A general kinetic model framework for the interpretation of adiabatic calorimeter rate data

Chemical Engineering Journal

Volumn 110, Issue 1-3, 2005, Pages 67-78

  Bhattacharya, Arijit ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Accelerating rate calorimeters (ARC); Kinetic modeling; MOC (material of construction) incompatibility in storage; Multi step reactions; Runaway reactions

Indexed keywords

CALORIMETERS; CATALYSTS; MATHEMATICAL MODELS; THERMAL EFFECTS;

ADIABATIC CALORIMETERS; DATA INTERPRETATION; KINETIC MODEL; THERMOKINETIC ANALYSIS;

REACTION KINETICS;

CALORIMETRY;

EID: 21244476281     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2005.05.003     Document Type: Article

References (19)

1. D.I. Townsend, and J.C. Tou Thermal hazard evaluation by an accelerating rate calorimeter Thermochim. Acta 37 1980 1 30
2. J.C. Leung, H.K. Fauske, and H.G. Fisher Thermal runaway reactions in a low thermal inertia apparatus Thermochim. Acta 104 1986 13 29
3. G. Arabito, V. Caprio, S. Crescitelli, G. Russo, and V. Tufano Runaway reactions in a polyacrylonitrile wet-spinning plant Inst. Chem. Eng. Symp. Ser. No. 82 1983 B10 B17
4. C.H. Bamford C.F.H. Tipper Comprehensive Chemical Kinetics, vol. 16: Liquid Phase Oxidation 1980 Elsevier Amsterdam 58
5. J.M. Zaldivar, C. Barcons, H. Hernandez, E. Molga, and T.J. Snee Modeling and optimization of semi-batch toluene mononitration with mixed acid from performance and safety viewpoints Chem. Eng. Sci. 47 1992 2517 2522
6. S.S.Y. Wang, S. Kiang, and W. Merkl Investigation of a thermal runaway hazard drum storage of thionyl chloride/ethyl acetate mixture Proc. Safety Prog. 13 1994 153 158
7. Y. Iizuka, and M. Surianarayanan Comprehensive kinetic model for adiabatic decomposition of di-tert-butyl peroxide using Batch CAD Ind. Eng. Chem. Res. 42 2003 2987 2995
8. A. Fredenslund, J. Gmehling, and P. Rasmussen Vapour-Liquid Equilibria using UNIFAC 1977 Elsevier Amsterdam pp. 21-26
9. D.W. Smith, M.C. Taylor, R. Young, and T. Stephens Accelerating rate calorimetry Am. Lab. (Fairfield, Conn.) 12 1980 51-54, 56, 61-64, 66
10. Ref. [24] as quoted in [1] above.
11. R. Reid, J.M. Prausnitz, and T.K. Sherwood The Properties of Gases and Liquids 3rd ed. 1977 McGraw-Hill New York
12. J.C. Tou, and L.F. Whiting The thermokinetic performance of an accelerating rate calorimeter Thermochim. Acta 48 1981 21 42
13. E. Bell, F. Rust, and W. Vaughan Decompositions of di-t-alkyl peroxides. IV. Decomposition of pure liquid peroxide J. Am. Chem. Soc. 72 1950 337 338
14. J. Raley, F. Rust, and W. Vaughan Decompositions of di-t-alkyl peroxides. III. Kinetics in liquid phase J. Am. Chem. Soc. 70 1948 1336 1338
15. J. Murawski, J. Roberts, and M. Szward Kinetics of thermal decomposition of di-t-butyl peroxide J. Chem. Phys. 19 1951 698 704
16. A.L. Williams, E.A. Oberright, and J.W. Brooks The abstraction of hydrogen atoms from liquid hydrocarbons by t-butoxy radicals J. Am. Chem. Soc. 78 1956 1190 1193
17. M.S. Kharasch, A. Fono, and W. Nudenberg The chemistry of hydroperoxides. VI. The thermal decomposition of α-cumyl hydroperoxide J. Org. Chem. 16 1951 113 127
18. R.L. Steinberger, and R.E. Treybal Mass transfer from a solid solute sphere to flowing liquid stream AIChE J. 6 1960 227 232
19. R.H. Perry D.W. Green J.O. Maloney Perry's Chemical Engineers' Handbook 7th ed. 1997 McGraw-Hill New York 2 84