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b) Atoms in the periodic system anywhere up to four places before an inert gas change their properties by uniting with 1, 2, 3, or 4, H atoms, so that the resulting complexes behave like pseudoatoms similar to elements of the groups before them in the periodic table.
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11
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21244463780
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see the Supporting Information
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a) For detailed temperature-dependent data for gas-phase IR spectra and HRMS, see the Supporting Information;
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33
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21244500039
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21244439362
-
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see Table S8 in the Supporting Information
-
a) For the approximate assignment of all normal modes on the basis of DFT calculations and trends see Table S8 in the Supporting Information.
-
-
-
-
46
-
-
21244464186
-
-
note
-
+, noncoordinated cations and anions were observed in solid state instead of the three-dimensional network, and the anions do not adopt the parallel eclipsed stacking found in KNNCM (Figure S4).
-
-
-
-
47
-
-
21244479974
-
-
4)NNCM (Tables S4 and S5)
-
4)NNCM (Tables S4 and S5).
-
-
-
-
48
-
-
21244482801
-
-
See Figure S7 and Table S10
-
d) See Figure S7 and Table S10.
-
-
-
-
49
-
-
21244440540
-
-
4)NNCM are given in the Supporting Information. CCDC 261891 and CCDC 261892 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
-
-
-
-
50
-
-
21244465782
-
-
note
-
4NNCM) and 0.090(2) Å (O2, KNNCM).
-
-
-
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51
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0001460427
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21244440913
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55
-
-
21244450602
-
-
note
-
All MOs are shown in Figure S7 of the Supporting Information.
-
-
-
-
56
-
-
21244483775
-
-
see the Supporting Information
-
The other ammonium and alkali-metal NNCM salts can be obtained either by ion-exchange reactions or by the described synthetic procedure (see the Supporting Information).
-
-
-
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58
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0242560405
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