
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We are indebted to the late Emeritus Professor M. S. Newman for this suggestion.
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9
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0012360296
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4-Nitrophenol and 3,5-dimethyl-4-nitrophenol have pKa values of 7.21 and 8.24, respectively. G. W. Wheland, R. M. Brownell, and E. C. Mayo, J. Am. Chem. Soc., 70, 2492 (1948).
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[11a] G. A. Russell, E. J. Geels, F. J. Smentowski, K.-Y. Chang, J. Reynolds, and G. Kaup, J. Am. Chem. Soc., 89, 3821 (1967);
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Henry Feuer, ed, Interscience Publishers, New York
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[b] Reactions of amines and nitrosobenzene to yield azo compounds are usually carried out under mild conditions in acetic acid: ref 10 and J. H. Boyer, The Chemistry of Nitro and Nitroso Groups, Part I, Henry Feuer, ed, Interscience Publishers, New York. 1969, p 278.
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Boyer, J.H.1
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