Quantification of lignin and hexenuronic acid in bleached hardwood kraft pulps: A new calibration method for UVRR spectroscopy and evaluation of the conventional methods

Journal of Wood Chemistry and Technology

Volumn 25, Issue 1-2, 2005, Pages 51-65

  Jääskeläinen, Anna Stiina ^a   Saariaho, Anna Maija ^a,b   Vuorinen, Tapani ^a  

^a AALTO UNIVERSITY   (Finland)

^b M real   (Germany)

Author keywords

Bleached pulp; Hardwood kraft pulp; Hexenuronic acid; Kappa number; Klason lignin; Lignin content determination; UV resonance Raman spectroscopy

Indexed keywords

BLEACHED HARDWOOD KRAFT PULPS; LIGNIN CONTENT DETERMINATION; ULTRAVIOLET RESONANCE RAMAN SPECTROSCOPY; UNSATURATED STRUCTURES;

AROMATIC COMPOUNDS; BLEACHED PULP; CHEMICAL ANALYSIS; COMPOSITION; HARDWOODS; LIGNIN; ORGANIC ACIDS; RAMAN SPECTROSCOPY; STRUCTURE (COMPOSITION); ULTRAVIOLET SPECTROSCOPY; UNSATURATED COMPOUNDS; WOOD CHEMICALS;

KRAFT PULP;

AROMATIC COMPOUNDS; BLEACHED PULPS; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; EXTRACTIVES; HARDWOODS; HEXENURONIC ACID; KAPPA NUMBER; KLASON LIGNINS; KRAFT PULPS; LIGNINS; PRETREATMENT; ULTRAVIOLET SPECTROSCOPY; WOOD STRUCTURE;

EID: 21344464891     PISSN: 02773813     EISSN: 15322319     Source Type: Journal    
DOI: 10.1081/WCT-200058239     Document Type: Article

References (19)

1. Dence, C.W. The determination of lignin. In Methods in Lignin Chemistry; Lin, S.Y., Dence, C.W., Eds.; Springer-Verlag: Berlin, 1992; 33-61.
2. Scandinavian pulp, paper and board testing committee. SCAN-C 1:00, Kappa number.
3. Tasman, J.E.; Berzinz, V. The permanganate consumption of pulp materials: I. Development of a basic procedure. Tappi 1957, 40 (9), 691-704.
4. Li, J.; Gellerstedt, G. Kinetics and mechanism of kappa number determination. Nord. Pulp Pap. Res. J. 1998, 13, 152-147.
5. Teleman, A.; Harjunpää, V.; Tenkanen, M.; Buchert, J.; Hausalo, T.; Drakenberg, T.; Vuorinen, T. Characterization of 4-deoxy-β-L-threo-hex-4-enopyranosyluronic acid attached to xylan in pine kraft pulp and pulping liquor by 1H NMR and 13C NMR spectroscopy. Carbohydr. Res. 1995, 272, 55-71.
6. Li, J.; Sevastyanova, O.; Gellerstedt, G. The relationship between kappa number and oxidizable structures in bleached pulps. J. Pulp Pap. Sci. 2002, 28 (8), 262-266.
7. Brunow, G.; Lundquist, K.; Gellerstedt, G. Lignin. In Analytical Methods in Wood Chemistry, Pulping, and Papermaking; Sjöström, E., Alén, R., Eds.; Springer-Verlag: Berlin, 199977-124.
8. Saariaho, A.-M.; Hortling, B.; Jääskeläinen, A.-S.; Tamminen, T.; Vuorinen, T. Simultaneous quantification of residual lignin and hexenuronic acid from chemical pulps with UV resonance Raman spectroscopy and multivariate calibration. J. Pulp Pap. Sci. 2003, 29 (11), 363-370.
9. Agarwal, U.P.; Weinstock, I.A.; Atalla, R.H. FT-Raman spectroscopy for direct measurement of lignin in kraft pulps. Tappi J. 2003, 2 (1), 22-26.
10. Vuorinen, T.; Buchert, J.; Teleman, A.; Tenkanen, M.; Fagerström, P. Selective hydrolysis of hexenuronic acid groups and its application in ECF and TCF bleaching of kraft pulps, International Pulp Bleaching Conference, Washington, DC, April 14-18, 1996; Book 1, 43-51.
11. Li, J.; Gellerstedt, G. The contribution of kappa number from hexenuronic acid groups in xylan. Carbohydr. Res. 1997, 302, 213-216.
12. Tappi Official Testing Method T222 om-83.
13. Halttunen, M.; Vyörykkä, J.; Hortling, B.; Tamminen, T.; Batchelder, D.; Zimmermann, A.; Vuorinen, T. Study of residual lignin in pulp by UV resonance Raman spectroscopy. Holzforschung 2001, 55 (6), 631-638.
14. Tappi official testing method T236 om-99.
15. Tamminen, T.; Ohra-aho, T.; Hortling, B.; Tenkanen, M. Residual lignin in hydrogen peroxide-bleached softwood pulps, 12th International Symposium on Wood and Pulping Chemistry, Madison, WI, June 9-12, 2003; Vol. I, 69-72.
16. Perander, A.-M.; Halttunen, M.; Jääskeläinen, A.-S.; Vyörykkä, J.; Vuorinen, T. Determination of residual lignin from pulp samples with UV resonance Raman spectroscopy, 11th International Symposium on Wood and Pulping Chemistry, Nice, France, June 11-14, 2001; Vol. 1, 331-334.
17. Nuopponen, M.; Saariaho, A.-M.; Vuorinen, T. A study on resin acid model compounds and resin ain pine wood with UV resonance Raman (UVRR) spectroscopy, 7th European Workshop on Lignocellulosics and Pulp, Turku, Finland, Aug 26-29, 2002; 221-224.
18. Jääskeläinen, A.-S.; Saariaho, A.-M.; Matousek, P.; Towrie, M.; Parker, A.W.; Vuorinen, T. Characterisation of residual lignin structures by UV resonance Raman spectroscopy and the possibilities of Raman spectroscopy in the visible region with Kerr-Gated fluorescence suppression, 12th International Symposium on Wood and Pulping Chemistry, Madison, WI, June 9-12, 2003; Vol. 1, 139-142.
19. Tenkanen, M.; Gellerstedt, G.; Vuorinen, T.; Teleman, A.; Perttula, M.; Li, J.; Buchert, J. Determination of hexenuronic acid in softwood kraft pulps by three different methods. J. Pulp Pap. Sci. 1999, 25 (9), 306-311.